Citation: TANG Shu-Xuan, ZHANG Li, RUAN Hua-Peng, ZHAO Yue, TAN Geng-Wen, WANG Xin-Ping. An Isolable Dinuclear Iron Hydride Radical Cation[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(6): 1131-1136. doi: 10.11862/CJIC.2020.115 shu

An Isolable Dinuclear Iron Hydride Radical Cation

1.
State Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210023, China
2.
Center of Materials Science and Engineering, Guangxi University of Science and Technology, Liuzhou, Guangxi 545006, China
3.
College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu 215123, China

Corresponding author: TAN Geng-Wen, gwtan@suda.edu.cn WANG Xin-Ping, xpwang@nju.edu
Received Date: 10 February 2020
Revised Date: 13 March 2020

Figures(5)

The dinuclear iron hydride radical cation salt cis-[Fe₂Cp₂(μ-H)(μ-PPh₂)(CO)₂]^·+[Al(OC(CF₃)₃)₄]^-(cis-1^·+[Al(OC(CF₃)₃)₄]^-) was isolated as a crystalline solid. It has been characterized by single crystal X-ray crystallography, electron paramagnetic resonance (EPR), infrared, and UV-Vis spectroscopy, in conjunction with density functional theory (DFT) calculations. EPR and DFT calculation studies reveal that the spin density of the radical is mainly equally located at both of the iron atoms.
- transition metal hydride,
- radical cations,
- iron hydride radical cations,
- weakly coordinating anion
1. [1]
  (a) Hu Y, Shaw A P, Estes D P, et al. Chem. Rev., 2016, 116: 8427-8462
  (b)Wiedner E S, Chambers M B, Pitman C L, et al. Chem. Rev., 2016, 116: 8655-8692
  (c)Schilter D, Camara J M, Huynh M T, et al. Chem. Rev., 2016, 116: 8693-8749
2. [2]
  (a) Liu T F, Guo M Y, Orthaber A, et al. Nat. Chem., 2018, 10: 881-887
  (b)Huang T, Rountree E S, Traywick A P, et al. J. Am. Chem. Soc., 2018, 140: 14655-14669
  (c)Bourrez M, Steinmetz R, Ott S, et al. Nat. Chem., 2014, 7: 140-145
3. [3]
  (a) Ogata H, Lubitz W, Higuchi Y. Dalton Trans., 2009: 7577-7587
  (b)Frey M. ChemBioChem, 2002, 3: 153-160
  (c)Evans D J, Pickett C J. Chem. Soc. Rev., 2003, 32: 268-275
  (d)Lubitz W, Ogata H, Rüdiger O, et al. Chem. Rev., 2014, 114: 4081-4148
  (e)Hembre R T, Scott McQueen J, Day V W. J. Am. Chem. Soc., 1996, 118: 798-803
4. [4]
  Shaw A P, Ryland B L, Franklin M J, et al. J. Org. Chem., 2008, 73:9668-9674 doi: 10.1021/jo801928t
5. [5]
  (a) Ryan O B, Tilset M, Parker V D. J. Am. Chem. Soc., 1990, 112: 2618-2626
  (b)Roberts J A S, Appel A M, DuBois D L, et al. J. Am. Chem. Soc., 2011, 133: 14604-14613
6. [6]
  (a) Blaine C A, Ellis J E, Mann K R. Inorg. Chem., 1995, 34: 1552-1561
  (b)Roullier L, Lucas D, Mugnier Y, et al. J. Organomet. Chem., 1990, 396: C12-C16
7. [7]
  Baya M, Houghton J, Daran J C, et al. Chem. Eur. J., 2007, 13:5347-5359 doi: 10.1002/chem.200700293
8. [8]
  Klingler R J, Huffman J C, Kochi J K. J. Am. Chem. Soc., 1980, 102:208-216 doi: 10.1021/ja00521a033
9. [9]
  Ryan O B, Tilset M. J. Am. Chem. Soc., 1991, 113:9554-9561 doi: 10.1021/ja00025a020
10. [10]
  Eberhart M S, Norton J R, Zuzek A, et al. J. Am. Chem. Soc., 2013, 135:17262-17265 doi: 10.1021/ja408925m
11. [11]
  Bianchini C, Masi D, Mealli C, et al. Gazz. Chim. Ital., 1986, 116:201-206
12. [12]
  (a) Hamor P, Toupet L, Hamon J R, et al. Organometallics, 1992, 11: 1429-1431
  (b)Tilset M, Fjeldahl I, Hamon J R, et al. J. Am. Chem. Soc., 2001, 123: 9984-10000
  (c)Zhang F J, Jia J, Dong S L, et al. Organometallics, 2016, 35: 1151-1159
  (d)Yu X, Tung C H, Wang W G, et al. Organometallics, 2017, 36: 2245-2253
13. [13]
  Nakazawa H, Itazaki M. Iron Catalysis: Fundamentals and Applications. Plietker B, Ed., Berlin, Heidelberg: Springer-Verlag, 2011: 27-81
14. [14]
  (a) Volbeda A, Charon M H, Piras C, et al. Nature, 1995, 373: 580-587
