Citation: Bhavna Sharma, XUE Zi-Ling. Formation of Zirconium Chloride Guanidinate Complexes from the Reaction of their Amide Analog with CCl₄[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(6): 1157-1162. doi: 10.11862/CJIC.2020.129 shu

Formation of Zirconium Chloride Guanidinate Complexes from the Reaction of their Amide Analog with CCl₄

Bhavna Sharma ,
XUE Zi-Ling ^,

Department of Chemistry, the University of Tennessee, Knoxville, Tennessee 37996, USA

Corresponding author: XUE Zi-Ling, xue@utk.edu
Received Date: 28 February 2020
Revised Date: 5 April 2020

Figures(4)

Reaction of CCl₄ with zirconium amide guanidinate Zr(NMe₂)₂ [ⁱPrNC(NMe₂)NⁱPr]₂ (1) has been found to give ZrCl(NMe₂) [ⁱPrNC(NMe₂)NⁱPr]₂ (2) as an intermediate and later ZrCl₂ [ⁱPrNC(NMe₂)NⁱPr]₂ (3). The reaction is likely radical in nature. Complex 2 has been independently prepared from the reaction of ZrCl(NMe₂)₃ with diisopropylcarbodiimide, ⁱPr-N=C=N-ⁱPr, and characterized by nuclear magnetic resonance (NMR) and elemental analysis.
- zirconium,
- chlorine,
- amide complex
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沈阳化工大学材料科学与工程学院沈阳 110142

Formation of Zirconium Chloride Guanidinate Complexes from the Reaction of their Amide Analog with CCl4

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通讯作者: 陈斌, bchen63@163.com

Formation of Zirconium Chloride Guanidinate Complexes from the Reaction of their Amide Analog with CCl₄