Citation: XIE Yan-Yan, SUN Hong-Juan, PENG Tong-Jiang, LUO Li-Ming, TIAN Jing-Fei, QIN Ya-Ting. High Expansion Rate Expanded Vermiculite: Preparation by Chemical-Microwave Method and the Adsorption Mechanism of Methylene Blue[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(1): 113-122. doi: 10.11862/CJIC.2020.004 shu

High Expansion Rate Expanded Vermiculite: Preparation by Chemical-Microwave Method and the Adsorption Mechanism of Methylene Blue

XIE Yan-Yan ^1,2,3 ,
SUN Hong-Juan ^1,2,3,, ,
PENG Tong-Jiang ^1,2,3,4 ,
LUO Li-Ming ^1,2,3 ,
TIAN Jing-Fei ^1,2,3 ,
QIN Ya-Ting ^1,2,3

1.
Key Laboratory of Ministry of Education for Solid Waste Treatment and Resource Recycle, Southwest University of Science and Technology, Mianyang, Sichuan 621010, China
2.
Institute of Mineral Materials and Applications, Southwest University of Science and Technology, Mianyang, Sichuan 621010, China
3.
Sichuan Engineering Lab of Nonmetallic Mineral Powder Modification & High-quality Utilization, Southwest University of Science and Technology, Mianyang, Sichuan 621010, China
4.
Center of Forecasting and Analysis, Southwest University of Science and Technology, Mianyang, Sichuan 621010, China

Corresponding author: SUN Hong-Juan, sunhongjuan@swust.edu.cn
Received Date: 7 July 2019
Revised Date: 16 October 2019

Figures(8)

