Citation: MENG Liu-Li, CHENG Hong-Tao, XUE Dong-Xu, WANG Qian, BAI Jun-Feng. Synthesis and Selective CO₂ Adsorption of a rtl-MOF Based upon 5-(3-Amino-pyridin-4-yl)-isophthalic Acid and [Cu₂(COO)₄]-Paddlewheel Unit[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(6): 1098-1104. doi: 10.11862/CJIC.2020.120 shu

Synthesis and Selective CO₂ Adsorption of a rtl-MOF Based upon 5-(3-Amino-pyridin-4-yl)-isophthalic Acid and [Cu₂(COO)₄]-Paddlewheel Unit

1.
Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry & Chemical Engineering, Shaanxi Normal University, Xi'an 710062, China
2.
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China

Corresponding author: WANG Qian, wangq@snnu.edu.cn BAI Jun-Feng, bjunfeng@snnu.edu.cn; bjunfeng@nju.edu.cn
Received Date: 10 January 2020
Revised Date: 26 March 2020

Figures(5)

Based upon a new ligand of 5-(3-amino-pyridin-4-yl)-isophthalic acid (NH₂-H₂L₁), the NH₂-functionalized pillar-layer rtl-MOF, SNNU-Bai65, has been successfully designed and synthesized. With the polar amino group decorating the pore surface and partitioning the pore channel, activated SNNU-Bai65 exhibits more highly selective CO₂ adsorption over N₂ and CH₄ than the parent MOF, SYSU.
- amino-functionalization,
- rtl-MOF,
- selective CO₂ adsorption
1. [1]
  Furukawa H, Cordova K E, O'Keeffe M, et al. Science, 2013, 341:1230444 doi: 10.1126/science.1230444
2. [2]
  Lu W G, Wei Z W, Zhou H C, et al. Chem. Soc. Rev., 2014, 43:5561-5593 doi: 10.1039/C4CS00003J
3. [3]
  Trickett C A, Helal A, Al-Maythalony B A, et al. Nat. Rev. Mater., 2017, 2:17045 doi: 10.1038/natrevmats.2017.45
4. [4]
  Rungtaweevoranit B, Diercks C S, Kalmutzki M J, et al. Faraday Discuss., 2017, 201:9-45 doi: 10.1039/C7FD00160F
5. [5]
  Sumida K, Rogow D L, Mason J A, et al. Chem. Rev., 2012, 112:724-781 doi: 10.1021/cr2003272
6. [6]
  Zhang Z, Yao Z Z, Xiang S, et al. Energy Environ. Sci., 2014, 7:2868-2899 doi: 10.1039/C4EE00143E
7. [7]
  Duan J, Zhang Q, Wang S, et al. Inorg. Chem. Front., 2018, 5:1780-1786 doi: 10.1039/C8QI00240A
8. [8]
  Ding M, Flaig R W, Jiang H L, et al. Chem. Soc. Rev., 2019, 48:2783-2828 doi: 10.1039/C8CS00829A
9. [9]
  Jiao L, Seow J Y R, Skinner W S, et al. Mater. Today, 2019, 27:43-68 doi: 10.1016/j.mattod.2018.10.038
10. [10]
  Duan J, Li Y, Pan Y, et al. Coord. Chem. Rev., 2019, 395:25-45 doi: 10.1016/j.ccr.2019.05.018
11. [11]
  Dong Q, Guo Y, Cao H, et al. ACS Appl. Mater. Interfaces, 2020, 12:3764-3772 doi: 10.1021/acsami.9b20623
12. [12]
  Duan J, Higuchi M, Zheng J, et al. J. Am. Chem. Soc., 2017, 139:11576-11583 doi: 10.1021/jacs.7b05702
13. [13]
  He Y, Chen F, Li B, et al. Coord. Chem. Rev., 2018, 373:167-198 doi: 10.1016/j.ccr.2017.10.002
14. [14]
