Citation: LIU Cai-Ming, HAO Xiang. Fluorescence and Magnet Relaxation of 3d-4f Tetranuclear Cluster Complexes Based on Zn(Ⅱ) Schiff Base Building Block and 6-(Hydroxymethyl)pyridine-2-carboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(6): 1105-1112. doi: 10.11862/CJIC.2020.109 shu

Fluorescence and Magnet Relaxation of 3d-4f Tetranuclear Cluster Complexes Based on Zn(Ⅱ) Schiff Base Building Block and 6-(Hydroxymethyl)pyridine-2-carboxylic Acid

LIU Cai-Ming ^, ,
HAO Xiang

Beijing National Laboratory for Molecular Sciences, Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China

Corresponding author: LIU Cai-Ming, cmliu@iccas.ac.cn
Received Date: 30 December 2019
Revised Date: 13 March 2020

Figures(5)

Two new 3d-4f tetranuclear cluster complexes, [Zn₂Ln₂(salen)₂(CO₂PyCH₂O)₂(MeOH)₂](ClO₄)₂·2MeOH (Ln=Dy (1), Tb (2); H₂salen=N, N'-bis(3-methoxysalicylidene)-1, 3-diaminopropane; HCO₂PyCH₂OH=6-(hydroxymethyl)pyridine-2-carboxylic acid), have been prepared solvothermally using Zn(salen) as the building block and CO₂PyCH₂O^2- as the co-ligand. They are Zn-Ln₂-Zn cluster complexes. Magnetic measurements indicate ferro-magnetic interactions between lanthanide(Ⅲ) ions. The Zn₂Dy₂ complex 1 shows magnet relaxation under a 2 000 Oe dc field, while the Zn₂Tb₂ complex 2 displays both field-induced magnet relaxation and fluorescence properties.
- 3d-4f cluster complex,
- crystal structure,
- fluorescence,
- magnetic properties
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