Citation: FENG Zhe, GAO Jian-Fei, LI Gang, ZHU Dun-Ru. Syntheses and Crystal Structures of Two Copper Complexes Based on Quinolyl and Pyridyl Substituted Triaryltriazoles[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(6): 1169-1175. doi: 10.11862/CJIC.2020.100 shu

Syntheses and Crystal Structures of Two Copper Complexes Based on Quinolyl and Pyridyl Substituted Triaryltriazoles

FENG Zhe ¹ ,
GAO Jian-Fei ¹ ,
LI Gang ¹ ,
ZHU Dun-Ru ^1,2,,

1.
College of Chemical Engineering, State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 211816, China
2.
State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210023, China

Corresponding author: ZHU Dun-Ru, zhudr@njtech.edu.cn
Received Date: 22 January 2020
Revised Date: 7 March 2020

Figures(4)

Two new copper(Ⅱ) complexes, trans-[Cu(L¹)₂(NO₃)(H₂O)]NO₃·H₂O (1) and trans-[Cu(L²)₂(NO₃)(H₂O)]NO₃·H₂O (2) (L¹=3-(2-pyridyl)-4-(p-methylphenyl)-5-(2-quinolyl)-1, 2, 4-triazole, L²=3-(2-pyridyl)-4-(p-fluorophenyl)-5-(2-quinolyl)-1, 2, 4-triazole), were synthesized and characterized by FT-IR, elemental analyses and single-crystal X-ray crystallography. Both 1 and 2 crystallize in triclinic system with space group P1. X-ray crystallography analysis reveals that the copper ion in 1 and 2 lies in a distorted octahedral environment [CuN₄O₂] with one nitrate and one water molecule, respectively in the trans-position. The L¹ or L² ligand coordinates with Cu(Ⅱ) via one pyridine N atom and one triazole N atom, while the quinolyl group does not take part in coordination. In 1 and 2 there are some intermolecular O-H…O, C-H…O and C-H…N hydrogen bonds and C-H…π interactions, connecting the mononuclear complexes to form a 3D framework.
- synthesis,
- Cu(Ⅱ) complex,
- crystal structure,
- triaryltriazole
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