Citation: LI Rui, SUN Xiao-Gang, ZOU Jing-Yi, HE Qiang. NMAP Interlayer for Inhibiting Shuttle Effect of Lithium-Sulfur Battery[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(4): 673-680. doi: 10.11862/CJIC.2020.088 shu

NMAP Interlayer for Inhibiting Shuttle Effect of Lithium-Sulfur Battery

School of Mechantronics Engineering, Nanchang University, Nanchang 330031, China

Corresponding author: SUN Xiao-Gang, xiaogangsun@163.com
Received Date: 12 September 2019
Revised Date: 26 February 2020

Figures(7)

Nano-NiO was prepared by hydrothermal synthesis and cross-linked with multi-walled carbon nanotubes (MWCNTs) and aramid paper (AP) to form a novel composite interlayer (NMAP). The NMAP interlayer has a three-dimensional porous structure, which not only reduces the loss of active materials, but also captures soluble polysulfides; NMAP material has strong chemical adsorption capacity for adsorbing polysulfide. The morphology and structure of the composite interlayer were observed by transmission electron microscopy (TEM), scanning electron microscopy (SEM), X-ray diffraction (XRD). The electrochemical test results showed that the first discharge capacity of electrode with NMAP interlayer reached 1 437 mAh·g^-1 at a rate of 0.05C, and the utilization rate of active material was as high as 85.8%. The specific discharge capacity still reached 668 mAh·g^-1 at 4C, and the coulomb efficiency remained at 99.1%, showing excellent magnification and cycling performance.
- lithium-sulfur batteries,
- shuttle effect,
- lithium polysulfides,
- carbon nanotube,
- interlayer
1. [1]
  Zhao Q, Zhu Q Z, An Y B, et al. Appl. Surf. Sci., 2018, 440:770-777 doi: 10.1016/j.apsusc.2018.01.162
2. [2]
  Luo L Y, Qin X Y, Wu J X, et al. J. Mater. Chem. A, 2018, 6(18):8612-8619 doi: 10.1039/C8TA01726C
3. [3]
  Yang K, Zhong L, Guan R, et al. Appl. Surf. Sci., 2018, 441:914-922 doi: 10.1016/j.apsusc.2018.02.108
4. [4]
  Yan L J, Luo N N, Kong W B, et al. J. Power Sources, 2018, 389:169-177 doi: 10.1016/j.jpowsour.2018.04.015
5. [5]
  Zhang A Y, Fang X, Shen C F, et al. Nano Res., 2018, 11(6):3340-3352 doi: 10.1007/s12274-017-1929-0
6. [6]
  Tang H, Yao S S, Xue S K, et al. Electrochim. Acta, 2018, 263:158-167 doi: 10.1016/j.electacta.2018.01.066
7. [7]
  Li Z, Ma Z L, Wang Y Y, et al. Sci. Bull., 2018, 63(3):169-175 doi: 10.1016/j.scib.2017.12.018
8. [8]
  Mikhaylik Y V, Akridge J R. J. Electrochem. Soc., 2004, 151(151):A1969-A1976
9. [9]
  Hofmann A F, Fronczek D N, Bessler W G. J. Power Sources, 2014, 259(259):300-310
10. [10]
  Singhal R, Chung S H, Manthiram A, et al. J. Mater. Chem. A, 2015, 3(8):4530-4538 doi: 10.1039/C4TA06511E
11. [11]
  Liu Y M, Qin X Y, Zhang S Q, et al. ACS Appl. Mater. Interfaces, 2018, 10(31):26264-26273 doi: 10.1021/acsami.8b07316
12. [12]
  Jayaprakash N, Shen J, Moganty S S, et al. Angew. Chem. Int. Ed., 2011, 50(26):5904-5908 doi: 10.1002/anie.201100637
13. [13]
