Citation: YU Hai-Feng, WANG Fang, FENG Ting, LIU Shao-Bing, MA Fu-Gui, YANG Meng-Xin, LIANG Peng-Ju. Zn-Doped Co₉S₈ Nanomaterials: Preparation and Application for Supercapacitor and Hydrogen Evolution Reaction of Electrocatalysis[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(7): 1318-1326. doi: 10.11862/CJIC.2020.147 shu

Zn-Doped Co₉S₈ Nanomaterials: Preparation and Application for Supercapacitor and Hydrogen Evolution Reaction of Electrocatalysis

1.
College of Chemistry and Chemistry, Luoyang Institute of Science and Technology, Luoyang, Henan 471023, China
2.
State Key Laboratory of Organic-Inorganic Composites, Beijing 100029, China
3.
College of Life Science, Tarim University, Alar, Xinjiang 843300, China

Corresponding author: WANG Fang, wangfang1116@163.com LIANG Peng-Ju, lpjltx1984@163.com
Received Date: 17 October 2019
Revised Date: 24 April 2020

Figures(6)

Herein, Zn-doped Co₉S₈ nanoparticles were synthesized via an in situ solvothermal growth method. These particles have a pore size of 18 nm and specific surface area of 23 m²·g^-1. A series of performance tests showed that microscale Zn doping significantly improved the catalytic activity and capacitor performance of Co₉S₈. In HER performance tests, Zn-doped Co₉S₈ exhibited a lower potential of -361 mV at the current density of 10 mA·cm^-2 and the highest current density up to 38.26 mA·cm^-2, excellent cycling stability as well. In capacitor performance tests, Zndoped Co₉S₈ showed pretty high specific capacitance with mass and area specific capacitances of 235.48 F·g^-1 and 812.4 mF·cm^-2 respectively at a current density of 1 A·g^-1.
- doping,
- Co₉S₈,
- nanoparticles,
- HER performance,
- supercapacitors,
- energy conversion
1. [1]
  Yu L, Zhou H Q, Sun J Y, et al. Energy Environ. Sci., 2017, 10(8):1820-1827 doi: 10.1039/C7EE01571B
2. [2]
  Li S W, Wang Y C, Peng S J, et al. Adv. Energy Mater., 2016, 6(3):1501661
3. [3]
  Valenti G, Boni A, Melchionna M, et al. Nat. Commun., 2016, 7:13549 doi: 10.1038/ncomms13549
4. [4]
  Zhu X D, Xie Y, Liu Y T. J. Mater. Chem. A, 2018, 6(43):21255-21260 doi: 10.1039/C8TA08374F
5. [5]
  ZHOU Yue-Wei, JI Yun-Hui, TAN ChangBin, et al. Chinese J. Inorg. Chem., 2019, 35(8):1419-1426
6. [6]
  LI Hui-Hua, SONG Juan, ZHOU Jin-Hua, et al. Chinese J. Inorg. Chem., 2016, 32(11):2041-2048
7. [7]
  LI Hui-Hua, GE You, ZHU Hong-Li, et al. Chinese J. Inorg. Chem., 2018, 34(10):1799-1807 doi: 10.11862/CJIC.2018.231
8. [8]
  Zou K Y, Cai P, Liu C, et al. J. Mater. Chem. A, 2019, 7(22):13540-13549 doi: 10.1039/C9TA03797G
9. [9]
  Zou G Q, Hou H S, Foster C W, et al. Adv. Sci., 2018, 5:1800241 doi: 10.1002/advs.201800241
10. [10]
  Hou H S, Banks C E, Jing M J, et al. Adv. Mater., 2015, 27(47):7861-7866 doi: 10.1002/adma.201503816
11. [11]
  Chao L, Balamurugan J, Kim N H, et al. Adv. Energy Mater., 2017, 8(8):1702014
12. [12]
  Xiong D B, Li X F, Bai Z M, et al. Small, 2018, 14(17):1703419 doi: 10.1002/smll.201703419
13. [13]
  Miller J R, Simon P. Science, 2008, 321(5889):651-652 doi: 10.1126/science.1158736
14. [14]
  Choudhary N, Li C, Moore J, et al. Adv. Mater., 2017, 29(21):1605336 doi: 10.1002/adma.201605336
15. [15]
  Yu Z N, Tetard L, Zhai L, et al. Energy Environ. Sci., 2015, 8(3):702-730
16. [16]
  Jia H N, Lin J H, Liu Y L, et al. J. Mater. Chem. A, 2017, 5(21):10678-10686 doi: 10.1039/C7TA02627G
