Citation: JU Feng-Yang, LI Yun-Ping, LIU Guang-Zhen. Syntheses, Structures and Properties of Ni(Ⅱ)/Cd(Ⅱ)/Zn(Ⅱ) Complexes with Flexible Homophthalic Acid and Diimidazolyl-Type Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(2): 368-376. doi: 10.11862/CJIC.2020.044 shu

Syntheses, Structures and Properties of Ni(Ⅱ)/Cd(Ⅱ)/Zn(Ⅱ) Complexes with Flexible Homophthalic Acid and Diimidazolyl-Type Ligands

1.
School of Food and Drug, Luoyang Normal University, Luoyang, Henan 471934, China
2.
College of Chemistry and Chemical Engineering, Henan Key Laboratory of Function-Oriented Porous Materials, Luoyang Normal University, Luoyang, Henan 471934, China

Corresponding author: LIU Guang-Zhen, gzliuly@126.com
Received Date: 2 July 2019
Revised Date: 4 November 2019

Figures(6)

Based on flexible homophthalic acid (H₂hmph) and diimidazolyl-type ligands, three novel coordination polymers with the formulas determined as {[Ni₂(hmph)₂(bib)₂(H₂O)₂]·3H₂O}_n (1), [Cd(hmph)(bib)]_n (2) and {[Zn(hmph)(bip)]·H₂O}_n (3) (bib=1, 4-bis(1-imidazolyl)benzene; bip=3, 5-bis(1-imidazolyl)pyridine) have been solvothermally synthesized. Complex 1 displays a 2D mono-layer structure featuring Ni-carboxylate chains cross-linked further by bib co-ligands. Complex 2 exhibits a 2D bilayer structure containing double-stranded Cd-carboxylate chains bridged by bib co-ligands, wherein there are carboxyl-bridged dinuclear kernels. Complex 3 is double-stranded chain featuring Zn-carboxylate binuclear units extended further by bip co-ligands. TGA experiments show that all three complexes have high thermal stabilities. And the magetic data indicate there is typical ferromagnetic exchange coupling in complex 1. Furthermore, the fluorescent properties of both complexes 2 and 3 show significant blue-shift compared with the free ligands.
- homophthalic acid,
- diimidazolyl,
- coordination polymers,
- magnetic property,
- fluorescent property
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沈阳化工大学材料科学与工程学院沈阳 110142