Citation: WANG Lei, HE Pan-Pan, WANG Hong-Sheng. Structures and Luminescent Properties of Eu(Ⅲ) and Tb(Ⅲ) Complexes with a Pentacarboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(9): 1625-1630. doi: 10.11862/CJIC.2020.182 shu

Structures and Luminescent Properties of Eu(Ⅲ) and Tb(Ⅲ) Complexes with a Pentacarboxylic Acid

College of Chemistry and Chemical Engineering, Xuchang University, Xuchang, Henan 461000, China

Corresponding author: WANG Hong-Sheng, xcuwaller@163.com
Received Date: 27 August 2019
Revised Date: 29 May 2020

Figures(8)

Two 2D coordination polymers {[Eu₄(HL)₂(ox)₂(H₂O)₁₀]·3H₂O}_n (1) and {[Tb₂(HL) (ox) (H₂O)₅]·2H₂O}_n (2) (H₅L=4-(4-carboxyphenyl)-pyridine-2, 3, 5, 6-tetracarboxylic acid; ox=oxalate) were synthesized by using europium or terbium perchlorate to react with a new organic penta-carboxylic acids under hydrothermal condition. Single crystal X-ray diffraction structure analyses show that the two complexes are isomorphic and crystallize in monoclinic crystal system, P2₁/c space group. The oxalate anions were formed perhaps by the decomposition of part of the ligands. A 2D layer is constructed by europium or terbium ions, oxalate anions and HL ligands. Both the complexes emitted the characteristic fluorescence of Eu (Ⅲ) or Tb (Ⅲ). The absolute quantum yields of the luminescence for 1 and 2 were 45% and 38%, respectively. The fluorescence lifetimes of ⁵D₀ excited state for 1 and ⁵D₄ excited state for 2 were also tested and the values were 1.83 and 1.07 ms, respectively.
- 4-(4-carboxyphenyl)pyridine-2, 3, 5, 6-tetracarboxylic acid,
- europium,
- terbium,
- coordination polymer,
- quantum yield,
- fluorescence lifetime
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