17. [17]
  Yu N, Guo K, Zhang W, et al. J. Mater. Chem. A, 2017, 5(2):804-813
18. [18]
  Gutierrez-Pardo A, Lacroix B, Martinez-Fernandez J, et al. ACS Appl. Mater. Interfaces, 2016, 8(45):30890-30898 doi: 10.1021/acsami.6b09361
19. [19]
  Li X F, Shen J F, Li N, et al. J. Power Sources, 2015, 282:194-201 doi: 10.1016/j.jpowsour.2015.02.057
20. [20]
  Song X Z, Sun F F, Meng Y L, et al. New J. Chem., 2019, 43(8):3601-3608 doi: 10.1039/C8NJ05814H
21. [21]
  Rui K H, Liu J J, Tu R, et al. J. Alloys Compd., 2018, 747:100-108 doi: 10.1016/j.jallcom.2018.02.347
22. [22]
  Liu Y T, Zhu X D, Xie X M. Adv. Sustainable Syst., 2018, 2(1):1700107
23. [23]
  Wang W C, Yuan Y L, Yang J, et al. J. Mater. Sci., 2018, 53:6116-6123 doi: 10.1007/s10853-017-1971-z
24. [24]
  Wei X J, Zhang Y H, He H C, et al. Chem. Commun., 2019, 55(46):6515-6518 doi: 10.1039/C9CC02037C
25. [25]
  Haripriya M, Sivasubramanian R, Ashok A M, et al. J. Mater. Sci:Mater. Electron., 2019, 30:7497-7506 doi: 10.1007/s10854-019-01063-z
26. [26]
  Basu M. Chem. Asian J., 2018, 13(21):3204-3211 doi: 10.1002/asia.201801185
27. [27]
  Zhang S L, Zhai D, Sun T T, et al. Appl. Catal. B, 2019, 254:186-193 doi: 10.1016/j.apcatb.2019.04.096
28. [28]
  Yu H, Miao S J, Tang D H, et al. J. Colloid Interface Sci., 2019, 558:155-162
29. [29]
  Du X Q, Huang C R, Zhang X S. Int. J. Hydrogen Energy, 2019, 44(36):19953-19966 doi: 10.1016/j.ijhydene.2019.06.003
30. [30]
  Yang Y, Yao H Q, Yu Z H, et al. J. Am. Chem. Soc, 2019, 141(26):10417-10430 doi: 10.1021/jacs.9b04492
31. [31]
  Chauke H R, Nguyen-Manh D, Ngoepe P E, et al. Phys. Rev. B, 2002, 66(15):155105 doi: 10.1103/PhysRevB.66.155105
32. [32]
  Yu X Y, Yu L, Lou X W. Adv. Energy Mater., 2016, 6(3):1501333
33. [33]
  Wang X Z, Su D C, Xiao Y H, et al. Electrochim. Acta, 2019, 293:419-425 doi: 10.1016/j.electacta.2018.10.059
34. [34]
  Liu Q, Hong X D, Zhang X, et al. Chem. Eng. J., 2019, 356:985-993 doi: 10.1016/j.cej.2018.09.095
35. [35]
  Xie B Q, Yu M Y, Lu L H, et al. Carbon, 2019, 141:134-142 doi: 10.1016/j.carbon.2018.09.044
36. [36]
  Zhou Y Q, Li N, Sun L D, et al. Nanoscale, 2019, 11(15):7457-7464 doi: 10.1039/C9NR00828D
37. [37]
  Feng L L, Fan M H, Wu Y Y, et al. J. Mater. Chem. A, 2016, 4(18):6860-6867 doi: 10.1039/C5TA08611F
38. [38]
  Wang F, Liu T, Guo Y F, et al. RSC Adv., 2017, 7(55):3476334769
39. [39]
  Miao R, Tao B R, Miao F J, et al. Ionics, 2019, 25:1783-1792 doi: 10.1007/s11581-019-02888-8
40. [40]
  Zhou Y, Xi S Q, Yang X G, et al. J. Solid State Chem., 2019, 270:398-406 doi: 10.1016/j.jssc.2018.12.004
41. [41]
  Niu H T, Zhang Y, Liu Y, et al. J. Mater. Chem. A, 2019, 7(14):8503-8509 doi: 10.1039/C8TA11983J
42. [42]
  Wen Y X, Liu Y P, Dang S, et al. J. Power Sources, 2019, 423:106-114 doi: 10.1016/j.jpowsour.2019.03.045
43. [43]
  Lu W, Yuan Z, Xu C Y, et al. J. Mater. Chem. A, 2019, 7(10):5333-5343 doi: 10.1039/C8TA10998B
44. [44]
  Wang F, Qiao J S, Wang J, et al. Electrochim. Acta, 2018, 271:1-9
45. [45]
  Liang P J, Wang F, Hu Z A. Chem. Eng. J., 2018, 350:627636
46. [46]
  Yao M, Sun P X, He W D, et al. Nanoscale, 2019, 11(2):688697
47. [47]
  Qi H L, Bo Z, Yang S L, et al. Energy Storage Mater., 2019, 16:607-618 doi: 10.1016/j.ensm.2018.07.019
48. [48]
  Qian J M, Wang T T, Xia B R, et al. Electrochim. Acta, 2019, 296:701-708 doi: 10.1016/j.electacta.2018.10.089
