Citation: XIE Qing-Fan, CHEN Yan-Min. Syntheses, Crystal Structures, and Characterization of Three Zinc Complexs with Different Acylhydrazone-Type Schiff Base Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(12): 2209-2216. doi: 10.11862/CJIC.2019.267 shu

Syntheses, Crystal Structures, and Characterization of Three Zinc Complexs with Different Acylhydrazone-Type Schiff Base Ligands

XIE Qing-Fan ,
CHEN Yan-Min ^,

College of Chemical Engineering and Material, Quanzhou Normal University, Quanzhou, Fujian 362000, China

Corresponding author: CHEN Yan-Min, QZUCYM@163.com
Received Date: 1 April 2019
Revised Date: 29 October 2019

Figures(8)

Three zinc complexes, namely[Zn(Lss)(phen)(DMF)] (1), {[Zn(HLdis)]₂·2CH₃OH}_n (2) and[Zn(Baf)₂]·CH₃OH (3), formed from different acylhydrazone-type Schiff base ligands were synthesized by using different methods, and the compounds were characterized by IR, UV-Vis spectra and TGA. The X-ray diffraction analyses reveal that 1 and 3 crystallize in the triclinic space group P1 while 2 in monoclinic system space group P2₁/n. In 1 and 3, coordination number of the Zn(Ⅱ) is six, and the centric atom locate in a distorted octahedron geometry, while in 2 Zn(Ⅱ) is five-coordination in a distorted square-pyramidal geometry. The precursor of 3 is pyrazoline derivative with the formula C₁₅H₁₄N₂O₃ (Pzl) crystallizing in monoclinic system space group P2₁/c. Due to the coordination of Zn(Ⅱ) causing the intramolecular rearrangement of Pzl, the ring open product HBaf in the form of an acylhydrazone structure coordinates with Zn(Ⅱ) to form complex 3.
- Schiff base,
- zinc complex,
- crystal structure,
- spectral properties
1. [1]
  Chellaian J D, Johnson J. Spectrochim. Acta Part A, 2014, 127:396-404 doi: 10.1016/j.saa.2014.02.075
2. [2]
  Chooset S, Kantacha A, Chainok K, et al. Inorg. Chim. Acta, 2018, 471:493-501 doi: 10.1016/j.ica.2017.11.053
3. [3]
  Azam M, Wabaidur S M, Alam M J, et al. Inorg. Chim. Acta, 2019, 487:97-106 doi: 10.1016/j.ica.2018.12.009
4. [4]
  Asadizadeh S, Amirnasr M, Tirani F F, et al. Inorg. Chim. Acta, 2018, 483:310-320 doi: 10.1016/j.ica.2018.08.037
5. [5]
  Jungwirth U, Kowol C R, Keppler B K, et al. Antioxid. Redox Signaling, 2011, 15(4):1085-1127 doi: 10.1089/ars.2010.3663
6. [6]
  GAO Ping-Zhang, CHEN Ya-Xin, ZHENG Min-Min, et al. Chinese J. Inorg. Chem., 2016, 32(3):1572-1578
7. [7]
  Wang J F, Liu B, Liu X M, et al. Dalton Trans., 2014, 43:14142-14146 doi: 10.1039/C4DT01799D
8. [8]
  CHEN Yan-Min, FENG Ying-Jian, CAI Ming-Yu, et al. Chinese J. Inorg. Chem., 2018, 34(1):123~128
9. [9]
  CHEN Yan-Min, ZENG Qian-Ru, LI Ying, et al. Chinese J. Inorg. Chem., 2016, 32(8):1398-1404
10. [10]
  Sheldrick G M. SHELXL-97, Program for the Refinement of Crystal Structure, Germany:University of Gottingen, 1997.
11. [11]
  DU Kang-Kai. Journal of Huaqiao University:Natural Science, 2010, 31(5):534-538
1. [1]
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2. [2]
  Hongjie SHEN , Haozhe MIAO , Yuhe YANG , Yinghua LI , Deguang HUANG , Xiaofeng ZHANG . Synthesis, crystal structure, and fluorescence properties of two Cu(Ⅰ) complexes based on pyridyl ligand. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 855-863. doi: 10.11862/CJIC.20250009
3. [3]
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4. [4]
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5. [5]
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6. [6]
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7. [7]
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8. [8]
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9. [9]
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10. [10]
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11. [11]
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12. [12]
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13. [13]
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14. [14]
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15. [15]
  Lifang HE , Wenjie TANG , Yaoze LUO , Mingsheng LIANG , Jianxin TANG , Yuxuan WU , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two dialkyltin complexes constructed based on 2, 2′-bipyridin-6, 6′-dicarboxylic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1601-1609. doi: 10.11862/CJIC.20250012
16. [16]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
17. [17]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
18. [18]
  Xiaogang YANG , Xinya ZHANG , Jing LI , Huilin WANG , Min LI , Xiaotian WEI , Xinci WU , Lufang MA . Synthesis, structure, and photoelectric properties of Zinc(Ⅱ)-triphenylamine based metal-organic framework. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2078-2086. doi: 10.11862/CJIC.20250167
19. [19]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
20. [20]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029

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