Citation: WANG He-Li, ZHU Mei-Hua, WU Ting, ZHANG Fei, WU Ya-Fen, CHEN Xiang-Shu. Hydrothermal Secondary Growth Process of High-Slica SSZ-13 Zeolite Membrane[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(7): 1366-1374. doi: 10.11862/CJIC.2020.140 shu

Hydrothermal Secondary Growth Process of High-Slica SSZ-13 Zeolite Membrane

WANG He-Li ^1,2 ,
ZHU Mei-Hua ¹ ,
WU Ting ¹ ,
ZHANG Fei ¹ ,
WU Ya-Fen ³ ,
CHEN Xiang-Shu ^1,,

1.
Institute of Advanced Materials, State-Province Joint Engineering Laboratory of Zeolite Membrane Materials, College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, China
2.
Energy Institute, Jiangxi Academy of Sciences, Nanchang 330096, China
3.
Jiangxi University of Traditional Cinese Medicine, Nanchang 330004, China

Corresponding author: CHEN Xiang-Shu, cxs66cn@jxnu.edu.cn
Received Date: 11 December 2019
Revised Date: 2 April 2020

Figures(8)

High-silica SSZ-13 zeolite membranes were prepared on tubular mullite supports using a diluted organic template gel composition to investigate the hydrothermal growth process. Membranes and powders at the bottom of autoclave were characterized after secondary growth from 2 to 72 h at 433 K, and the XRD patterns show SSZ-13 characteristic peaks appeared in the membranes and powders simultaneously after 6 h. The size of zeolite crystals in the powder was almost the same when the synthesis time delayed. The SSZ-13 membrane synthesized at 433 K and 72 h had a CO₂ permeance of 2.08×10^-7 mol·m^-2·s^-1·Pa^-1 with an ideal selectivity of CO₂/CH₄ of 24 at 298 K and 0.4 MPa. The possible growth process of SSZ-13 zeolite membrane was proposed with the seeds coated on supports dissolved and formed numerous orderly structure units in the gel firstly, inducing SSZ-13 zeolite crystals generated and grew rapidly, the crystals deposited on the supports, grew up and intergrew for limited space to from a defectfree layer.
- SSZ-13 zeolite membrane,
- hydrothermal secondary growth,
- process,
- gas separation
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