Citation: WANG Qi-Bao, LI Xiang, WANG Hai-Ying, LU Wen-Xin, WANG Peng. Regulation of Ligand Scale on Structure and Photocatalytic Degradation Activity of Complex: from Zero-Dimensional to One-Dimensional Cu(Ⅱ) Complexes[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(2): 233-240. doi: 10.11862/CJIC.2020.043 shu

Regulation of Ligand Scale on Structure and Photocatalytic Degradation Activity of Complex: from Zero-Dimensional to One-Dimensional Cu(Ⅱ) Complexes

WANG Qi-Bao ¹ ,
LI Xiang ¹ ,
WANG Hai-Ying ² ,
LU Wen-Xin ^1,, ,
WANG Peng ^1,,

1.
College of Chemical and Environmental Engineering, Shandong University of Science and Technology, Qingdao, Shandong 266590, China
2.
College of Chemistry and Materials Science, Sichuan Normal University, Chengdu 610068, China

Corresponding author: LU Wen-Xin, lwx08lwx@126.com WANG Peng, pengwang@sdust.edu.cn
Received Date: 9 July 2019
Revised Date: 4 November 2019

Figures(7)

Bridged pyridine ligand 4-methyl-2, 6-bis(pyridin-3'-ylethynyl) aniline (L1) and an unreported ligand with smaller scale, 2, 6-bis(3'-pyridyl)-4-methylaniline (L2) were synthesized. Two complexes[Cu₂(L1)(OAc)₄]₂ (1, OAc^-=CH₃CO₂^-) and {[Cu₂(L2)(OAc)₄]·2CH₂Cl₂·CH₃CN}_n (2) were obtained using L1 or L2 and cupric acetate monohydrate (Cu(OAc)₂·H₂O) in mixed organic solvent at room temperature. The complexes 1 and 2 were characterized by X-ray single crystal diffraction, IR and elemental analysis. The structural research reveals that both the complexes 1 and 2 contain the dinuclear copper cluster of {Cu₂(OAc)₄}, but complex 1 has a "2+2" planar macrocycle structure in which L1 coordinated with the dinuclear copper clusters in a U-configuration and complex 2 has 1D chain structure where L2 connected the adjacent dinuclears in a Z-configuration. The structural difference between the two complexes is due to the different scale of the ligands L1 and L2, demonstrating the effect of the ligand scale in structural regulation. The fluorescence property of these two complexes were investigated, and it was confirmed that the introduction of copper quenched the fluorescence emission. The experiment of photocatalytic degradation of methylene blue (MB) proved that the macrocycle complex 1 has better catalytic activity than complex 2 with 1D chain structure and both of them are better than cupric acetate.
- bipyridine ligand,
- Cu(Ⅱ) complex,
- crystal structure,
- fluorescent properties,
- photocatalytic MB degradation
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