In order to improve the application efficiency of vermiculite and broaden its application field, high expansion rate expanded vermiculite (HEV) was prepared by chemical-microwave method based on the excellent thermal expansion and cation exchange properties of industrial vermiculite and the adsorption properties of methylene blue (MB) were studied by comparative analysis. The experimental results showed that the HEV has a high expansion rate (K=60 times), large specific surface area (80 m²·g^-1), and the pore diameter was mainly distributed between 2 and 5 nm. The crystalline formof vermiculite, hydrophlogopite and phlogopite were still maintained, and the cation exchange capacity increased to 1.005 mmol·g^-1 from the original 0.835 mmol·g^-1. The adsorption capacity of HEV was influenced by the initial concentration of MB, adsorption time, solution pH and adsorption temperature. When the initial concentration of MB solution was 300 mg·L^-1, the adsorption time was 240 min, the pH value was 9, the adsorption temperature was 298 K, and the adsorption capacity was 419.87 mg·g^-1, much higher than the original vermiculite ore. The adsorption process conforms to the Langmuir model and the pseudo-second order kinetic model, and is a spontaneous and disordered endothermic reaction process with single molecular layer adsorption and low adsorption barrier. Removal of HEV effect on MB has surpassed that of some natural minerals as well as commercial-grade activated carbon, indicating that HEV is an efficient, low-cost cationic dye waste water adsorbent.
- industrial vermiculite,
- microwave,
- expanded vermiculite,
- adsorption,
- methylene blue
1. [1]
  XU Rong-Qi, CAO Jun-Chen. Acta Miner-alogica Sinica, 1993, 13(1):39-47
2. [2]
  PENG Tong-Jiang, WAN Pu, PAN Zhao-Lu, et al. Acta Petrologica et Mineralogica, 1996, 15(3):250-258
3. [3]
  Marcos C, Rodríguez I. Appl. Clay Sci., 2014, 87(4):219-227
4. [4]
  Hillier S, Marwa E M M, Rice C M. Clay Miner., 2013, 48(4):563-582 doi: 10.1180/claymin.2013.048.4.01
5. [5]
  Crini G. Bioresour. Technol., 2006, 97(9):1061-1085 doi: 10.1016/j.biortech.2005.05.001
6. [6]
  CAO Yu-Cheng, SHAN Sheng-Dao, ZHANG Miao-Xian, et al. Environ. Sci. Technol., 2009, 32(11):32-36 doi: 10.3969/j.issn.1003-6504.2009.11.008
7. [7]
  Duman O, Tun S, Polat T G. Appl. Clay Sci., 2015, 109:22-32
8. [8]
9. [9]
  Marcos C, Rodríguez I. Appl. Clay Sci., 2011, 51(1/2):33-37
10. [10]
  Lee T. Water Air Soil Pollut., 2012, 223(6):3399-3408 doi: 10.1007/s11270-012-1119-3
11. [11]
  Marcos C, Rodríguez I. Appl. Clay Sci., 2014, 90(12):96-100
12. [12]
  Freitas E D D, Almeida H J D. Appl. Clay Sci., 2017, 146:503-509 doi: 10.1016/j.clay.2017.07.004
13. [13]
  Marcos C, Menéndez R, Rodríguez I. Appl. Clay Sci., 2017, 150:147-152 doi: 10.1016/j.clay.2017.09.026
14. [14]
  WANG Meng-Meng, QI Yu, LI Hong-Ling, et al. Journal of Shihezi University:Natural Science, 2016, 34(3):367-371
15. [15]
  ZHAO Shuang-Meng, PENG Tong-Jiang, SUN Hong-Juan. Journal of Mineralogy and Petrology, 2006, 26(2):30-34 doi: 10.3969/j.issn.1001-6872.2006.02.005
16. [16]
  ZHAO Shuang-Meng, PENG Tong-Jiang, SUN Hong-Juan. Conservation and Utilization of Mineral Resources, 2006(3):22-25 doi: 10.3969/j.issn.1001-0076.2006.03.005
17. [17]
  Ferdousi B N, Islam M M, Okajima T, et al. Electrochim. Acta, 2008, 53(2):968-974
18. [18]
  Na Z, Qian X. Procedia Eng., 2012, 45(2):526-532
19. [19]
20. [20]
  PENG Tong-Jiang, SUN Hong-Juan, SUN Jin-Mei, et al. Journal of Mineralogy and Petrology, 2009, 29(1):14-19 doi: 10.3969/j.issn.1001-6872.2009.01.003
21. [21]
  Tu S X, GuoZ F, Sun J H. Pedosphere, 2007, 17(4):457-466 doi: 10.1016/S1002-0160(07)60055-1
22. [22]
  Neimark A V, Sing K S W, Thommes M. Surface Area and Porosity. Weinheim: Wiley-VCH Verlag GmbH & Co. KGaA, 2008.
23. [23]
  Andrew M, David H, John P, et al. Dyes Pigm., 2011, 88(2):149-155 doi: 10.1016/j.dyepig.2010.05.015
24. [24]
  Doǧan M, Alkan M, Türkyilmaz A, et al. J. Hazard. Mater., 2004, 109(1/2/3):141-148
25. [25]
  Özcan A S, Erdem B, Özcan A. Colloids Surf. A, 2005, 266(1/2/3):73-81
26. [26]
  Almeida C a P, Debacher N A, Downs A J, et al. Colloid Interface Sci., 2009, 332(1):46-53 doi: 10.1016/j.jcis.2008.12.012
27. [27]
  Doǧan M, Alkan M, Onganer Y. Water Air Soil Pollut., 2000, 120(3/4):229-248 doi: 10.1023/A:1005297724304
28. [28]
  Al-Ghouti M, Khraisheh M, Allen S, et al. J. Environ. Manage., 2003, 69(3):229-238 doi: 10.1016/j.jenvman.2003.09.005
29. [29]
  Bestani B, Benderdouche N, Benstaali B, et al. Bioresour. Technol., 2008, 99(17):8441-8444 doi: 10.1016/j.biortech.2008.02.053
30. [30]
  Kannan N, Sundaram M M. Dyes Pigm., 2001, 51(1):25-40 doi: 10.1016/S0143-7208(01)00056-0
31. [31]
  Gücek A, ener S, Bilgen S, et al. J. Colloid Interface Sci., 2005, 286(1):53-60 doi: 10.1016/j.jcis.2005.01.012
32. [32]
  Langmuir I. J. Am. Chem. Soc., 1916, 184(5):102-105
33. [33]
