Citation: HU Su-Fang, WANG Yan, MA Jing-Hong, LI Rui-Feng. One-Step Synthesis of High-Silica ZSM-5 in the Absence of Organic Amine[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(12): 2253-2259. doi: 10.11862/CJIC.2019.263 shu

One-Step Synthesis of High-Silica ZSM-5 in the Absence of Organic Amine

College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, China

Corresponding author: MA Jing-Hong, majinghong@tyut.edu.cn
Received Date: 8 May 2019
Revised Date: 30 July 2019

Figures(6)

The plate-like high-silica ZSM-5 zeolite (n_SiO₂/n_Al₂O₃>90) with uniform morphology was synthesized by hydrothermal method at a lower crystallization temperature (130℃) in the absence of organic amine and seed. The effects on ratio of the amount of substance of reactants on the synthesis of high-silica ZSM-5 zeolite were systematically investigated. The synthesized high-silica ZSM-5 zeolite was characterized by XRD, FT-IR, SEM, N₂ adsorption/desorption and ²⁹Si MAS NMR techniques. Results confirmed that the synthesized ZSM-5 zeolite (n_C₂H₅OH/n_SiO₂=2.8, n_Na₂O/n_SiO₂=0.14, n_SiO₂/n_Al₂O₃=150) exhibited high crystallinity of the product. The specific surface area and micropore volume were 409 m²·g^-1 and 0.14 cm³·g^-1. ²⁹Si MAS NMR analysis showed that the n_SiO₂/n_Al₂O₃ was 96.4.
- absence of organic amine,
- ZSM-5 zeolite,
- high-silica,
- hydrothermal synthesis
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