Citation: YANG Zong-Fei, DONG Kai-Li, JIN Lin-Yu, MA Peng-Tao, WANG Jing-Ping, NIU Jing-Yang. Synthesis, Structure and Properties of a Germanotungstate Containing an Octanuclear Cobalt(Ⅱ) Cluster[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(6): 1093-1097. doi: 10.11862/CJIC.2020.152 shu

Synthesis, Structure and Properties of a Germanotungstate Containing an Octanuclear Cobalt(Ⅱ) Cluster

Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan 475004, China

Corresponding author: WANG Jing-Ping, jpwang@henu.edu.cn NIU Jing-Yang, jyniu@henu.edu.cn
Received Date: 28 April 2020
Revised Date: 12 May 2020

Figures(3)

A high-nuclearity transition metal derivative based on the trivacant Keggin-type polyoxotungstate {GeW₉O₃₄}, K_10.5Cs₄H_1.5{[Co₈(OH)₆(H₂O)₂](CO₃)₃(GeW₉O₃₄)₂}·12H₂O (1), has been successfully synthesized by the reaction of K₈Na₂ [A-α-GeW₉O₃₄]·25H₂O, Co(NO₃)₂·6H₂O and K₂CO₃ in a conventional aqueous solution method. It was structurally characterized by elemental analysis, IR spectrum, TG analysis and X-ray single crystal diffraction, etc. The results show that compound 1 contains a V-type polyoxoanion {[Co₈(OH)₆(H₂O)₂](CO₃)₃(GeW₉O₃₄)₂}^16-, and further forms a two-dimensional structure through K⁺ and Cs⁺ connections. In addition, magnetic properties show that compound 1 mainly represents the antiferromagnetic exchange interactions among Co²⁺ centers.
- polyoxometalates,
- high-nuclearity transition metal cluster,
- crystal structure,
- magnetic properties
1. [1]
  Clemente-Juan J M, Coronado E. Coord. Chem. Rev., 1999, 193:361-394
2. [2]
  Mizuno N, Yamaguchi K, Kamata K. Coord. Chem. Rev., 2005, 249:1944-1956 doi: 10.1016/j.ccr.2004.11.019
3. [3]
  He T, Yao J N. Prog. Mater. Sci., 2006, 51:810-879 doi: 10.1016/j.pmatsci.2005.12.001
4. [4]
  GU Wen-Jun, GU Jin-Zhong. Chinese J. Inorg. Chem., 2017, 33:227-236 doi: 10.11862/CJIC.2017.035
5. [5]
  Ma P T, Hu F, Wang J P, et al. Coord. Chem. Rev., 2019, 378:281-309 doi: 10.1016/j.ccr.2018.02.010
6. [6]
  Zheng S T, Yang G Y. Chem. Soc. Rev., 2012, 41:7623-7646 doi: 10.1039/c2cs35133a
7. [7]
  NIU Jing-Yang, WANG Jing-Ping. Introduc-tion of Heteropoly Compound. Kaifeng:Henan University Press, 2000.
8. [8]
  Kortz U, Savelieff M G, Bassil B S, et al. Inorg. Chem., 2002, 41:783-789 doi: 10.1021/ic010855s
9. [9]
  Anderson T M, Neiwert W A, Hardcastle K I, et al. Inorg. Chem., 2004, 43:7353-7358 doi: 10.1021/ic049517s
10. [10]
  Bi L H, Kortz U, Nellutla S, et al. Inorg. Chem., 2005, 44:896-903 doi: 10.1021/ic048713w
11. [11]
  Zhao J W, Zhang J, Zheng S T, et al. Inorg. Chem., 2007, 46:10944-10946 doi: 10.1021/ic701810t
12. [12]
  Compain J D, Mialane P, Dolbecq A, et al. Angew. Chem. Int. Ed., 2009, 48:3077-3081 doi: 10.1002/anie.200900117
