Citation: LI Jin-Jin, LIU Cong-Cong, GUO Min, LI Shi-Ying, WU Zi-Chen, ZHAO Xiao-Li, YANG Xiao-Wei. Electrochemical Preparation of MoS₂ Intercalated Compound with Micron Size for Magnesium-Ion Storage[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(8): 1543-1549. doi: 10.11862/CJIC.2020.173 shu

Electrochemical Preparation of MoS₂ Intercalated Compound with Micron Size for Magnesium-Ion Storage

School of Materials Science and Engineering, Tongji University, Shanghai 201804, China

Corresponding author: ZHAO Xiao-Li, zxl36@tongji.edu.cn
Received Date: 15 April 2020
Revised Date: 28 May 2020

Figures(7)

The micro-sized MoS₂ intercalated compound with the intercalant of 1-butyl-3-methyl-imidazolium cation (BMIM⁺) was prepared by a simple electrochemical method and used as cathode material of magnesium ion batteries. The MoS₂ intercalated compound (denoted as MoS₂-BMIM⁺) has an expanded interlayer spacing of 0.98 nm, which effectively reduced the insertion/extraction barrier of Mg²⁺ and provided abundant active sites for Mg²⁺ intercalation. Therefore, the MoS₂-BMIM+ deliverd a significantly improved charging capacity (101.93 mAh·g^-1 at 20 mA· g^-1, about 4 times as much as bulk MoS₂) and a good rate performance. We further show that this method can also be applied for the intercalation of 1-butyl-1-methylpyrrolidinium cation (Pyr₁₄⁺), which showed an interlayer spacing of 1.04 nm.
- magnesium ion battery,
- cathode material,
- molybdenum disulfide,
- electrochemical intercalation,
- interlayer spacing
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Electrochemical Preparation of MoS2 Intercalated Compound with Micron Size for Magnesium-Ion Storage

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Electrochemical Preparation of MoS₂ Intercalated Compound with Micron Size for Magnesium-Ion Storage