Citation: XU Tian-Yang, ZHAO Ya-Li, LI Jia-Ming, SHI Zhong-Feng. Co(Ⅱ) Coordination Polymer Based on Bis(carboxyl) Dibenzylamine and Bis(imidazole) Biphenyl Ligands: Synthesis, Crystal Structure and Detection for Fe³⁺ Ions in Water[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(9): 1735-1743. doi: 10.11862/CJIC.2020.183 shu

Co(Ⅱ) Coordination Polymer Based on Bis(carboxyl) Dibenzylamine and Bis(imidazole) Biphenyl Ligands: Synthesis, Crystal Structure and Detection for Fe³⁺ Ions in Water

XU Tian-Yang ^1,2 ,
ZHAO Ya-Li ³ ,
LI Jia-Ming ^1,, ,
SHI Zhong-Feng ^1,2,,

1.
College of Petroleum and Chemical Engineering, Beibu Gulf University, Qinzhou, Guangxi 535011, China
2.
School of Chemistry and Pharmacy, Guangxi Normal University, Guilin, Guangxi 541004, China
3.
College of International Studies, Beibu Gulf University, Qinzhou, Guangxi 535011, China

Corresponding author: LI Jia-Ming, jmli@bbgu.edu.cn SHI Zhong-Feng, shizhongfeng01@163.com
Received Date: 20 December 2019
Revised Date: 5 April 2020

Figures(6)

