Citation: XIE Qing-Fan, CHEN Yan-Min. Syntheses, Crystal Structures, and Characterization of Three Zinc Complexs with Different Acylhydrazone-Type Schiff Base Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(12): 2209-2216. doi: 10.11862/CJIC.2019.267 shu

Syntheses, Crystal Structures, and Characterization of Three Zinc Complexs with Different Acylhydrazone-Type Schiff Base Ligands

XIE Qing-Fan ,
CHEN Yan-Min ^,

College of Chemical Engineering and Material, Quanzhou Normal University, Quanzhou, Fujian 362000, China

Corresponding author: CHEN Yan-Min, QZUCYM@163.com
Received Date: 1 April 2019
Revised Date: 29 October 2019

Figures(8)

Three zinc complexes, namely[Zn(Lss)(phen)(DMF)] (1), {[Zn(HLdis)]₂·2CH₃OH}_n (2) and[Zn(Baf)₂]·CH₃OH (3), formed from different acylhydrazone-type Schiff base ligands were synthesized by using different methods, and the compounds were characterized by IR, UV-Vis spectra and TGA. The X-ray diffraction analyses reveal that 1 and 3 crystallize in the triclinic space group P1 while 2 in monoclinic system space group P2₁/n. In 1 and 3, coordination number of the Zn(Ⅱ) is six, and the centric atom locate in a distorted octahedron geometry, while in 2 Zn(Ⅱ) is five-coordination in a distorted square-pyramidal geometry. The precursor of 3 is pyrazoline derivative with the formula C₁₅H₁₄N₂O₃ (Pzl) crystallizing in monoclinic system space group P2₁/c. Due to the coordination of Zn(Ⅱ) causing the intramolecular rearrangement of Pzl, the ring open product HBaf in the form of an acylhydrazone structure coordinates with Zn(Ⅱ) to form complex 3.
- Schiff base,
- zinc complex,
- crystal structure,
- spectral properties
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