Citation: SONG Cui, ZHAO Li-Hua, QI Ming-Ying, SUN Rong-Wei, ZHU Qian. Hydrothermal Preparation and Properties of Ag₃PO₄/HAP Composite Photocatalysts[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(3): 521-528. doi: 10.11862/CJIC.2020.067 shu

Hydrothermal Preparation and Properties of Ag₃PO₄/HAP Composite Photocatalysts

Marine College, Shandong University, Weihai, Shandong 264209, China

Corresponding author: ZHU Qian, qianzhu@sdu.edu.cn
Received Date: 31 August 2019
Revised Date: 9 January 2020

Figures(6)

High-purity hydroxyapatite (HAP) was prepared from oyster-shell waste by a hydrothermal method and was used as the carrier for Ag₃PO₄, resulting in the preparation of a nanorod-like Ag₃PO₄/HAP composite photocatalyst. Scanning electron microscopy (SEM), high-resolution transmission electron microscopy (TEM), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS) were used to characterize the prepared photocatalyst and to explore the effect of different preparation parameters on the catalytic activity of the photocatalyst toward the degradation of a methylene blue solution. The results shows that the 1:2-Ag₃PO₄/HAP catalyst exhibited the best performance, achieving 50% degradation in 10 min and complete degradation in 40 min. The 1:2-Ag₃PO₄/HAP catalyst was a highly efficient composite photocatalyst.
- oyster shell,
- silver phosphate,
- hydroxyapatite,
- photodegradation
1. [1]
  Akira F, Kenichi H. Nature, 1972, 238(5358):37-38 doi: 10.1038/238037a0
2. [2]
  Li Q, Guo B D, Yu J G, et al. J. Am. Chem. Soc., 2011, 133(28):10878-10884 doi: 10.1021/ja2025454
3. [3]
  Yi Z G, Ye J H, Kikugawa N, et al. Nat. Mater., 2010, 9(7):559-564 doi: 10.1038/nmat2780
4. [4]
  Bi Y P, Ouyang S X, Cao J Y, et al. Phys. Chem. Chem. Phys., 2011, 13(21):10071-10075 doi: 10.1039/c1cp20488b
5. [5]
  Yao W F, Bo Z, Huang C P, et al. J. Mater. Chem., 2012, 22(9):4050-4055 doi: 10.1039/c2jm14410g
6. [6]
  Teng W, Li X Y, Zhao Q D, et al. J. Mater. Chem., 2013, 1(32):9060-9068 doi: 10.1039/c3ta11254c
7. [7]
  Jiang X H, Xing Q J, Luo X B, et al. Appl. Catal. B, 2018, 228:29-38 doi: 10.1016/j.apcatb.2018.01.062
8. [8]
  Wei L, Wang M L, Xu C X, et al. Mater. Res. Bull., 2013, 48(1):106-113 doi: 10.1016/j.materresbull.2012.10.015
9. [9]
  Katsumata H, Sakai T, Suzuki T, et al. Ind. Eng. Chem. Res., 2014, 53(19):8018-8025 doi: 10.1021/ie5012036
10. [10]
  Bai J R, Lv W H, Xu H Y, et al. J. Nanosci. Nanotechnol., 2019, 19(9):5736-5742 doi: 10.1166/jnn.2019.16561
11. [11]
  Nie Y C, Yu F, Wang L C, et al. Appl. Catal. B, 2018, 227:312-321 doi: 10.1016/j.apcatb.2018.01.033
12. [12]
  Zhou G, Wu M F, Xing Q J, et al. Appl. Catal. B, 2018, 220:607-614 doi: 10.1016/j.apcatb.2017.08.086
13. [13]
  Wang D K, Ye P, Li K L, et al. Appl. Catal. B, 2020, 260:118182 doi: 10.1016/j.apcatb.2019.118182
14. [14]
  Shinger M I, Idris A M, Devaramani S, et al. J. Environ. Chem. Eng., 2017, 5(2):1526-1535 doi: 10.1016/j.jece.2017.02.032
15. [15]
  YAN Xin, HUI Xiao-Yan, GAO Qiang, et al. Chinese J. Inorg. Chem., 2017, 33(10):1782-1788 doi: 10.11862/CJIC.2017.212
16. [16]