13. [13]
  Singh V, Chen Z Y, Ma P T, et al. Chem. Eur. J., 2016, 22:10983-10989 doi: 10.1002/chem.201601453
14. [14]
  Pastor N C, Serra J B, Coronado E, et al. J. Am. Chem. Soc., 1992, 114:10380-10383 doi: 10.1021/ja00052a038
15. [15]
  Ibrahim M, Lan Y, Bassil B S, et al. Angew. Chem. Int. Ed., 2011, 50:4708-4711 doi: 10.1002/anie.201100280
16. [16]
  Han X B, Zhang Z M, Zhang T, et al. J. Am. Chem. Soc., 2014, 136:5359-5366 doi: 10.1021/ja412886e
17. [17]
  Sato R, Suzuki K, Minato T, et al. Chem. Commun., 2015, 51:4081-4084 doi: 10.1039/C4CC09435B
18. [18]
  Duan Y, Clemente-juan J M, Fierro J L G, et al. Chem. Commun., 2016, 52:13245-13248 doi: 10.1039/C6CC05485D
19. [19]
  Zhang Z M, Li Y G, Wang E B, et al. Inorg. Chem., 2006, 45:4313-4315 doi: 10.1021/ic052149n
20. [20]
  Wang J P, Ma P T, Shen Y, et al. Cryst. Growth Des., 2007, 7:603-605 doi: 10.1021/cg060751y
21. [21]
  Pichon C, Mialane P, Dolbecq A, et al. Inorg. Chem., 2008, 47:11120-11128 doi: 10.1021/ic801431f
22. [22]
  Zhang H M, Li Y G, Lu Y, et al. Inorg. Chem., 2009, 48:10889-10891 doi: 10.1021/ic901552f
23. [23]
  Han X B, Li Y G, Zhang Z M, et al. J. Am. Chem. Soc., 2015, 137:5486-5493 doi: 10.1021/jacs.5b01329
24. [24]
  Ritchie C, Ferguson A, Nojiri H, et al. Angew. Chem. Int. Ed., 2008, 47:5609-5612 doi: 10.1002/anie.200801281
25. [25]
  Wu Q, Li Y G, Wang Y H, et al. Inorg. Chem., 2009, 48:1606-1612 doi: 10.1021/ic802023h
26. [26]
  Haider A, Ibrahim M, Bassil B S, et al. Inorg. Chem., 2016, 55:2755-2764 doi: 10.1021/acs.inorgchem.5b02503
27. [27]
  Limanski E M, Piepenbrink M, Droste E, et al. J. Cluster Sci., 2002, 13:369-379 doi: 10.1023/A:1020551016077
28. [28]
  Mialane P, Dolbecq A, Marrot J, et al. Angew. Chem. Int. Ed., 2003, 42:3523-3526 doi: 10.1002/anie.200351486
29. [29]
  Farsani M R, Jalilian F, Yadollahi B, et al. Polyhedron, 2014, 76:102-107 doi: 10.1016/j.poly.2014.03.060
30. [30]
  Gilbert H, Ander T. Inorg. Chem., 1997, 16:2115-2117
31. [31]
  Sheldrick G M. Acta Crystallogr. Sect. A, 2008, A64:112-122
32. [32]
  Mialane P, Duboc C, Marrot J, et al. Chem. Eur. J., 2006, 12:1950-1959 doi: 10.1002/chem.200500877
33. [33]
  Han X B, Zhang Z M, Zhang T, et al. J. Am. Chem. Soc., 2014, 136:5359-5366 doi: 10.1021/ja412886e
34. [34]
  Liu H, Qin C, Wei Y G, et al. Inorg. Chem., 2008, 47:4166-4172 doi: 10.1021/ic7022264
35. [35]
  Zhang Z M, Duan X, Yao S, et al. Chem. Sci., 2016, 7:4220-4229 doi: 10.1039/C5SC04408A
36. [36]
  Brown I D, Altermatt D. Acta Crystallogr. Sect. B, 1985, B41:244-246
37. [37]
  Zhao J W, Shi D Y, Chen L J, et al. Dalton Trans., 2012, 41:10740-10751 doi: 10.1039/c2dt30949a
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