  Li P Z, Wang X J, Zhao Y. Coord. Chem. Rev., 2019, 380:484-518 doi: 10.1016/j.ccr.2018.11.006
15. [15]
  Lin R B, Xiang S, Li B, et al. Coord. Chem. Rev., 2019, 384:21-36 doi: 10.1016/j.ccr.2019.01.009
16. [16]
  Ali Akbar Razavi S, Morsali A. Coord. Chem. Rev., 2019, 399:213023 doi: 10.1016/j.ccr.2019.213023
17. [17]
  Cui Y, Li B, He H, et al. Acc. Chem. Res., 2016, 49:483-493 doi: 10.1021/acs.accounts.5b00530
18. [18]
  Benson O, Silva I da, Argent S P, et al. J. Am. Chem. Soc., 2016, 138:14828-14831 doi: 10.1021/jacs.6b08059
19. [19]
  Flaig R W, Osborn Popp T M, Fracaroli A M, et al. J. Am. Chem. Soc., 2017, 139:12125-12128 doi: 10.1021/jacs.7b06382
20. [20]
  Sumida K, Rogow D L, Mason J A, et al. Chem. Rev., 2011, 112:724-781
21. [21]
  Zhang Z, Zhao Y, Gong Q, et al. Chem. Commun., 2013, 49:653-661 doi: 10.1039/C2CC35561B
22. [22]
  Wang Q, Lu Z Y, Bai J F, et al. Chem. Commun., 2016, 52:443-452 doi: 10.1039/C5CC07751F
23. [23]
  Millward A R, Yaghi O M. J. Am. Chem. Soc., 2005, 127:17998-17999 doi: 10.1021/ja0570032
24. [24]
  Farrusseng D, Daniel C, Gaudillere C, et al. Langmuir, 2009, 25:7383-7388 doi: 10.1021/la900283t
25. [25]
  An J, Geib S J, Rosi N L, et al. J. Am. Chem. Soc., 2010, 132:38-39 doi: 10.1021/ja909169x
26. [26]
  Couck S, Denayer J F M, Baron G V, et al. J. Am. Chem. Soc., 2009, 131:6326-6327 doi: 10.1021/ja900555r
27. [27]
  Zhao Y, Wu H, Emge T J, et al. Chem. Eur. J., 2011, 17:5101-5109 doi: 10.1002/chem.201002818
28. [28]
  Colombo V, Montoro C, Maspero A, et al. J. Am. Chem. Soc., 2012, 134:12830-12843 doi: 10.1021/ja305267m
29. [29]
  Ryu U J, Kim S J, Lim H K, et al. Sci. Rep., 2017, 7:612 doi: 10.1038/s41598-017-00574-1
30. [30]
  Du L, Lu Z, Zheng K, et al. J. Am. Chem. Soc., 2012, 135:562-565
31. [31]
  Wang Q, Song X, Zhang M, et al. Cryst. Growth Des., 2016, 16:6156-6159 doi: 10.1021/acs.cgd.6b01265
32. [32]
  Wang Q, Jiang J, Zhang M, et al. Cryst. Growth Des., 2017, 17:16-18 doi: 10.1021/acs.cgd.6b01484
33. [33]
  Jiang J, Wang Q, Zhang M, et al. Cryst. Growth Des., 2017, 17:2223-2227 doi: 10.1021/acs.cgd.7b00206
34. [34]
  Xiang S, Huang J, Li L, et al. Inorg. Chem., 2011, 50:1743-1748 doi: 10.1021/ic102188v
35. [35]
  Sheldrick G M. Acta Crystallogr. Sect. A, 2008, A64:112
36. [36]
  Spek A L. J. Appl. Crystallogr., 2003, 36:7 doi: 10.1107/S0021889802022112
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Synthesis and Selective CO2 Adsorption of a rtl-MOF Based upon 5-(3-Amino-pyridin-4-yl)-isophthalic Acid and [Cu2(COO)4]-Paddlewheel Unit

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通讯作者: 陈斌, bchen63@163.com

Synthesis and Selective CO₂ Adsorption of a rtl-MOF Based upon 5-(3-Amino-pyridin-4-yl)-isophthalic Acid and [Cu₂(COO)₄]-Paddlewheel Unit