  (b)Fontecilla-Camps J C, Volbeda A, Cavazza C, et al. Chem. Rev., 2007, 107: 4273-4303
15. [15]
  Liu Y C, Chu K T, Huang Y L, et al. ACS Catal., 2016, 6:2559-2576 doi: 10.1021/acscatal.5b02646
16. [16]
  (a) Bianchini C, Laschi F, Peruzzini M, et al. Inorg. Chem., 1990, 29: 3394-3402
  (b)Alvarez C M, Esther García M, Ruiz M A, et al. Organometallics, 2004, 23: 4750-4758
  (c)Jiménez-Tenorio M, Carmen Puerta M, Valerga P. Organometallics, 1994, 13: 3330-3337
  (d)Gargano M, Giannoccaro P, Rossi M, et al. J. Chem. Soc. Dalton Trans., 1975: 9-12
17. [17]
  (a) Zheng X, Wang X Y, Zhang Z C, et al. Angew. Chem. Int. Ed., 2015, 54: 9084-9087
  (b)Wang W Q, Wang X Y, Zhang Z C, et al. Chem. Commun., 2015, 51: 8410-8413
  (c)Li S Y, Wang X Y, Zhang Z C, et al. Dalton Trans., 2015, 44: 19754-19757
  (d)Zheng X, Zhang Z C, Tan G W, et al. Inorg. Chem., 2016, 55: 1008-1010
  (e)Wang W Q, Li J, Yin L, et al. J. Am. Chem. Soc., 2017, 139: 12069-12075
  (f)Tan G W, Wang X P. Chin. J. Chem., 2018, 36: 573-586
18. [18]
  Krossing I. Chem. Eur. J., 2001, 7:490-502 doi: 10.1002/1521-3765(20010119)7:2<490::AID-CHEM490>3.0.CO;2-I
19. [19]
  Sheldrick G M. SHELX-2018, Program for Crystal Structure Refinement, University of Göttingen, Germany, 2018.
20. [20]
  Decken A, Craig C D, Bottomley F. Acta Crystallogr. Sect. E, 2004, E60:m1284-m1285
21. [21]
  Frisch M J, Trucks G W, Schlegel H B, et al. Gaussian 09, Revision B.01, Gaussian, Inc., Wallingford CT, 2010.
1. [1]
  Wei Zhou , Xi Chen , Lin Lu , Xian-Rong Song , Mu-Jia Luo , Qiang Xiao . Recent advances in electrocatalytic generation of indole-derived radical cations and their applications in organic synthesis. Chinese Chemical Letters, 2024, 35(4): 108902-. doi: 10.1016/j.cclet.2023.108902
2. [2]
  Jing JIN , Zhuming GUO , Zhiyin XIAO , Xiujuan JIANG , Yi HE , Xiaoming LIU . Tuning the stability and cytotoxicity of fac-[Fe(CO)₃I₃]^- anion by its counter ions: From aminiums to inorganic cations. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 991-1004. doi: 10.11862/CJIC.20230458
3. [3]
  Jingtai Bi , Yupeng Cheng , Mengmeng Sun , Xiaofu Guo , Shizhao Wang , Yingying Zhao . Efficient and selective photocatalytic nitrite reduction to N₂ through CO₂ anion radical by eco-friendly tartaric acid activation. Chinese Chemical Letters, 2024, 35(11): 109639-. doi: 10.1016/j.cclet.2024.109639
4. [4]
  Zhengzhong Zhu , Shaojun Hu , Zhi Liu , Lipeng Zhou , Chongbin Tian , Qingfu Sun . A cationic radical lanthanide organic tetrahedron with remarkable coordination enhanced radical stability. Chinese Chemical Letters, 2025, 36(2): 109641-. doi: 10.1016/j.cclet.2024.109641
5. [5]
  Huaixiang Yang , Miao-Miao Li , Aijun Zhang , Jiefei Guo , Yongqi Yu , Wei Ding . Visible-light-induced photocatalyst- and metal-free radical phosphinoyloximation of alkenes with tert-butyl nitrite as bifunctional reagent. Chinese Chemical Letters, 2025, 36(3): 110425-. doi: 10.1016/j.cclet.2024.110425
6. [6]
  Jindian Duan , Xiaojuan Ding , Pui Ying Choy , Binyan Xu , Luchao Li , Hong Qin , Zheng Fang , Fuk Yee Kwong , Kai Guo . Oxidative spirolactonisation for modular access of γ-spirolactones via a radical tandem annulation pathway. Chinese Chemical Letters, 2024, 35(10): 109565-. doi: 10.1016/j.cclet.2024.109565
7. [7]
  Xiao-Bo Liu , Ren-Ming Liu , Xiao-Di Bao , Hua-Jian Xu , Qi Zhang , Yu-Feng Liang . Nickel-catalyzed reductive formylation of aryl halides via formyl radical. Chinese Chemical Letters, 2024, 35(12): 109783-. doi: 10.1016/j.cclet.2024.109783
8. [8]
  Honglin Gao , Chunlin Yuan , Hongyu Chen , Aiyi Dong , Pan Gao , Guangjin Hou . Surface gallium hydride on Ga2O3 polymorphs: A comparative solid-state NMR study. Chinese Journal of Structural Chemistry, 2025, 44(4): 100561-100561. doi: 10.1016/j.cjsc.2025.100561
