Citation: LI Ming-Li, ZHANG Xiu-Xiu, RAO Wen-Jun, WEI Zhen-Hong, WANG Ling-Yu, CAI Hu. Synthesis and Characterization of Two Organic-Inorganic Hybrid Copper(Ⅱ) Compounds with the Reversible Thermochromism[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(6): 1137-1142. doi: 10.11862/CJIC.2020.118 shu

Synthesis and Characterization of Two Organic-Inorganic Hybrid Copper(Ⅱ) Compounds with the Reversible Thermochromism

College of Chemistry, Nanchang University, Nanchang 330031, China

Corresponding author: WEI Zhen-Hong, weizh@ncu.edu.cn
Received Date: 19 February 2020
Revised Date: 1 April 2020

Figures(5)

Reactions of N, N-dimethyl-1, 5-diazabicyclo [3.2.1]octane iodide ([3.2.1-Me₂dabco]I₂) and 1-amino-1, 4-diazabicyclo [2.2.2]octane iodide ([2.2.2-NH₂dabco]I) with anhydrous copper chloride in concentrated HCl aqueous solution afforded two organicinorganic hybrid compounds [3.2.1-Me₂dabco] [CuCl₄] (1) and [2.2.2-NH₂dabco] [CuCl₄] (2), respectively. The single-crystal X-ray diffraction revealed that the inorganic component in compounds 1 and 2 was a distorted tetrahedral geometry [CuCl₄]^2-. Compounds 1 and 2 showed an intriguing reversible thermochromism with color change from yellow to red which may be derived from the deformation of [CuCl₄]^2- tetrahedron.
- 1, 4-Diazabicyclo[2.2.2]octane,
- copper chloride,
- thermochromism,
- organic-inorganic hybrid,
- crystal structure
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