Citation: LI Yu, ZHAO Zhen-Yu, ZOU Xun-Zhong, FENG An-Sheng, GU Jin-Zhong. Syntheses, Crystal Structures, Luminescent and Magnetic Properties of 2D Manganese(Ⅱ) and Zinc(Ⅱ) Coordination Polymers Based on an Ether-Bridged Tetracarboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(2): 377-384. doi: 10.11862/CJIC.2020.042 shu

Syntheses, Crystal Structures, Luminescent and Magnetic Properties of 2D Manganese(Ⅱ) and Zinc(Ⅱ) Coordination Polymers Based on an Ether-Bridged Tetracarboxylic Acid

1.
Guangdong Research Center for Special Building Materials and Its Green Preparation Technology/Foshan Research Center for Special Functional Building Materials and Its Green Preparation Technology, Guangdong Industry Polytechnic, Guangzhou 510300, China
2.
School of Intelligent Manufacturing and Equipment, Shenzhen Institute of Information Technology, Shenzhen, Guangdong 518172, China
3.
College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China

Corresponding author: ZHAO Zhen-Yu, gujzh@lzu.edu.cn GU Jin-Zhong, yxpzzy01@163.com
Received Date: 26 July 2019
Revised Date: 6 November 2019

Figures(10)

Two 2D manganese(Ⅱ) and zinic(Ⅱ) coordination polymers, namely {[Mn₂(μ₆-L)(phen)₂]·5H₂O}_n (1) and {[Zn₂(μ₇-L)(py)]·H₂O}_n (2), have been constructed hydrothermally using H₄L (H₄L=3, 3', 4, 5'-diphenyl ether tetra-carboxylic acid), phen (phen=1, 10-phenanthroline), py (py=pyridine), and manganese or zinc chlorides. Single-crystal X-ray diffraction analyses revealed that two complexes crystallize in the triclinic or monoclinic systems, space groups P1 or I2/a. Both complexes feature a 2D sheet structure based on Mn₄ or Zn₂ subunits. The luminescent and magnetic properties for two complexes were also investigated. The results of fluorescence and magnetic studies show that complex 2 can emit blue fluorescence at room temperature, and antiferromagnetic interactions exist between adjacent Mn(Ⅱ) ions in polymer 1.
- coordination polymer,
- ether-bridged tetracarboxylic acid,
- luminescent properties,
- magnetic properties
1. [1]
  Zhu J, Usov P M, Xu W Q, et al. J. Am. Chem. Soc., 2018, 140:993-1003 doi: 10.1021/jacs.7b10643
2. [2]
  Fu H R, Zhao Y, Zou Z, et al. Dalton Trans., 2018, 47:3725-3732 doi: 10.1039/C8DT00206A
3. [3]
  Zou L F, Yuan J Q, Yuan Y, et al. CrystEngComm, 2019, 21:3289-3294 doi: 10.1039/C9CE00343F
4. [4]
  Gu J Z, Wen M, Cai Y, et al. Inorg. Chem., 2019, 58:2403-2412 doi: 10.1021/acs.inorgchem.8b02926
5. [5]
  Gu J Z, Wen M, Cai Y, et al. Inorg. Chem., 2019, 58:5875-5885 doi: 10.1021/acs.inorgchem.9b00242
6. [6]
  Minguez E G, Coronado E. Chem. Soc. Rev., 2018, 47:533-557 doi: 10.1039/C7CS00653E
7. [7]
  Cui Y J, Yue Y F, Qian G D, et al. Chem. Rev., 2012, 112:1126-1162 doi: 10.1021/cr200101d
8. [8]
  Gao L L, Zhang J, Zhai L J, et al. J. Solid State Chem., 2019, 271:346-353 doi: 10.1016/j.jssc.2019.01.008
9. [9]
  Morrison C N, Powell A K, Kostakis G E, et al. Cryst. Growth Des., 2011, 11:3653-3662 doi: 10.1021/cg2007028
10. [10]
  Gu J Z, Gao Z Q, Tang Y. Cryst. Growth Des., 2012, 12:3312-3323 doi: 10.1021/cg300442b
11. [11]
  ZOU Xun-Zhong, WU Jiang, GU Jin-Zhong, et al. Chinese J. Inorg. Chem., 2019, 35(9):1705-1711
12. [12]
  Gu J Z, Cui Y H, Liang X X, et al. Cryst. Growth Des., 2016, 16:4658-4670 doi: 10.1021/acs.cgd.6b00735
13. [13]
  Sánchez-Férez F, Bayés L, Font-Bardia M, et al. Inorg. Chim. Acta, 2019, 494:112-122 doi: 10.1016/j.ica.2019.05.010
14. [14]
  Zhai Z W, Yang S H, Luo P, et al. Eur. J. Inorg. Chem., 2019:2725-2734
15. [15]
  GU Wen-Jun, GU Jin-Zhong. Chinese J. Inorg. Chem., 2017, 33(2):227-236
16. [16]
  ZHAO Su-Qin, GU Jin-Zhong. Chinese J. Inorg. Chem., 2016, 32(9):1611-1618
17. [17]
  Gu J Z, Wen M, Liang X X. Crystals, 2018, 8:83 doi: 10.3390/cryst8020083
18. [18]
  Gu J Z, Cai Y, Wen M, et al. Dalton Trans., 2018, 47:14327-14339 doi: 10.1039/C8DT02467G
19. [19]
  Yue Q, Liu X, Guo W X, et al. CrystEngComm, 2018, 20:4258-4267 doi: 10.1039/C8CE00692J
20. [20]
  Spek A L. Acta Crystallogr. Sect. C:Cryst. Struct. Commun., 2015, C71:9-18
21. [21]
  Van de Sluis P, Spek A L. Acta Crystallogr. Sect. A:Found. Crystallogr., 1990, A46:194-201
22. [22]
  Gu J Z, Liang X X, Cai Y, et al. Dalton Trans., 2017, 46:10908-10925 doi: 10.1039/C7DT01742A
23. [23]
  Chen S S, Sheng L Q, Zhao Y, et al. Cryst. Growth Des., 2016, 16:229-241 doi: 10.1021/acs.cgd.5b01133
1. [1]
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2. [2]
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1.
沈阳化工大学材料科学与工程学院沈阳 110142