49. [49]
  Li H M, Qian X, Xu C, et al. ACS Appl. Mater. Interfaces, 2017, 9(34):28394-28405 doi: 10.1021/acsami.7b06384
50. [50]
  Yu H, Miao S J, Tang D H, et al. J. Colloid Interface Sci., 2020, 558:155-162 doi: 10.1016/j.jcis.2019.09.121
51. [51]
  Mujtaba J, Sun H Y, Huang G Y, et al. RSC Adv., 2016, 6:31775-31781 doi: 10.1039/C6RA03126A
52. [52]
  Wang J, Bai F, Chen X, et al. J. Mater. Chem. A, 2017, 5(7):3628-3637 doi: 10.1039/C6TA10151H
53. [53]
  Tang Y P, Jing F, Xu Z X, et al. ACS Appl. Mater. Interfaces, 2017, 9(14):12340-12347 doi: 10.1021/acsami.6b15461
54. [54]
  Liu P, Chang X, Lin J J, et al. J. Mater. Sci., 2018, 53:759773
55. [55]
  Guo M, Balamurugan J, Li X Y, et al. Small, 2017, 13(33):1701275 doi: 10.1002/smll.201701275
56. [56]
  Li Y J, Zhang H C, Jiang M, et al. Adv. Funct. Mater., 2017, 27(37):1702513 doi: 10.1002/adfm.201702513
1. [1]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
2. [2]
  Min LUO , Xiaonan WANG , Yaqin ZHANG , Tian PANG , Fuzhi LI , Pu SHI . Porous spherical MnCo₂S₄ as high-performance electrode material for hybrid supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 413-424. doi: 10.11862/CJIC.20240205
3. [3]
  Siling Chen , Yang Hu , Sijia Zhang , Xuesong Liu , Zhuqun Shi , Chuanxi Xiong , Weiwei Wu , Ruizhi Ning , Quanling Yang . Enhancing the electroactivity of supercapacitors through nitrogen doping on cellulose-derived carbon materials. Chinese Chemical Letters, 2026, 37(2): 111301-. doi: 10.1016/j.cclet.2025.111301
4. [4]
  Wenjiang LI , Pingli GUAN , Rui YU , Yuansheng CHENG , Xianwen WEI . C₆₀-MoP-C nanoflowers van der Waals heterojunctions and its electrocatalytic hydrogen evolution performance. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 771-781. doi: 10.11862/CJIC.20230289
5. [5]
  Hao GUO , Tong WEI , Qingqing SHEN , Anqi HONG , Zeting DENG , Zheng FANG , Jichao SHI , Renhong LI . Electrocatalytic decoupling of urea solution for hydrogen production by nickel foam-supported Co₉S₈/Ni₃S₂ heterojunction. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2141-2154. doi: 10.11862/CJIC.20240085
6. [6]
  Jie WEI , Qing ZHOU , Dandan DING , Xiang JING , Fei LI . Photothermal toxicity of Prussian blue nanoparticles to cervical cancer cells. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2345-2357. doi: 10.11862/CJIC.20240435
7. [7]
  Weilong Liu , Jipeng Dong , Luyao Zhang , Ning Li , Yangqin Gao , Lei Ge . Dynamic tuning of d-p orbital hybridization during sulfur vacancy evolution in Co9S8 toward efficient overall water splitting. Chinese Journal of Structural Chemistry, 2025, 44(9): 100661-100661. doi: 10.1016/j.cjsc.2025.100661
8. [8]
  Ting Shi , Ziyang Song , Yaokang Lv , Dazhang Zhu , Ling Miao , Lihua Gan , Mingxian Liu . Hierarchical porous carbon guided by constructing organic-inorganic interpenetrating polymer networks to facilitate performance of zinc hybrid supercapacitors. Chinese Chemical Letters, 2025, 36(1): 109559-. doi: 10.1016/j.cclet.2024.109559
9. [9]
  Mengying XU , Wen LI , Junzhong MEI , Cheng ZHANG , Kannan Palanisamy , Lei LU , Lianpeng ZHANG , Peng WANG . Manganese-doped poly(1,5-diaminonaphthalene) based high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2026, 42(2): 387-397. doi: 10.11862/CJIC.20250211
10. [10]
