Citation: ZHU Ning, PAN Xun, LIN Sen, YANG Yu-Ping, XIN Xiu-Lan, LI Zhong-Feng, ZHANG Fan, JIN Qiong-Hua. Syntheses, Structures and Terahertz Time-Domain Spectroscopy of Two Diimine-Copper(Ⅰ)-Phosphine Complexes[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(1): 183-191. doi: 10.11862/CJIC.2020.015 shu

Syntheses, Structures and Terahertz Time-Domain Spectroscopy of Two Diimine-Copper(Ⅰ)-Phosphine Complexes

ZHU Ning ^1,2 ,
PAN Xun ¹ ,
LIN Sen ¹ ,
YANG Yu-Ping ³ ,
XIN Xiu-Lan ⁴ ,
LI Zhong-Feng ¹ ,
ZHANG Fan ^1,, ,
JIN Qiong-Hua ^1,2,,

1.
Department of Chemistry, Capital Normal University, Beijing 100048, China
2.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
3.
School of Science, Minzu University of China, Beijing 100081, China
4.
School of Food and Chemical Engineering, Beijing Technology and Business University, Beijing 100048, China

Corresponding author: ZHANG Fan, 3938@cnu.edu.cn JIN Qiong-Hua, jinqh@cnu.edu.cn
Received Date: 28 May 2019
Revised Date: 11 October 2019

Figures(11)

