Citation: ZHENG Jin-Le, WU Xiu-Lan, REN Qiang, HAI Ou, REN Yu-Han, ZHAO Yu-Jing, YIN Bo-Jie, YANG En-Long. Luminescent Properities and Energy Transfer of Color Tunable Sr₃Y(BO₃)₃: Tm³⁺, Dy³⁺ Phosphors[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(12): 2226-2232. doi: 10.11862/CJIC.2019.256 shu

Luminescent Properities and Energy Transfer of Color Tunable Sr₃Y(BO₃)₃: Tm³⁺, Dy³⁺ Phosphors

School of Materials Science and Engineering, Shaanxi Key Laboratory of Green Preparation and Functionalization for Inorganic Materials, Shaanxi University of Science and Technology, Xi'an 710021, China

Corresponding author: WU Xiu-Lan, wuxl@sust.edu.cn
Received Date: 7 May 2019
Revised Date: 15 October 2019

Figures(10)

Sr₃Y(BO₃)₃:xTm³⁺, yDy³⁺ phosphors were prepared by high-temperature solid phase reaction. The phase structure, micromorphology, luminescence properties, energy transfer and CIE coordinates of the samples were investigated by XRD diffraction, SEM and fluorescence spectrophotometer. All results indicated that Sr₃Y(BO₃)₃:xTm³⁺ phosphors emitted blue light under the excitation of 359 nm UV light and the Tm³⁺ concentration quenching point was x=0.08(n/n). In Sr₃Y(BO₃)₃:0.08Tm³⁺, yDy³⁺ phosphors, with the Dy³⁺ doping concentration increasing, the Tm³⁺ luminescence intensity decreased; meanwhile, the Dy³⁺ luminescence intensity firstly increased and then decreased, and the critical quenching concentration of Dy³⁺ was y=0.1(n/n). The emitting color could be tuned by changing the doped Dy³⁺ concertration or the excitation wavelength. There is energy transfer between Tm³⁺-Dy³⁺ in the phosphors. When the doping concentration was y=0.15, the energy transfer efficiency was as high as 75.14%, and the energy transfer mechanism is electric dipole-dipole interaction.
- high-temperature solid phase method,
- Sr₃Y(BO₃)₃:xTm³⁺, yDy³⁺,
- fluorescence spectrum,
- color tunable,
- energy transfer
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Luminescent Properities and Energy Transfer of Color Tunable Sr₃Y(BO₃)₃: Tm³⁺, Dy³⁺ Phosphors