Citation: ZHANG Qi-Long, WANG Jia-Zhong, YANG Xiao-Sheng, ZHU Bi-Xue. Synthesis and Crystal Structure of Ni(Ⅱ)/Cu(Ⅱ)/Mn(Ⅲ) Complexes with Asymmetric Salen Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(1): 132-138. doi: 10.11862/CJIC.2020.030 shu

Synthesis and Crystal Structure of Ni(Ⅱ)/Cu(Ⅱ)/Mn(Ⅲ) Complexes with Asymmetric Salen Ligand

1.
State Key Laboratory of Functions and Applications of Medicinal Plants, Guizhou Medical University, Guiyang 550014, China
2.
School of Basic Medical Sciences, Guizhou Medical University, Guiyang 550025, China
3.
China Tobacco Guizhou Industrial Co., Ltd., Guiyang 550009, China
4.
Key laboratory of Macrocycle and Supramolecular Chemistry, Guizhou Medical University, Guiyang 550025, China

Corresponding author: ZHANG Qi-Long, gzuqlzhang@126.com
Received Date: 11 July 2019
Revised Date: 17 October 2019

Figures(8)

Reaction of (1R, 2R)-diaminocyclohexane with 2-hydroxy-1-naphthaldehyde and 3, 5-di-tert-butyl sali-cylaldehyde gave an asymmetric salen ligand H₂L. Then H₂L conducted the coordination reaction with Ni(OAc)₂·4H₂O, Cu(OAc)₂·H₂O and Mn(OAc)₂·4H₂O, and three mononuclear complex of[Ni(L)]·CH₂Cl₂ (1), [Cu(L)] (2) and[Mn(L)(Cl)]·CH₂Cl₂ (3) were obtained. The compounds were characterized by ¹H NMR, FT-IR and elemental analysis respectively and the crystal structure of ligand and three complexes were measured through X-ray single crystal diffraction technology. The ligand H₂L belongs to the orthorhombic system, P2₁2₁2₁ space group. Complex 1 belongs to the monoclinic system, P2₁/c space group, and the structures of complex 2 and 1 are similar. Complex 3 belongs to the triclinic system, P1 space group.
- asymmetric salen ligand,
- complex,
- synthesis,
- crystal structure
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沈阳化工大学材料科学与工程学院沈阳 110142