Herein, two novel copper(Ⅰ) complexes, [Cu(PPh₃)₂(dppz)]Ⅰ (1) and[Cu₂(dppm)₂(dppz)₂]Cl₂ (2) (PPh₃=triphenylphosphine, dppz=dipyrido[3, 2-a:2', 3'-c]phenazine, dppm=bis(diphenylphosphino) methane) have been synthesized, and the characterization of the complexes was carried out through single-crystal X-ray diffraction, elemental analysis, IR, ¹H/³¹P NMR spectroscopy, fluorescence spectra and THz time domain spectroscopy (THz-TDS). The results show that 1 is a mononuclear complex. The central Cu(Ⅰ) builds a distorted tetrahedral geometry by coordinating with two phosphine ligands (PPh₃) and one chelating N-donor ligand (dppz). Different from 1, 2 exhibits a dinuclear structure which was obtained by the reaction of CuCl and dppm with dppz in 1:1:1 molar ratio, where the diphosphine ligand (dppm) was utilized as a bridging ligand coordinating to two copper(Ⅰ) atoms. The luminescent spectra show that the emission mechanism belongs to metal-to-ligand charge transfer (MLCT). At the same time, the terahertz (THz) time-domain spectroscopy was used to represent these two complexes as well as the corresponding ligands.
- copper(Ⅰ) complex,
- structures,
- fluorescence,
- terahertz (THz) time-domain spectroscopy,
- dipyrido[3, 2-a:2', 3'-c]phenazine
1. [1]
  dos Santos C M G, Harte A J, Quinn S J, et al. Coord. Chem. Rev., 2008, 252:2512-2527 doi: 10.1016/j.ccr.2008.07.018
2. [2]
  Hu X, Wang F Y, Peng Q Q, et al. RSC Adv., 2019, 9:13048-13053 doi: 10.1039/C9RA01748H
3. [3]
  Farahani Y D, Safarifard V. J. Solid State Chem., 2019, 275:131-140 doi: 10.1016/j.jssc.2019.04.018
4. [4]
  Jana M K, Janke S M, Dirkes D J, et al. J. Am. Chem. Soc., 2019, 141:7955-7964 doi: 10.1021/jacs.9b02909
5. [5]
  Hayashi T, Kobayashi A, Ohara H, et al. Inorg. Chem., 2019, 54:8905-8913
6. [6]
  Huang X S, Hu M, Zhao X H, et al. Org. Lett., 2019, 21:3382-3386 doi: 10.1021/acs.orglett.9b01130
7. [7]
  Cao L D, Zhang H R, Zhou Z L, et al. Nanoscale, 2018, 10:20354-20365 doi: 10.1039/C8NR04626C
8. [8]
  Taha Z A, Ajlouni A M, Al Momani W. J. Lumin., 2012, 132:2832-2841 doi: 10.1016/j.jlumin.2012.05.041
9. [9]
  Gao H, Zhao X, Chen S J. Molecules, 2018, 23:419/1-419/20
10. [10]
  Zhang D D, Duan L. J. Phys. Chem. Lett., 2019, 10:2528-2537 doi: 10.1021/acs.jpclett.9b00526
11. [11]
  Tsuboyama A, Kuge K, Furugori M, et al. Inorg. Chem., 2007, 46:1992-2001 doi: 10.1021/ic0608086
12. [12]
  Xiao L, Chen Z, Qu B, et al. Adv. Mater., 2011, 23:926-952 doi: 10.1002/adma.201003128
13. [13]
  Hashimoto M, Igawa S, Yashima M, et al. J. Am. Chem. Soc., 2011, 133:10348-10351 doi: 10.1021/ja202965y
14. [14]
  Minaev B, Jansson E, Agren H, et al. J. Chem. Phys., 2006, 125:234704 doi: 10.1063/1.2388263
15. [15]
  Helander M G, Wang Z B, Qiu J, et al. Science, 2011, 332:944-947 doi: 10.1126/science.1202992
16. [16]
  Hamze R, Peltier J L, Sylvinson D, et al. Science, 2019, 363:601-606 doi: 10.1126/science.aav2865
17. [17]
  Brunner F, Martinez-Sarti L, Keller S, et al. Dalton Trans., 2016, 45:15180-15192 doi: 10.1039/C6DT02665F
18. [18]
  Linfoot C L, Leitl M J, Richardson P, et al. Inorg. Chem., 2014, 53:10854-10861 doi: 10.1021/ic500889s
19. [19]
  Adachi C, Baldo M A, Thompson M E, et al. J. Appl. Phys., 2001, 90:5048-5051 doi: 10.1063/1.1409582
20. [20]
  Tanaka D, Agata Y, Takeda T, et al. Jpn. J. Appl. Phys., 2007, 46:L117-L119 doi: 10.1143/JJAP.46.L117
21. [21]
  Zhang Y, Schulz M, Waechtler M, et al. Coord. Chem. Rev., 2018, 356:127-146 doi: 10.1016/j.ccr.2017.10.016
22. [22]
  Kuang S M, Cuttell D G, McMillin D R. Inorg. Chem., 2002, 41:3313-3322 doi: 10.1021/ic0201809
23. [23]
  Zhang Q S, Zhou Q G, Cheng Y X, et al. Adv. Mater., 2004, 16:432-436 doi: 10.1002/adma.200306414
24. [24]
  Bergmann L, Friedrichs J, Mydlak M, et al. Chem. Commun., 2013, 49:6501-6503 doi: 10.1039/c3cc42280a
25. [25]
  Chen X L, Yu R M, Zhang Q K, et al. Chem. Mater., 2013, 25:3910-3920 doi: 10.1021/cm4024309
26. [26]
  Mara M W, Jackson N E, Huang J, et al. J. Phys. Chem. B, 2013, 117:1921-1931 doi: 10.1021/jp311643t
27. [27]
  Garakyaraghi S, Danilov E O, McCusker C E, et al. J. Phys. Chem. A, 2015, 119:3181-3193 doi: 10.1021/acs.jpca.5b00901
28. [28]
  McCusker C E, Castellano F N. Inorg. Chem., 2013, 52:8114-8120http://med.wanfangdata.com.cn/Paper/Detail/PeriodicalPaper_PM23789625
29. [29]
  Green O, Gandhi B A, Burstyn J N. Inorg. Chem., 2009, 48:5704-5714http://med.wanfangdata.com.cn/Paper/Detail/PeriodicalPaper_PM19496591
30. [30]
  Kuang X N, Lin S, Liu J M, et al. Polyhedron, 2019, 165:51-62
31. [31]
  PAN Xun, KUANG Xiao-Nan, ZHU Ning, et al. Chinese J. Inorg. Chem., 2019, 35:361-368
32. [32]
  Zhang Y R, Yu X, Lin S, et al. Polyhedron, 2017, 138:46-56
33. [33]
  Wang Y, Kuang X N, Cui Y Z. Polyhedron, 2018, 155:135-143
34. [34]
  Sheldrick G M. SHELXTL NT Ver.5.1, University of Göttingen, Germany, 1997.
35. [35]
  Sheldrick G M. SHELXS-97 and SHELXL-97, Madison, WI, USA, 1997.
36. [36]
  Zhang L M, Yue S M, Li B, et al. Inorg. Chim. Acta, 2012, 384:225-232
37. [37]
  Villarreal W, Colina-Vegas L, Visbal G, et al. Inorg. Chem., 2017, 56:3781-3793
38. [38]
  Chen H F, Hung W Y, Chen S W, et al. Inorg. Chem., 2012, 51:12114-12121
39. [39]
  Tsukuda T, Nakamura A, Arai T, et al. Bull. Chem. Soc. Jpn., 2006, 79:288-290 doi: 10.1039/b608641a
40. [40]
  Ruina Y, Kunhua L, Yimin H, et al. Polyhedron, 1997, 16:4033-4038 doi: 10.1023/A:1018412524042
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