Citation: MA Yu-Hua, AINIWA·Munire, ZHU En-Quan, SU Zhi. Hierarchically Porous Nanosized Red Phosphorus with Enhanced Photo-Oxidation and Photo-Reduction Activities[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(5): 949-957. doi: 10.11862/CJIC.2020.106 shu

Hierarchically Porous Nanosized Red Phosphorus with Enhanced Photo-Oxidation and Photo-Reduction Activities

College of Chemistry and Chemical Engineering, Xinjiang Normal University, Urumqi, 830054, China

Corresponding author: MA Yu-Hua, 15199141253@163.com SU Zhi, suzhixj@sina.com

Received Date: 2 December 2019
Revised Date: 10 March 2020

Figures(5)

The as-prepared red phosphorus showed a well-defined complicated porous and nano-sized structure, and the uppermost photocatalytic activity for the hydrothermal treatment 24 h red phosphorus (H-RP24h). The rate constants of the H-RP24h photo-oxidation of rhodamine B (RhB) and photo-reduction of Cr(Ⅵ) were 9.2×10^-2 and 3.4×10^-2 min^-1, 23 and 26 times superior to those of commercial red phosphorus, respectively. Further studies demonstrated that hydrothermal treatment effectively decreased the size of red phosphorus, enhanced light response, and accelerated the detachment of photogenerated electrons and holes (h⁺), thus increased its photocatalytic activity. It was found that the core reactive species in the photodegradation process were h⁺ and superoxide ion radicals.
- red phosphorus,
- photo-oxidation,
- photo-reduction,
- photocatalysis,
- hydrothermal synthesis
1. [1]
  Li H L, Chen Y J, Zhou W, et al. Appl. Surf. Sci., 2019, 470:631-638 doi: 10.1016/j.apsusc.2018.11.183
2. [2]
  Yuan X J, Floresyona D, Aubert P H, et al. Appl. Catal. B, 2019, 242:284-292 doi: 10.1016/j.apcatb.2018.10.002
3. [3]
  Ma J F, Liu Q, Zhu L F, et al. Appl. Catal. B, 2016, 182:26-32 doi: 10.1016/j.apcatb.2015.09.004
4. [4]
  Chan D K L, Yu J C, Li Y C, et al. J. Environ. Sci., 2017, 60:91-97 doi: 10.1016/j.jes.2016.11.025
5. [5]
  Shen Z R, Sun S T, Wang W J, et al. J. Mater. Chem. A, 2015, 3:3285-3288 doi: 10.1039/C4TA06871H
6. [6]
  Lin T, Jia W J, Ming Z G, et al. J. Hazard. Mater., 2016, 306:295-304 doi: 10.1016/j.jhazmat.2015.12.044
7. [7]
  Deng Y C, Tang L, Zeng G M, et al. Appl. Surf. Sci., 2016, 387:882-893 doi: 10.1016/j.apsusc.2016.07.026
8. [8]
  Pu S Y, Hou Y Q, Chen H Y, et al. Catalysts, 2018, 8:251-268 doi: 10.3390/catal8060251
9. [9]
  Chen F, Yang Q, Wang Y L, et al. Chem. Eng. J., 2018, 348:157-170 doi: 10.1016/j.cej.2018.04.170
10. [10]
  Qiu J H, Zhang X F, Zhang X G, et al. J. Hazard. Mater., 2018, 349:234-241 doi: 10.1016/j.jhazmat.2018.02.009
11. [11]
  Zhang G Q, Chen D Y, Li N, et al. Appl. Catal. B, 2018, 232:164-174 doi: 10.1016/j.apcatb.2018.03.017
12. [12]
  Wang T Q, Jiang Z F, An T C, et al. Environ. Sci. Technol., 2018, 52:4774-4784 doi: 10.1021/acs.est.7b06537
13. [13]
  Xia D H, He H J W, Liu H D, et al. Appl. Catal. B, 2018, 238:70-81 doi: 10.1016/j.apcatb.2018.07.003
14. [14]
  Wang W J, Li G Y, An T C, et al. Appl. Catal. B, 2018, 238:126-135 doi: 10.1016/j.apcatb.2018.07.004
