Citation: WANG Ying-Ying, TONG Hong-Bo, ZHOU Mei-Su. Pentanuclear Sn(Ⅱ) Guanidinate Complex: Synthesis, Structure, and Catalytic Activity for Addition of Arylamines into N, N'-Diisopropylcarbodiimide[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(8): 1567-1572. doi: 10.11862/CJIC.2020.178 shu

Pentanuclear Sn(Ⅱ) Guanidinate Complex: Synthesis, Structure, and Catalytic Activity for Addition of Arylamines into N, N'-Diisopropylcarbodiimide

Institute of Applied Chemistry, Shanxi University, Taiyuan 030006, China

Corresponding author: ZHOU Mei-Su, mszhou@sxu.edu.cn
Received Date: 20 December 2019
Revised Date: 20 April 2020

Figures(3)

A pentanuclear Sn(Ⅱ) guanidinate complex[PhNC(NMe)₂N(H)SnCl]₂[PhNC(NMe)₂NSnCl]₂Sn (1) was synthesized via the reaction of PhN(Li)SiMe₃ and anhydrous tin(Ⅱ) chloride. It was well structurally characterized by ¹H NMR, ¹³C NMR, elemental analysis, and X-ray single crystal crystallography techniques. Complex 1 is an active catalyst in the addition reaction of arylamines into N, N'-diisopropylcarbodiimide giving guanidinates. CCDC:1954650.
- tin(Ⅱ),
- guanidinate,
- structure,
- catalytic addition
1. [1]
  Edelmann F T. Adv. Organomet. Chem., 2008, 57:183-352 doi: 10.1016/S0065-3055(08)00003-8
2. [2]
  Coles M P. Dalton Trans., 2006(8):985-1001 doi: 10.1039/b515490a
3. [3]
  Foley S R, Yap G P A, Richeson D S. Inorg. Chem., 2002, 41(16):4149-4157 doi: 10.1021/ic020088c
4. [4]
  Zhou M S, Tong H B, Wei X H, et al. J. Organomet. Chem., 2007, 692(23):5195-5202 doi: 10.1016/j.jorganchem.2007.07.051
5. [5]
  Zhou M S, Zhang S, Tong H B, et al. Inorg. Chem. Commun., 2007, 10(11):1262-1264 doi: 10.1016/j.inoche.2007.08.001
6. [6]
  Bazinet P, Wood D, Yap G P A, et al. Inorg. Chem., 2003, 42(20):6225-6229 doi: 10.1021/ic034445a
7. [7]
  Zhang J, Cai R F, Weng L H, et al. J. Organomet. Chem., 2003, 672(1/2):94-99
8. [8]
  Corey B W, Laurel L R, Khalil A A, et al. Inorg. Chem., 2006, 45(1):263-268 doi: 10.1021/ic051497m
9. [9]
  Daniel R, Arne B, Manuela W, et al. Inorg. Chem., 2006, 45(1):269-277 doi: 10.1021/ic0512431
10. [10]
  Coles M P, Hitchcock P B. Eur. J. Inorg. Chem., 2004(13):2662-2672
11. [11]
  Wang H, Guo Z L, Tong H B, et al. Polyhedron, 2018, 141:100-104 doi: 10.1016/j.poly.2017.11.027
12. [12]
  Foley S R, Zhou Y L, Yap G P A, et al. Inorg. Chem., 2000, 39(5):924-929 doi: 10.1021/ic991004b
13. [13]
  Foley S R, Yap G P A, Richeson D S. Organometallics, 1999, 18(23):4700-4705 doi: 10.1021/om990405w
14. [14]
  Foley S R, Yap G P A, Richeson D S. Polyhedron, 2002, 21(5/6):619-627
15. [15]
  Chlupatý T, Padělková Z, DeProft F, et al. Organometallics, 2012, 31(6):2203-2211 doi: 10.1021/om201118m
16. [16]
  Barman M K, Baishya A, Peddarao T, et al. J. Organomet. Chem., 2014, 772:265-270
17. [17]
  Chlupaty T, Ruzickova Z, Horacek M, et al. Organometal-lics, 2015, 34(11):2202-2211 doi: 10.1021/om500873a
18. [18]
  Ahmet I Y, Hill M S, Raithby P R, et al. Dalton Trans., 2018, 47(14):5031-5048 doi: 10.1039/C8DT00773J
19. [19]
  Guo Z L, Liu F, Tong H B, et al. Polyhedron, 2018, 151:273-278 doi: 10.1016/j.poly.2018.05.016
20. [20]
  Guo Z L, Tian D, Yang Q K, et al. Polyhedron, 2019, 166:162-165 doi: 10.1016/j.poly.2019.03.057
21. [21]
  Sheldrick G M. Correction Software, University of Götting-gen, Germany, 1996.
22. [22]
  Sheldrick G M. ^{Program for the Solution of Crystal Struc-tures}, University of Göttinggen, Germany, 1997.
23. [23]
  Sheldrick G M. SHELXTL, Ver. 6.14, Bruker Analytical X-ray Instruments, Inc., Madison, WI, USA, 2003.
24. [24]
  Vaňkátová H, Broeckaert L, Proft F D, et al. Inorg. Chem., 2011, 50(19):9454-9464 doi: 10.1021/ic2011056
25. [25]
  Chivers T, Eisler D J, Ritch J S. Z. Anorg. Allg. Chem., 2004, 630(12):1941-1946 doi: 10.1002/zaac.200400284
26. [26]
  Armstrong D R, Benevelli F, Bond A D, et al. Inorg. Chem., 2002, 41(6):1492-1501 doi: 10.1021/ic011090r
27. [27]
  DENG Yi-Fang, CHEN Man-Sheng, ZHANG Chun-Hua, et al. Chinese J. Inorg. Chem., 2009, 25(12):2229-2232 doi: 10.3321/j.issn:1001-4861.2009.12.028
28. [28]
  YU Jiang-Xi, FENG Yong-Lan, PENG Yan, et al. Chinese J. Inorg. Chem., 2014, 30(5):1135-1142
29. [29]
  Allen F H, Kennard O, Watson D G, et al. J. Chem. Soc. Per-kin Trans.2, 1987:S1-S19
30. [30]
  Dias H V R, Jin W. J. Am. Chem. Soc., 1996, 118(38):9123-9126 doi: 10.1021/ja961910c
31. [31]
  Bos K D, Bulten E J, Noltes J G, et al. J. Organomet. Chem., 1975, 99(1):71-77 doi: 10.1016/S0022-328X(00)86363-9
32. [32]
  Veith M. Z. Naturforsch. B, 1978, 33b:7-13
33. [33]
  YANG Hua, LI Lei, LIU Xiao-Li. Chemical Research and Application, 2015, 27(4):429-434 doi: 10.3969/j.issn.1004-1656.2015.04.003
34. [34]
  SHEN Qi(沈琪), ZHU Xu-Hua(朱雪华), XU Fan(徐凡). China Patent, 201110177362.4. 2011-12-14.
35. [35]
  Hong Y B, Zheng Y, Xue M Q, et al. Z. Anorg. Allg. Chem., 2015, 641(7):1230-1237 doi: 10.1002/zaac.201500047
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