  Qiang Fu , Shouhong Sun , Kangzhi Lu , Ning Li , Zhanhua Dong . Boron-doped carbon dots: Doping strategies, performance effects, and applications. Chinese Chemical Letters, 2024, 35(7): 109136-. doi: 10.1016/j.cclet.2023.109136
11. [11]
  Xingxing Jiang , Yuxin Zhao , Yan Kong , Jianju Sun , Shangzhao Feng , Xin Lu , Qi Hu , Hengpan Yang , Chuanxin He . Support effect and confinement effect of porous carbon loaded tin dioxide nanoparticles in high-performance CO₂ electroreduction towards formate. Chinese Chemical Letters, 2025, 36(1): 109555-. doi: 10.1016/j.cclet.2024.109555
12. [12]
  Jieqiong Qin , Zhi Yang , Jiaxin Ma , Liangzhu Zhang , Feifei Xing , Hongtao Zhang , Shuxia Tian , Shuanghao Zheng , Zhong-Shuai Wu . Interfacial assembly of 2D polydopamine/graphene heterostructures with well-defined mesopore and tunable thickness for high-energy planar micro-supercapacitors. Chinese Chemical Letters, 2024, 35(7): 108845-. doi: 10.1016/j.cclet.2023.108845
13. [13]
  Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473
14. [14]
  Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au₁₁(dppf)₄Cl₂ nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047
15. [15]
  Pingping LU , Shuguang ZHANG , Peipei ZHANG , Aiyun NI . Preparation of zinc sulfate open frameworks based probe materials and detection of Pb²⁺ and Fe³⁺ ions. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 959-968. doi: 10.11862/CJIC.20240411
16. [16]
  Qilin YU , Yifei XU , Pengjun ZHANG , Shuwei HAO , Chongqiang ZHU , Chunhui YANG . Effect of regulating K⁺/Na⁺ ratio on the structure and optical properties of double perovskite Cs₂NaBiCl₆: Mn²⁺. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1058-1067. doi: 10.11862/CJIC.20240418
17. [17]
  Ximeng CHI , Jianwei WEI , Yunyun WANG , Wenxin DENG , Jiayi DAI , Xu ZHOU . First-principles study of the electronic structure and optical properties of Au and I doped-inorganic lead-free double perovskite Cs₂NaBiCl₆. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1371-1379. doi: 10.11862/CJIC.20240401
18. [18]
  Jianqiao ZHANG , Yang LIU , Yan HE , Yaling ZHOU , Fan YANG , Shihui CHENG , Bin XIA , Zhong WANG , Shijian CHEN . Ni-doped WP₂ nanowire self-standingelectrode: Preparation and alkaline electrocatalytic hydrogen evolution property. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1610-1616. doi: 10.11862/CJIC.20240444
19. [19]
  Ao XIA , Botao YU , Jun CHEN , Guoqiang TAN . Preparation and electrochemical property of Ce-doped MnO₂. Chinese Journal of Inorganic Chemistry, 2025, 41(12): 2514-2526. doi: 10.11862/CJIC.20250163
20. [20]
  Tingting Liu , Pengfei Sun , Wei Zhao , Yingshuang Li , Lujun Cheng , Jiahai Fan , Xiaohui Bi , Xiaoping Dong . Magnesium doping to improve the light to heat conversion of OMS-2 for formaldehyde oxidation under visible light irradiation. Chinese Chemical Letters, 2024, 35(4): 108813-. doi: 10.1016/j.cclet.2023.108813

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(1460)
HTML views(244)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Zn-Doped Co9S8 Nanomaterials: Preparation and Application for Supercapacitor and Hydrogen Evolution Reaction of Electrocatalysis

Metrics

通讯作者: 陈斌, bchen63@163.com

Zn-Doped Co₉S₈ Nanomaterials: Preparation and Application for Supercapacitor and Hydrogen Evolution Reaction of Electrocatalysis