Citation: NING Xiang, WU Yue-Tao, WANG Xu-Feng, LIU Yan-Li. Preparation and Photocatalytic Activity of g-C₃N₄/SnO₂ Composite[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(12): 2243-2252. doi: 10.11862/CJIC.2019.272 shu

Preparation and Photocatalytic Activity of g-C₃N₄/SnO₂ Composite

NING Xiang ^1,2 ,
WU Yue-Tao ^1,2 ,
WANG Xu-Feng ^1,2 ,
LIU Yan-Li ^1,2,,

1.
College of Material Science and Engineering, Hunan University, Changsha 410082, China
2.
Hunan Province Key Laboratory for Spray Deposition Technology and Application, Hunan University, Changsha 410082, China

Corresponding author: LIU Yan-Li, yanliliu@hnu.edu.cn
Received Date: 30 April 2019
Revised Date: 28 August 2019

Figures(11)

The g-C₃N₄/SnO₂ composite had been fabricated by the combination of hydrothermal method and thermal polymerization process in this paper. The crystal structures and morphology of various samples were characterized using XRD, SEM, TEM, FT-IR, and UV-Vis DRS. The results showed that the optical absorption edge of g-C₃N₄/SnO₂ composites with co-effect of heterojunction had an obvious red shift to the longer wavelength in comparison with pure SnO₂ and SnO₂ nanoparticles were dispersing on the g-C₃N₄ surface well. The photocatalytic degradation properties of g-C₃N₄/SnO₂ composites on rhodamine B (RhB) were remarkably improved under visible light irradiation, and the degradation rate of optimal 50%-g-C₃N₄/SnO₂ composite was 3.78 times as great as that of pure g-C₃N₄.
- photocatalysis,
- heterojunction,
- g-C₃N₄,
- SnO₂,
- nanoparticles
1. [1]
  LIU Chang-Ming, CAO Ying-Jie. Impact Sci Soc, 2009, 2:16-22 doi: 10.3969/j.issn.2095-1949.2009.02.003
2. [2]
  HAN Zhao-Hui, ZHAO Hua-Qiao. Prog. Chem., 1999, 11(1):1-10 doi: 10.3321/j.issn:1005-281X.1999.01.002
3. [3]
  LI Na, WANG Ming, ZHAO Bei-Ping, et al. Chinese J. Inorg. Chem., 2016, 32(6):1033-1040
4. [4]
  DUAN Li-Ying, LU Shan-Shan, DUAN Fang, et al. Chinese J. Inorg. Chem., 2019, 35(5):793-802
5. [5]
  Wang X C, Blechert S, Antonietti M. ACS Catal., 2012, 2(8):1596-1606
6. [6]
  Wang X F, Mao W W, Zhang J, et al. J. Colloid Interface Sci., 2015, 448:17-23 doi: 10.1016/j.jcis.2015.01.090
7. [7]
  Faisala M, Ismail A A, Harraz F A, et al. Mater. Des., 2016, 98:223-230 doi: 10.1016/j.matdes.2016.03.019
8. [8]
  He Y M, Wang Y, Zhang L H, et al. Appl. Catal., B, 2015, 168-169(168):1-8
9. [9]
  Sun M, Yan Q, Yan T, et al. RSC Adv., 2014, 4:31019-31027 doi: 10.1039/C4RA03843F
10. [10]
  MA Ling-Juan, HOU Meng-Ning, MA Hong -Bin, et al. Chinese J. Inorg. Chem., 2018, 34(10):1899-1909 doi: 10.11862/CJIC.2018.251
11. [11]
  Tian Y L, Cheng F X, Zhang X, et al. Powder Technol., 2014, 267:126-133 doi: 10.1016/j.powtec.2014.07.021
12. [12]
  Tong Z W, Yang D, Xiao T X, et al. Chem. Eng. J., 2015, 260:117-125 doi: 10.1016/j.cej.2014.08.072
13. [13]
  Tian Y L, Chang B B, Lu J L, et al. ACS Appl. Mater. Interfaces, 2014, 267(15):126-133
14. [14]
  Uddin M T, Nicolas Y, Olivier C, et al. Inorg. Chem., 2012, 51(14):7764-7773 doi: 10.1021/ic300794j
15. [15]
  Xu M, Han L, Dong S J. ACS Appl. Mater. Interfaces, 2013, 5(23):12533-12540 doi: 10.1021/am4038307
16. [16]
  Dong F, Wu L W, Sun Y J, et al. J. Mater. Chem., 2011, 21(39):15171-15174 doi: 10.1039/c1jm12844b
17. [17]
  Bojdys M J, Muller J O, Antonietti M, et al. Chem. Eur. J., 2008, 14(27):8177-8182.1 doi: 10.1002/chem.200800190
18. [18]
  Liao G Z, Chen S, Quan X, et al. J. Mater. Chem., 2012, 22:2721-2726 doi: 10.1039/C1JM13490F
19. [19]
  Li Y B, Zhang H M, Liu P R, et al. Small, 2013, 9(19):3336-3344
20. [20]
  Chen Y F, Huang W X, He D L, et al. ACS Appl. Mater. Interfaces, 2014, 6(16):14405-14414 doi: 10.1021/am503674e
21. [21]
  Pradhan G K, Reddy K H, Parida K M. Catal. Today, 2014, 224:171-179 doi: 10.1016/j.cattod.2013.10.038
22. [22]
  Xing C S, Wu Z D, Jiang D L, et al. J. Colloid Interface Sci., 2014, 433(11):9-15
23. [23]
  Watanabe T, Takirawa T, Honda K. J. Phys. Chem., 1977, 81(19):1845-1851 doi: 10.1021/j100534a012
24. [24]
  Zhuang S D, Xu X Y, Feng B, et al. ACS Appl. Mater. Interfaces, 2014, 6(1):613-621
25. [25]
  Zhou M J, Gao X H, Hu Y, et al. Appl. Catal., B, 2013, 139-139(21):1-8
26. [26]
  Sun J X, Yuan Y P, Qiu L G, et al. Dalton Trans., 2012, 41(22):6756-6763
27. [27]
  Xiong Z G, Zhang L L, Ma J Z, et al. Chem. Commun., 2010, 46(33):60
28. [28]
  Zhao S S, Chen S, Yu H T, et al. Sep. Purif. Technol., 2012, 99(41):50-54
29. [29]
  Wen J Q, Xie J, Chen X B, et al. Appl. Surf. Sci., 2017, 391:72-123 doi: 10.1016/j.apsusc.2016.07.030
30. [30]
  Zhang C, Li Y, Shuai D M, et al. Chemosphere, 2019, 214:462-479 doi: 10.1016/j.chemosphere.2018.09.137
31. [31]
  Ikeda K, Sakai H, Baba R, et al. J. Phys. Chem. A, 1997, 101(14):2617-2620 doi: 10.1021/jp9627281
32. [32]
  Kubo W, Tatsuma T. J. Am. Chem. Soc., 2006, 128(50):16034-16035 doi: 10.1021/ja066041y
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Preparation and Photocatalytic Activity of g-C₃N₄/SnO₂ Composite