  Xiang Y Y, Wang Z, Qiu W J, et al. J. Membr. Sci., 2018, 563:380-387 doi: 10.1016/j.memsci.2018.06.004
14. [14]
  Wang M X, Fan L S, Wu X, et al. J. Mater. Chem. A, 2017, 5(37):19613-19618 doi: 10.1039/C7TA04937D
15. [15]
  Yan X Y, Tong X L, Wang J, et al. J. Alloys Compd., 2013, 556:56-61 doi: 10.1016/j.jallcom.2012.12.124
16. [16]
  Guo J C, Xu Y H, Wang C S. Nano Lett., 2011, 11(10):4288-4294 doi: 10.1021/nl202297p
17. [17]
  Hu N N, Lv X S, Dai Y, et al. ACS Appl. Mater. Interfaces, 2018, 10(22):18665-18674 doi: 10.1021/acsami.8b03255
18. [18]
  Zhao M Q, Zhang Q, Huang J Q, et al. Nat. Commun., 2014, 5(5):3410
19. [19]
  Xiao Z B, Li Z L, Meng X P, et al. J. Mater. Chem. A, 2019, 7(40):22730-22743 doi: 10.1039/C9TA08600E
20. [20]
  Hencz L, Chen H, Ling H Y, et al. Nano-micro Lett., 2019, 11(1):17 doi: 10.1007/s40820-019-0249-1
21. [21]
  Hu X, Sun X, Yoo S J, et al. Nano Energy, 2019, 56:828-839 doi: 10.1016/j.nanoen.2018.11.081
22. [22]
  Wang J, Fang F, Yuan T, et al. ACS Appl. Mater. Interfaces, 2017, 9(4):3544-3553 doi: 10.1021/acsami.6b10807
23. [23]
  Cho H, Kim K, Park C M, et al. J. Power Sources, 2019, 410:25-30
24. [24]
  Wang K, Huang J G. Appl. Surf. Sci., 2019, 476:293-302 doi: 10.1016/j.apsusc.2019.01.094
25. [25]
  Qiu Z W, Nie Y Y, Sun X G, et al. J. Electron. Mater., 2018, 47(10):5850-5857 doi: 10.1007/s11664-018-6426-z
26. [26]
  Tang X N, Sun Z H, Yang H C, et al. J. Energy Chem., 2019, 31:119-124 doi: 10.1016/j.jechem.2018.06.001
27. [27]
  Hua W X, Yang Z, Nie H G, et al. ACS Nano, 2017, 11(2):2209-2218 doi: 10.1021/acsnano.6b08627
28. [28]
  Kim J H, Fu K, Choi J, et al. Chem. Commun., 2015, 51(71):13682-13685 doi: 10.1039/C5CC04103A
29. [29]
  Zeng P, Chen M F, Jiang S X, et al. ACS Appl. Mater. Interfaces, 2019, 11(25):22439-22448 doi: 10.1021/acsami.9b05874
30. [30]
  Salem H A, Babu U G, Rao C V, et al. J. Am. Chem. Soc., 2015, 137(36):11542 doi: 10.1021/jacs.5b04472
31. [31]
  Zu C X, Manthiram A. Adv. Energy Mater., 2013, 3(8):1008-1012 doi: 10.1002/aenm.201201080
32. [32]
  Xiao Z B, Yang Z, Wang L, et al. Adv. Mater., 2015, 27(18):2891-2898 doi: 10.1002/adma.201405637
33. [33]
  Zhou Z B, Xu Y H, Liu W G, et al. J. Alloy Compd., 2010, 493(1):636-639
34. [34]
  Cleland W W. Dithiothreitol. Biochemistry, 1964, 3(4):480-482 doi: 10.1021/bi00892a002
35. [35]
  Liang G M, Wu J X, Qin X Y, et al. ACS Appl. Mater. Interfaces, 2016, 8(35):23105-23113 doi: 10.1021/acsami.6b07487
36. [36]
  Li Y J, Zhan H, Liu S Q, et al. J. Power Sources, 2010, 195(9):2945-2949 doi: 10.1016/j.jpowsour.2009.11.004
37. [37]
  Liu M K, Yang Z B, Hao S, et al. Nano Res., 2016, 9(12):3735-3746 doi: 10.1007/s12274-016-1244-1
38. [38]
  Wang R, Li X, Liu L, et al. Electrochem. Commun., 2015, 60:70-73 doi: 10.1016/j.elecom.2015.08.003
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

NMAP Interlayer for Inhibiting Shuttle Effect of Lithium-Sulfur Battery

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com