  Rouquerol F, Rouquerol J, Sing K. Adsorption by Powders and Porous Solids. Pittsburgh: Academic Press, 2014.
34. [34]
  ZHU Hong-Yu, YANG Han-Pei, SUN Hui-Hua, et al. Chinese J. Inorg. Chem., 2018, 34(3):445-453
35. [35]
  Weber T W, Chakravorti R K. AIChE J., 1974, 20(2):228-238 doi: 10.1002/aic.690200204
36. [36]
  LI Jun, WANG Lu-Xiang, CAO Ya-Li, et al. Chinese J. Inorg. Chem., 2016, 32(9):1603-1610
37. [37]
  Doǧan M, Alkan M, DemirbasÖ, et al. Chem. Eng. J., 2006, 124(1):89-101
38. [38]
  Ho Y S, Mckay G. Chem. Eng. J., 1998, 70(2):115-124 doi: 10.1016/S0923-0467(98)00076-1
39. [39]
  WU Cai-Hong, ZHENG Guo-Yuan, WANG Ji-Lin, et al. Chinese J. Inorg. Chem., 2019, 35(3):449-458
40. [40]
  LIU Feng-Xian, SHAO Meng-Meng, XIA Sheng-Jie, et al. Chinese J. Inorg. Chem., 2015, 31(7):1342-1350
41. [41]
  Yu X B, Wei C H, Wu H Z. Sep. Purif. Technol., 2015, 156:489-495 doi: 10.1016/j.seppur.2015.10.039
42. [42]
  Stawiński W, Freitas O, Chmielarz L, et al. Chemosphere, 2016, 153:115-129 doi: 10.1016/j.chemosphere.2016.03.004
43. [43]
  Sonntag R E, Borgnakke C. Introduction to Chemical Engin-eering Thermodynamics. Beijing:Chemical Industry Press, 2014:e62-e70
44. [44]
  Sarma G K, Sengupta S, Bhattacharyya K G. Water Air Soil Pollut., 2018, 229(10):312 doi: 10.1007/s11270-018-3971-2
1. [1]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
2. [2]
  Hui Wang , Abdelkader Labidi , Menghan Ren , Feroz Shaik , Chuanyi Wang . 微观结构调控的g-C₃N₄在光催化NO转化中的最新进展：吸附/活化位点的关键作用. Acta Physico-Chimica Sinica, 2025, 41(5): 100039-. doi: 10.1016/j.actphy.2024.100039
3. [3]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
4. [4]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
5. [5]
  Jing Wang , Pingping Li , Yuehui Wang , Yifan Xiu , Bingqian Zhang , Shuwen Wang , Hongtao Gao . Treatment and Discharge Evaluation of Phosphorus-Containing Wastewater. University Chemistry, 2024, 39(5): 52-62. doi: 10.3866/PKU.DXHX202309097
6. [6]
  Guang Huang , Lei Li , Dingyi Zhang , Xingze Wang , Yugai Huang , Wenhui Liang , Zhifen Guo , Wenmei Jiao . Cobalt’s Valor, Nickel’s Foe: A Comprehensive Chemical Experiment Utilizing a Cobalt-based Imidazolate Framework for Nickel Ion Removal. University Chemistry, 2024, 39(8): 174-183. doi: 10.3866/PKU.DXHX202311051
7. [7]
  Fugui XI , Du LI , Zhourui YAN , Hui WANG , Junyu XIANG , Zhiyun DONG . Functionalized zirconium metal-organic frameworks for the removal of tetracycline from water. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 683-694. doi: 10.11862/CJIC.20240291
8. [8]
  Wei Li , Jinfan Xu , Yongjun Zhang , Ying Guan . 共价有机框架整体材料的制备及食品安全非靶向筛查应用——推荐一个仪器分析综合化学实验. University Chemistry, 2025, 40(6): 276-285. doi: 10.12461/PKU.DXHX202406013
9. [9]
  Shuanglin TIAN , Tinghong GAO , Yutao LIU , Qian CHEN , Quan XIE , Qingquan XIAO , Yongchao LIANG . First-principles study of adsorption of Cl₂ and CO gas molecules by transition metal-doped g-GaN. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1189-1200. doi: 10.11862/CJIC.20230482
10. [10]
  Yuena Yu , Fang Fang . Microwave-Assisted Synthesis of Safinamide Methanesulfonate. University Chemistry, 2024, 39(11): 210-216. doi: 10.3866/PKU.DXHX202401076
11. [11]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
12. [12]
  Yichang Liu , Li An , Dan Qu , Zaicheng Sun . “双碳”背景下的综合设计实验——以PbCrO₄催化甲基蓝的光降解速率常数测定为例. University Chemistry, 2025, 40(6): 222-229. doi: 10.12461/PKU.DXHX202407105
13. [13]
  Min LI , Xianfeng MENG . Preparation and microwave absorption properties of ZIF-67 derived Co@C/MoS₂ nanocomposites. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1932-1942. doi: 10.11862/CJIC.20240065
14. [14]
  Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030
15. [15]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
16. [16]
  Fang Niu , Rong Li , Qiaolan Zhang . Analysis of Gas-Solid Adsorption Behavior in Resistive Gas Sensing Process. University Chemistry, 2024, 39(8): 142-148. doi: 10.3866/PKU.DXHX202311102
17. [17]
  Jiali CHEN , Guoxiang ZHAO , Yayu YAN , Wanting XIA , Qiaohong LI , Jian ZHANG . Machine learning exploring the adsorption of electronic gases on zeolite molecular sieves. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 155-164. doi: 10.11862/CJIC.20240408
18. [18]
  Fei Xie , Chengcheng Yuan , Haiyan Tan , Alireza Z. Moshfegh , Bicheng Zhu , Jiaguo Yu . d带中心调控过渡金属单原子负载COF吸附O₂的理论计算研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2407013-. doi: 10.3866/PKU.WHXB202407013
19. [19]
  Xueqi Yang , Juntao Zhao , Jiawei Ye , Desen Zhou , Tingmin Di , Jun Zhang . 调节NNU-55(Fe)的d带中心以增强CO₂吸附和光催化活性. Acta Physico-Chimica Sinica, 2025, 41(7): 100074-. doi: 10.1016/j.actphy.2025.100074
20. [20]
  Jianan Zhang , Mengzhen Xu , Jiamin Liu , Yufei He . 面向“双碳”目标的脱氯吸附剂开发研究型综合实验设计. University Chemistry, 2025, 40(6): 248-255. doi: 10.12461/PKU.DXHX202408068

Get Citation

PDF

XML

Metrics

PDF Downloads(13)
Abstract views(1872)
HTML views(473)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142