Citation: XU Zhong-Xuan, BAI Xue-Lei, MENG Qin. Two 3D Pillar-Layered Homochiral Coordination Complexes: Syntheses, Structures and Properties[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(1): 165-172. doi: 10.11862/CJIC.2020.029 shu

Two 3D Pillar-Layered Homochiral Coordination Complexes: Syntheses, Structures and Properties

School of Chemistry and Chemical Engineering, Zunyi Normal College, Zunyi, Guizhou 563002, China

Corresponding author: XU Zhong-Xuan, xuzhongxuan4201@163.com
Received Date: 5 June 2019
Revised Date: 9 November 2019

Figures(7)

Two homochiral coordination polymers[Cd₃((R)-CIA)₂(bipy)_2.5(H₂O)₂]·xGuest (1) and[Zn₃((R)-CIA)(bmib)₂(H₂O)₂Cl]·H₂O·xGuest (2) ((R)-H₃CIA=(R)-5-(1-carboxyethoxy) isophthalic acid, bipy=4, 4'-bipyridine, bmib=1, 4-bis(2-methyl-1H-imidazol-1-yl)benzene) were obtained under solvothermal reaction conditions. X-ray single crystal structure analysis reveals that complexes 1 and 2 are all 3D pillar-layered frameworks. From the viewpoint of structural topology, complex 1 possesses a (3, 3, 3, 6, 6)-connected net with a point symbol of (4.5²)₂(4.8²)₂(4².6⁸.8³. 10²)(4².6⁸.8³.9²)(5.8.9)₂, while complex 2 is a (3, 4, 4)-connected net with a point symbol of (6·7²)₂(6·7⁵)₂(6²·7⁴). Moreover, thermal stabilities, CD spectra and luminescent properties of these new complexes have been studied.
- homochiral,
- lactic acid derivative,
- pillar-layered framework,
- topology
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沈阳化工大学材料科学与工程学院沈阳 110142