Citation: LI Yu, ZHAO Zhen-Yu, ZOU Xun-Zhong, FENG An-Sheng, QIU Wen-Da. Syntheses, Crystal Structures, and Luminescent Property of Two 1D Cadmium(Ⅱ) Coordination Polymers Assembled from an Ether-Bridged Tetracarboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(9): 1728-1734. doi: 10.11862/CJIC.2020.181 shu

Syntheses, Crystal Structures, and Luminescent Property of Two 1D Cadmium(Ⅱ) Coordination Polymers Assembled from an Ether-Bridged Tetracarboxylic Acid

1.
Guangdong Research Center for Special Building Materials and Its Green Preparation Technology/Foshan Research Center for Special Functional Building Materials and Its Green Preparation Technology, Guangdong Industry Polytechnic, Guangzhou 510300, China
2.
School of Intelligent Manufacturing and Equipment, Shenzhen Institute of Information Technology, Shenzhen, Guangdong 518172, China

Corresponding author: ZHAO Zhen-Yu, shzhzhao123@163.com QIU Wen-Da, qiuwd123@163.com
Received Date: 12 December 2019
Revised Date: 26 March 2020

Figures(8)

Two 1D cadmium(Ⅱ) coordination polymers, namely[Cd₂(μ₅-L)(phen)₂]_n (1) and {[Cd₂(μ₄-L)(2, 2'-bipy)₂ (H₂O)₂]·2H₂O}_n (2), have been constructed hydrothermally using H₄L (H₄L=2, 3, 3', 4'-diphenyl ether tetracarboxylic acid), phen (phen=1, 10-phenanthroline), 2, 2'-bipy (2, 2'-bipy=2, 2'-bipyridine), and cadmium chloride. Single-crystal X-ray diffraction analyses reveal that two polymers crystallize in the monoclinic or triclinic systems, space groups P2₁/c or P1. Polymers 1 and 2 show 1D chains composed of Cd₄ or Cd₂ units. The luminescent properties for two compounds were also investigated.
- coordination polymer,
- tetracarboxylic acid,
- luminescent properties
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1.
沈阳化工大学材料科学与工程学院沈阳 110142