Citation: LI Yu-Ling, ZHAO Yue, SUN Wei-Yin. Two Zn(Ⅱ) and Cd(Ⅱ) Metal-Organic Frameworks with Mixed Ligands: Synthesis, Structure, Sorption and Luminescent Properties[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(6): 1176-1184. doi: 10.11862/CJIC.2020.131 shu

Two Zn(Ⅱ) and Cd(Ⅱ) Metal-Organic Frameworks with Mixed Ligands: Synthesis, Structure, Sorption and Luminescent Properties

LI Yu-Ling ^1,2 ,
ZHAO Yue ^1,, ,
SUN Wei-Yin ¹

1.
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China
2.
School of Chemical Engineering and Food Science, Zhengzhou University of Technology, Zhengzhou 450044, China

Corresponding author: ZHAO Yue, zhaoyue@nju.edu.cn
Received Date: 14 March 2020
Revised Date: 14 April 2020

Figures(8)

Two new metal-organic frameworks (MOFs) [Cd₃(tib)₂(BPT)₂(H₂O)₂]·DMA·6H₂O (1) and [Zn₂(tib)(HBTB)₂(H₂O)]·2H₂O (2) (tib=1, 3, 5-tris(1-imidazolyl)benzene, H₃BPT=biphenyl-3, 4', 5-tricarboxylic acid, H₃BTB=4, 4', 4″-benzene-1, 3, 5-triyl-tribenzoic acid, DMA=N, N-dimethylacetamide) were synthesized and characterized. Complex 1 is a 4-nodal three-dimensional (3D) framework with point symbol {8³}₄{8⁵·12}{8⁶}₂, while 2 is a two-dimensional (2D) network to be joined together by hydrogen bonds to generate a 3D supramolecular structure. Gas/vapor adsorption and luminescence behavior of the two complexes were studied. It is meaningful that 1 and 2 can selectively adsorb CO₂ over N₂, and MeOH over EtOH. Furthermore, 1 can selectively detect acetone through a fluorescence quenching mechanism in the organic solvents including MeOH, EtOH, 2-PA, CH₃CN, DMF, DMA, THF, CHCl₃, CH₂Cl₂ and acetone.
- Zn(Ⅱ) and Cd(Ⅱ) MOFs,
- sorption properties,
- luminescent properties
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