9. [9]
  Ziyi Liu , Feifei Guo , Tingting Cao , Youxuan Sun , Xutang Tao , Zeliang Gao . High thermal conductivity in Ga2TeO6 crystals: Synergistic effects of rigid polyhedral frameworks and stereochemically inert cations. Chinese Journal of Structural Chemistry, 2025, 44(4): 100544-100544. doi: 10.1016/j.cjsc.2025.100544
10. [10]
  Shuai Li , Liuting Zhang , Fuying Wu , Yiqun Jiang , Xuebin Yu . Efficient catalysis of FeNiCu-based multi-site alloys on magnesium-hydride for solid-state hydrogen storage. Chinese Chemical Letters, 2025, 36(1): 109566-. doi: 10.1016/j.cclet.2024.109566
11. [11]
  Jing-Qi Tao , Shuai Liu , Tian-Yu Zhang , Hong Xin , Xu Yang , Xin-Hua Duan , Li-Na Guo . Photoinduced copper-catalyzed alkoxyl radical-triggered ring-expansion/aminocarbonylation cascade. Chinese Chemical Letters, 2024, 35(6): 109263-. doi: 10.1016/j.cclet.2023.109263
12. [12]
  Yu-Yu Tan , Lin-Heng He , Wei-Min He . Copper-mediated assembly of SO₂F group via radical fluorine-atom transfer strategy. Chinese Chemical Letters, 2024, 35(9): 109986-. doi: 10.1016/j.cclet.2024.109986
13. [13]
  Yuhan Liu , Jingyang Zhang , Gongming Yang , Jian Wang . Highly enantioselective carbene-catalyzed δ-lactonization via radical relay cross-coupling. Chinese Chemical Letters, 2025, 36(1): 109790-. doi: 10.1016/j.cclet.2024.109790
14. [14]
  Xiaoling WANG , Hongwu ZHANG , Daofu LIU . Synthesis, structure, and magnetic property of a cobalt(Ⅱ) complex based on pyridyl-substituted imino nitroxide radical. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 407-412. doi: 10.11862/CJIC.20240214
15. [15]
  Yaxuan Jin , Chao Zhang , Guigang Zhang . Atomically dispersed low-valent Au on poly(heptazine imide) boosts photocatalytic hydroxyl radical production. Chinese Journal of Structural Chemistry, 2024, 43(12): 100414-100414. doi: 10.1016/j.cjsc.2024.100414
16. [16]
  Haining Peng , Huijun Liu , Chengzong Li , Yingfu Li , Qizhi Chen , Tao Li . Diluent modified weakly solvating electrolyte for fast-charging high-voltage lithium metal batteries. Chinese Chemical Letters, 2025, 36(1): 109556-. doi: 10.1016/j.cclet.2024.109556
17. [17]
  Qi Li , Zi-Lu Wang , Yun-He Xu . Copper-catalyzed 1,4-silylcyanation of 1,3-enynes: A silyl radical-initiated approach for synthesis of difunctionalized allenes. Chinese Chemical Letters, 2025, 36(3): 109991-. doi: 10.1016/j.cclet.2024.109991
18. [18]
  You Zhou , Li-Sheng Wang , Shuang-Gui Lei , Bo-Cheng Tang , Zhi-Cheng Yu , Xing Li , Yan-Dong Wu , Kai-Lu Zheng , An-Xin Wu . I₂-DMSO mediated tetra-functionalization of enaminones for the construction of novel furo[2′,3′:4,5]pyrimido[1,2-b]indazole skeletons via in situ capture of ketenimine cations. Chinese Chemical Letters, 2025, 36(1): 109799-. doi: 10.1016/j.cclet.2024.109799
19. [19]
  Shuo Li , Xinran Liu , Yongjie Zheng , Jun Ma , Shijie You , Heshan Zheng . Effective peroxydisulfate activation by CQDs-MnFe₂O₄@ZIF-8 catalyst for complementary degradation of bisphenol A by free radicals and non-radical pathways. Chinese Chemical Letters, 2024, 35(5): 108971-. doi: 10.1016/j.cclet.2023.108971
20. [20]
  Peng Wang , Jianjun Wang , Ni Song , Xin Zhou , Ming Li . Radical dehydroxymethylative fluorination of aliphatic primary alcohols and diverse functionalization of α-fluoroimides via BF₃·OEt₂-catalyzed C‒F bond activation. Chinese Chemical Letters, 2025, 36(1): 109748-. doi: 10.1016/j.cclet.2024.109748

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(1415)
HTML views(115)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142