  DENG Jun-Yang, WANG Jie, ZHU Si-Long, et al. Chinese J. Inorg. Chem., 2019, 35(6):955-964
17. [17]
  Chang Q, Meng X, Hu S L, et al. RSC Adv., 2017, 7(48):30191-30198 doi: 10.1039/C7RA04881E
18. [18]
  Grünert W, Brückner A, Hofmeister H, et al. J. Phys. Chem. B, 2004, 108(18):5709-5717 doi: 10.1021/jp049855e
19. [19]
  Zhang H, Wang G, Chen D, et al. Chem. Mater., 2008, 77(1):87-95
20. [20]
  Zhang X F, Chaimayo W, Yang C, et al. Surf. Coat. Technol., 2017, 325:39-45 doi: 10.1016/j.surfcoat.2017.06.013
21. [21]
  Cao J, Luo B D, Lin H L, et al. J. Hazard. Mater., 2012, 217-218:107-115 doi: 10.1016/j.jhazmat.2012.03.002
22. [22]
  Hu Z, Liu J C, Ge M. Mater. Sci. Semicond. Process., 2020, 105:104731-1043740 doi: 10.1016/j.mssp.2019.104731
23. [23]
  Feng B, Wu Z Y, Liu J S, et al. Appl. Catal. B, 2017, 206:242-251 doi: 10.1016/j.apcatb.2017.01.029
24. [24]
  Chai Y Y, Ding J, Wang L, et al. Appl. Catal. B, 2015, 179:29-36 doi: 10.1016/j.apcatb.2015.05.006
1. [1]
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2. [2]
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4. [4]
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7. [7]
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8. [8]
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9. [9]
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10. [10]
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11. [11]
  Le Han , Zhou Yuan , Bohan Li , Yuchi Zhang , Lin Yang , Yan Xu . Highly-stable cesium lead halide perovskite CsPbBr₃/CsPb₂Br₅ heteronanocrystals in zeolitic imidazolate framework-8 for antibiotic photodegradation. Chinese Chemical Letters, 2025, 36(6): 110349-. doi: 10.1016/j.cclet.2024.110349
12. [12]
  Wenya Jiang , Jianyu Wei , Kuan-Guan Liu . Atomically precise superatomic silver nanoclusters stabilized by O-donor ligands. Chinese Journal of Structural Chemistry, 2024, 43(9): 100371-100371. doi: 10.1016/j.cjsc.2024.100371
13. [13]
  Zhifeng CAI , Ying WU , Yanan LI , Guiyu MENG , Tianyu MIAO , Yihao ZHANG . Effective detection of malachite green by folic acid stabilized silver nanoclusters. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 983-993. doi: 10.11862/CJIC.20240394
14. [14]
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15. [15]
  Xinxiu Yan , Xizhe Huang , Yangyang Liu , Weishang Jia , Hualin Chen , Qi Yao , Tao Chen . Hyperbranched polyamidoamine protective layer with phosphate and carboxyl groups for dendrite-free Zn metal anodes. Chinese Chemical Letters, 2024, 35(10): 109426-. doi: 10.1016/j.cclet.2023.109426
16. [16]
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17. [17]
  Jiayao Li , Xinru Peng , Shiwei Yin , Changwei Wang , Yirong Mo . Metastability of π-π stacking between the closed-shell ions of like charges. Chinese Journal of Structural Chemistry, 2024, 43(5): 100213-100213. doi: 10.1016/j.cjsc.2023.100213
18. [18]
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19. [19]
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20. [20]
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Hydrothermal Preparation and Properties of Ag₃PO₄/HAP Composite Photocatalysts