Citation: LIU Zhi-Qiang, WU Jun-Feng, CHEN Jun, WU Xia, WANG Yan. Two Metal-Organic Frameworks Constructed by 1, 3-Di(1H-imidazol-4-yl) Ligand: Synthesis, Crystal Structure and Photoluminescence Property[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(1): 159-164. doi: 10.11862/CJIC.2020.003 shu

Two Metal-Organic Frameworks Constructed by 1, 3-Di(1H-imidazol-4-yl) Ligand: Synthesis, Crystal Structure and Photoluminescence Property

LIU Zhi-Qiang ^1,2,, ,
WU Jun-Feng ¹ ,
CHEN Jun ¹ ,
WU Xia ¹ ,
WANG Yan ¹

1.
School of Chemistry and Chemical Engineering, Anhui Province Key Laboratory of Functional Optical, Electrical and Magnetic Materials, Key Laboratory of Functional Coordination Compounds and Nano Materials of Anhui Higher Education Institutes, Anqing Normal University, Anqing, Anhui 246011, China
2.
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China

Corresponding author: LIU Zhi-Qiang, liuzhiqiang711@126.com
Received Date: 5 June 2019
Revised Date: 17 September 2019

Figures(4)

Reactions of ligands 1, 3-di(1H-imidazol-4-yl)benzene (L) and with corresponding metal salts under hydrothermal conditions gave rise to two new metal-organic frameworks (MOFs), namely[Cd(L)(SO₄)]_n (1) and {[Ni(L)(SO₄)]·H₂O}_n (2). All of MOFs have been structurally characterized by single-crystal X-ray diffraction analyses and characterized by elemental analysis, infrared spectra (IR), powder X-ray diffraction (PXRD) and thermo-gravimetric analysis (TGA). 1 belongs to orthorhombic system, space group Pnma, with a=0.707 28(5) nm, b=1.343 81(9) nm, c=1.407 31(9) nm, V=1.337 58(16) nm³, D_c=2.079 g·cm^-3, Z=4, F(000)=824, GOF=1.072, R₁=0.019 0, wR₂=0.050 6. 2 belongs to triclinic system, space group P1, with a=0.986 65(18) nm, b=1.145 7(2) nm, c=1.302 5(2) nm, α=65.029(3)°, β=83.497(3)°, γ=86.423(4)°, V=1.326 0(4) nm³, D_c=1.441 g·cm^-3, Z=2, F(000)=592, GOF=1.016, R₁=0.043 4, wR₂=0.077 1. All the MOFs have two-dimensional (2D) layer structures. Furthermore, the thermal stability and photoluminescence property of the MOFs were investigated.
- metal-organic frameworks,
- bis(1H-imidazol-4-yl) ligands,
- crystal structure,
- photoluminescence property
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