Citation: JIA Hai-Lang, LI Shan-Shan, GONG Bing-Quan, GU Lei, GUAN Ming-Yun. Application of Self-Assembly of an Antenna Molecule with Porphyrin Dyes in Dye-Sensitized Solar Cells[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(1): 123-131. doi: 10.11862/CJIC.2020.014 shu

Application of Self-Assembly of an Antenna Molecule with Porphyrin Dyes in Dye-Sensitized Solar Cells

School of Chemical and Environmental Engineering, Jiangsu University of Technology, Changzhou 213001, China

Corresponding author: JIA Hai-Lang, jiahailang85@126.com
Received Date: 6 July 2019
Revised Date: 10 October 2019

Figures(9)

Using the porphyrin molecule H2-pTCPP as a basic dye, we modified antenna molecule S3 into dye structure by coordination self-assembly method. The results show that the overall performance of the device has been greatly improved after the modification of antenna molecule. The antenna effect effectively improves the light-harvesting ability and the photocurrent of the device, in addition, the charge recombination is obviously reduced. The device based on H2-pTCPP showed a PCE of 1.18%, and the device based on Mn-pTCPP+S3 showed a PCE of 2.64%. So, the overall performance of the device is increased by 1.2 times.
- dye-sensitized solar cells,
- antenna effect,
- porphyrin,
- self-assembly,
- charge recombination
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