Citation: LI Gui-Lian, YIN Wei-Dong, LIU Qian-Long, LI Xiao-Ling, XIN Ling-Yun, LIU Guang-Zhen. Syntheses, Structures and Properties of Three Coordination Polymers Based on Citraconic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(12): 2355-2363. doi: 10.11862/CJIC.2019.271 shu

Syntheses, Structures and Properties of Three Coordination Polymers Based on Citraconic Acid

1.
College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang, Henan 471934, China
2.
School of Food and Drug, Luoyang Normal University, Luoyang, Henan 471934, China

Corresponding author: LIU Guang-Zhen, gzliuly@126.com
Received Date: 28 May 2019
Revised Date: 12 September 2019

Figures(6)

Three coordination polymers, {[Zn(ca)(iimb)]·0.75H₂O}_n (1), {[Cd(ca)(iimb)(H₂O)]·0.75H₂O}_n (2) and {[Zn(ca)(bpe)_0.5(H₂O)]·H₂O}_n (3) (H₂ca=citraconic acid, iimb=1-(1-imidazolyl)-4-(imidazol-1-ylmethyl)benzene, bpe=1, 2-di(4-pyridyl)ethylene), were synthesized hydrothermally and measured structurally by single crystal X-ray diffraction, infrared spectroscopy(IR) and elemental analysis. Complex 1 displays a 2D reticular layer containing 1D metal-carboxylate chains. 2 features a 1D quasi-trapezoidal shape chain structure containing carboxylate-bridged dinuclear structures. Complex 3 shows a two-dimensional wave layer. The three-dimensional supramolecular structures of 2 and 3 are formed by abundant H-bond interactions; nevertheless, 3D supramolecular structure of 1 is formed through weak van der Waals force. Thermogravimetric analyses (TGA), powder X-ray diffractions (PXRD) and fluorescence properties for complexes 1~3 were investigated. The solid state fluorescence spectra indicate that all emission spectra of three complexes 1~3 are similar with those of the corresponding auxiliary ligands. In addition, complex 3 exhibits good photocatalytic activity for methylene blue (MB) degradation in the presence of H₂O₂ under UV irradiation.
- citraconic acid,
- hydrothermal synthesis,
- fluorescence property,
- photocatalytic degradation
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沈阳化工大学材料科学与工程学院沈阳 110142