A new Co(Ⅱ)-based coordination polymer (CP), namely {[Co(H₃bcba)(bdmi)]·H₂O}_n (1), where H₃bcba is 4, 4'-biscarboxyl-N, N-dibenzylamine and bdmi is 4, 4'-bis(2-methyl-1H-imidazol-1-yl)-1, 1'-biphenyl, has been hydrothermally synthesized and characterized by single-crystal X-ray diffraction, IR spectroscopy, elemental analysis, thermogravimetric and Hirshfeld surface analyses. X-ray diffraction crystallographic analyses show that the partly deprotonated H₃bcba ligand coordinates two Co (Ⅱ) ions with two carboxylate groups bending bidentate chelate modes, while bdmi serves as a μ₂-bridging ligand in 1, result in a 2D polymeric grid frameworks with a 4-connected (4, 4) topology. In the crystal, a 3D supramolecular architecture is further formed by O-H…O and N-H…O hydrogen bonds, C-H…O and C-H…N interactions, as well as C-H…π stacking in 1. Complex 1 showed intense luminescence in the solid state, and exhibited a high selectivity and sensitivity for Fe³⁺ ions through the fluorescence quenching effect in aqueous solution at room temperature.
- coordination polymer,
- luminescence property,
- fluorescence quenching effect,
- crystal structure,
- synthesis
1. [1]
  Chen L H, McBranch D W, Wang H L, et al. Proc. Natl. Acad. Sci. USA, 1999, 96:12287-12292 doi: 10.1073/pnas.96.22.12287
2. [2]
  Patel S K S, Kumar P, Kalia V C. Int. J. Hydrogen Energy, 2012, 37:10590-10603 doi: 10.1016/j.ijhydene.2012.04.045
3. [3]
  Ward R J, Zucca F A, Duyn J H, et al. Lancet Neurol., 2014, 13:1045-1060 doi: 10.1016/S1474-4422(14)70117-6
4. [4]
  QU Xing-Yu, BIAN Yong-Jun, BAI Yang, et al. Chinese J. Inorg. Chem., 2019, 35(4):649-657
5. [5]
  Nwachukwu M A, Feng H, Alinnor J. Procedia Environ. Sci., 2011, 4:310-322 doi: 10.1016/j.proenv.2011.03.036
6. [6]
  ZHAO Yue, ZHAI Ling-Ling, SUN Wei-Yin. Chinese J. Inorg. Chem., 2014, 30(8):99-105
7. [7]
  Wang B, Yang Q, Guo C, et al. ACS Appl. Mater. Interfaces, 2017, 9:10286-10295 doi: 10.1021/acsami.7b00918
8. [8]
  Chen S G, Shi Z Z, Qin L, et al. Cryst. Growth. Des., 2016, 17:67-72
9. [9]
  Wang T, Liu Q H, Gao Y, et al. Chin. Chem. Lett., 2016, 27:497-501 doi: 10.1016/j.cclet.2016.01.011
10. [10]
  Liu J W, Chen L F, Cui H, et al. Chem. Soc. Rev., 2014, 43:6011-6061 doi: 10.1039/C4CS00094C
11. [11]
  LIU Yuan-Yuan, ZHANG Hui-Min, WANG Xin-Rui, et al. Chinese J. Inorg. Chem., 2018, 34(4):791-799
12. [12]
  HOU Xiang-Yang, WANG Xiao, FU Feng, et al. Chinese J. Inorg. Chem., 2013, 29(10):2245-2250
13. [13]
  Li J X, Du Z X, Zhu B L, et al. Inorg. Chem. Commun., 2011, 14:522-525 doi: 10.1016/j.inoche.2011.01.012
14. [14]
  Li J X, Du Z X, Wang L Z, et al. Inorg. Chim. Acta, 2011, 376:479-485 doi: 10.1016/j.ica.2011.07.013
15. [15]
  Liao H P, Wang H M, Ding H M, et al. J. Mater. Chem. A, 2016, 4:7416-7421 doi: 10.1039/C6TA00483K
16. [16]
  Du Z X, Li J X. Inorg. Chim. Acta, 2015, 436:159-162 doi: 10.1016/j.ica.2015.07.036
17. [17]
  HUANG Yu-Ting, OUYANG Xing-Mei, Okamura T, et al. Chinese J. Inorg. Chem., 2005, 21(10):1479-1482
18. [18]
  Han Y H, Zeng D R, Li J M, et al. J. Coord. Chem., 2018, 71:16-18
19. [19]
  Li J X, Du Z X, Wang J G, et al. Inorg. Chem. Commun., 2012, 15:243-247 doi: 10.1016/j.inoche.2011.10.036
20. [20]
  Li J X, Guo W B, Du Z X, et al. Inorg. Chim. Acta, 2011, 375:290-297 doi: 10.1016/j.ica.2011.05.018
21. [21]
  Rajak R, Saraf M, Verma S K, et al. Inorg. Chem., 2019, 58:16065-16074 doi: 10.1021/acs.inorgchem.9b02611
22. [22]
  Li J X, Du Z X. J. Coord. Chem., 2016, 69:2563-2572 doi: 10.1080/00958972.2016.1216106
23. [23]
  Xu T Y, Wang H, Li J M, et al. Inorg. Chim. Acta, 2019, 493:72-80 doi: 10.1016/j.ica.2019.05.002
24. [24]
  LIU Zhi-Qiang, CAO Shi-Hu, ZHANG Zhe, et al. Chinese J. Inorg. Chem., 2019, 35(11):2145-2151
25. [25]
  Horike S, Hasegawa S, Tanaka D, et al. Chem. Commun., 2008, 37:4436-4438
26. [26]
  Dolomanov O V, Bourhis L J, Gildea R J, et al. J. Appl. Crys-tallogr., 2009, 42:339-341 doi: 10.1107/S0021889808042726
27. [27]
  Sheldrick G M. Acta Crystallogr. Sect. A, 2015, A71:3-8 doi: 10.1107/S2053273314026370
28. [28]
  Sheldrick G M. Acta Crystallogr. Sect. C, 2015, C71:3-8
29. [29]
  Spek A L. J. Appl. Cryst., 2003, 36:7-13 doi: 10.1107/S0021889802022112
30. [30]
  Chen W, Wang J Y, Chen C, et al. Inorg. Chem., 2003, 42:944-946 doi: 10.1021/ic025871j
31. [31]
  Zhou X J, Li B Y, Li G H, et al. CrystEngComm, 2012, 14:4664-4669 doi: 10.1039/c2ce25328c
32. [32]
  Turnner M J, McKinnon J J, Wolff S K, et al. Crystal Explorer 17.5, University of Western Australia, Australia, 2017.
33. [33]
  Konar S, Datta S K, Dolai M, et al. J. Mol. Struct., 2019, 1178:682-691 doi: 10.1016/j.molstruc.2018.10.073
34. [34]
  Yan T, Zhou J, Zhu R R, et al. Inorg. Chem., 2019, 58:3145-3155 doi: 10.1021/acs.inorgchem.8b03210
35. [35]
  Hong D L, Luo Y H, He X T, et al. ACS Appl. Mater. Interfaces, 2019, 11:7272-7279 doi: 10.1021/acsami.8b18883
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Co(Ⅱ) Coordination Polymer Based on Bis(carboxyl) Dibenzylamine and Bis(imidazole) Biphenyl Ligands: Synthesis, Crystal Structure and Detection for Fe3+ Ions in Water

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通讯作者: 陈斌, bchen63@163.com

Co(Ⅱ) Coordination Polymer Based on Bis(carboxyl) Dibenzylamine and Bis(imidazole) Biphenyl Ligands: Synthesis, Crystal Structure and Detection for Fe³⁺ Ions in Water