15. [15]
  Yu Z B, Chen X Q, Kang X D, et al. Adv. Mater., 2018, 30:1706259-1706266 doi: 10.1002/adma.201706259
16. [16]
  Karthik K, Dhanuskodi S, Gobinath C, et al. J. Mater. Sci.:Mater. Electron., 2018, 29:5459-5471 doi: 10.1007/s10854-017-8513-y
17. [17]
  Leow W R, Yu J C, Li Y B, et al. Angew. Chem. Int. Ed., 2018, 57:9780-9784 doi: 10.1002/anie.201805395
18. [18]
  Jin J, Yu J G, Guo D P, et al. Small, 2015, 11:5262-5271 doi: 10.1002/smll.201500926
19. [19]
  Strataki N, Antoniadou M, Dracopoulos V, et al. Catal. Today, 2010, 151:53-57 doi: 10.1016/j.cattod.2010.03.036
20. [20]
  Xu J, Cao X J. Chem. Eng. J., 2015, 260:642-648 doi: 10.1016/j.cej.2014.07.046
21. [21]
  Bai X, Wan J, Jia J, et al. Mater. Lett., 2018, 222:187-191 doi: 10.1016/j.matlet.2018.04.001
22. [22]
  Hu S Z, Ma L, You J G, et al. RSC Adv., 2014, 4:21657-21663 doi: 10.1039/C4RA02284J
23. [23]
  Pirhashemi M, HabibiYangjeh A, Rahim Pouran S. J. Ind. Eng. Chem., 2018, 62:1-25 doi: 10.1016/j.jiec.2018.01.012
24. [24]
  Ren Z P, Li D H, Xue Q, et al. Catal. Today, 2020, 340:115-120 doi: 10.1016/j.cattod.2018.09.029
25. [25]
  Liu G, Yin L C, Niu P, et al. Angew. Chem. Int. Ed., 2013, 52:6242-6245 doi: 10.1002/anie.201302238
26. [26]
  Kang Z H, Tsang C H A, Wong N B, et al. J. Am. Chem. Soc., 2007, 129:12090-12091 doi: 10.1021/ja075184x
27. [27]
  Chiou Y D, Hsu Y J. Appl. Catal. B, 2011, 105:211-219 doi: 10.1016/j.apcatb.2011.04.019
28. [28]
  Peng W C, Li X Y. Nano Res., 2013, 6:286-292 doi: 10.1007/s12274-013-0306-x
29. [29]
  Wang F, Ng W K H, Yu J C, et al. Appl. Catal. B, 2012, 111-112:409-414 doi: 10.1016/j.apcatb.2011.10.028
30. [30]
  Jing L, Zhu R X, Phillips D L, et al. Adv. Funct. Mater., 2017, 27:1703484-1703492 doi: 10.1002/adfm.201703484
31. [31]
  Pfitzner A. Angew. Chem. Int. Ed., 2006, 45:699-700 doi: 10.1002/anie.200503603
32. [32]
  Ansari S A, Cho M H. Sci. Rep., 2016, 6:25405-25415 doi: 10.1038/srep25405
33. [33]
  Wang F, Li C H, Li Y C, et al. Appl. Catal. B, 2012, 119-120:267-272 doi: 10.1016/j.apcatb.2012.03.011
34. [34]
  Shi Z S, Dong X F, Dang H F. Int. J. Hydrogen Energy, 2016, 41:5908-5915 doi: 10.1016/j.ijhydene.2016.02.146
35. [35]
  Dang H F, Dong X F, Dong Y C, et al. RSC Adv., 2014, 4:44823-44826 doi: 10.1039/C4RA06867J
36. [36]
  Li W B, Zhang Y P, Tian G D, et al. J. Mol. Catal. A:Chem., 2016, 423:356-364 doi: 10.1016/j.molcata.2016.07.039
37. [37]
  Li W B, Yue J G, Hua F X, et al. Mater. Res. Bull., 2015, 70:13-19 doi: 10.1016/j.materresbull.2015.04.009
38. [38]
  Ma Y H, Tuniyazi D L X, Ainiwa M N R, et al. Mater. Lett., 2020, 262:127023-127026 doi: 10.1016/j.matlet.2019.127023
39. [39]
  Wang J, Zhang D K, Deng J K, et al. J. Colloid Interface Sci., 2018, 516:215-223 doi: 10.1016/j.jcis.2018.01.003
40. [40]
  Xu D F, Cheng B, Cao S W, et al. Appl. Catal. B, 2015, 164:380-388 doi: 10.1016/j.apcatb.2014.09.051
41. [41]
  Yang S B, Xu D B, Chen B Y, et al. Appl. Surf. Sci., 2016, 383:214-221 doi: 10.1016/j.apsusc.2016.04.142
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