Citation: ZHANG Qing-Rui, SONG Ming-Xing, DENG Rui-Ping, ZHOU Liang, ZHANG Hong-Jie. A Unique Luminescence Behavior Based on Polyhedral Oligomeric Silsesquioxane Compounds[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(11): 2177-2184. doi: 10.11862/CJIC.2019.248 shu

A Unique Luminescence Behavior Based on Polyhedral Oligomeric Silsesquioxane Compounds

1.
Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
2.
College of Information Technology, Jilin Normal University, Siping, Jilin 136000, China

Corresponding author: DENG Rui-Ping, dengrp@ciac.ac.cn ZHANG Hong-Jie, hongjie@ciac.ac.cn
Received Date: 15 September 2019
Revised Date: 12 October 2019

Figures(8)

In this study, an unusual luminescence behavior from two polyhedral oligomeric silsesquioxane (POSS) monomers, aminopropyl isobutyl POSS (AIPOSS) and octal isobutyl POSS (OIPOSS) was observed after heating and stirring in their tetrahydrofuran (THF) solution. The chemical structures of these POSS samples were characterized before and after the heat treatment in THF by means of ¹H and ²⁹Si nuclear magnetic resonance (NMR) spectroscopy, and Fourier transform infrared (FTIR) spectroscopy. The valence state of silicon in the POSS sample was determined by X-ray photoelectron spectroscopy (XPS) as well. The characterization results showed that there is no obvious change in their structures, except tiny difference of the ¹H NMR spectra. Photoluminescence (PL) properties of the treated/untreated POSS were studied in detail. According to the PL and structure characterization results, it is speculated that this unusual luminescence from the treated POSS is most likely caused by the adsorption effect of the POSS cage, forming the POSS/solvent adducts, which lead to the change of the electronic structure of the POSS, and consequently the luminescence of the treated POSS.
- polyhedral oligomeric silsesquioxane,
- luminescence,
- adsorption effect
1. [1]
  Scott D W. J. Am. Chem. Soc., 1946, 68(3):356-358 doi: 10.1021/ja01207a003
2. [2]
  Tong Y D, Zhang Y H, Liu Y Y, et al. RSC Adv., 2018, 8(25):13813-13819 doi: 10.1039/C8RA01584H
3. [3]
  Nasab N H, Jalili M M, Farrokhpay S, et al. J. Appl. Polym. Sci., 2018, 135(8):45913 doi: 10.1002/app.45913
4. [4]
  Nguyen T A, Gregersen O W, Mannle F. Polymers, 2015, 7(8):1522-1540 doi: 10.3390/polym7081468
5. [5]
  WANG Chao, GUANG Shan-Yi, XU Hong-Yao. Func. Mater., 2019, 50(7):07071-07018 doi: 10.3969/j.issn.1001-9731.2019.07.013
6. [6]
  Fu B X, Hsiao B S, Pagola S, et al. Polymer, 2001, 42(2):599-611 doi: 10.1016/S0032-3861(00)00389-X
7. [7]
  Carroll J B, Frankamp B L, Rotello V M. Chem. Commun., 2002(17):1892-1893 doi: 10.1039/B203771H
8. [8]
  Dintcheva N T, Morici E, Arrigo R, et al. Express Polym. Lett., 2012, 6(7):561-571 doi: 10.3144/expresspolymlett.2012.59
9. [9]
  Milliman H W, Ishida H, Schiraldi D A. Macromolecules, 2012, 45(11):4650-4657 doi: 10.1021/ma3002214
10. [10]
  Fina A, Monticelli O, Camino G. J. Mater. Chem., 2010, 20(42):9297-9305 doi: 10.1039/c0jm00480d
11. [11]
  Zhang Y D, Lee S H, Yoonessi M, et al. J. Inorg. Orgnomet. Polym. Mater., 2007, 17(1):159-171 doi: 10.1007/s10904-006-9074-3
12. [12]
  Liu H, Zhu Q, Feng L, et al. Mol. Struct., 2013, 1032:29-34 doi: 10.1016/j.molstruc.2012.07.045
13. [13]
  Solouk A, Cousins B G, Mirahmadi F, et al. Mater. Sci. Eng. C-Mater., 2015, 46:400-408 doi: 10.1016/j.msec.2014.10.065
14. [14]
  Wang C Y, Chen W T, Xu C, et al. Chinese J. Polym. Sci., 2016, 34(11):1363-1372 doi: 10.1007/s10118-016-1845-x
15. [15]
  Sharma A K, Sloan R, Ramakrishnan R, et al. Polymer, 2018, 139:201-212 doi: 10.1016/j.polymer.2018.02.014
16. [16]
  Ni Y, Zheng S X, Nie K M. Polymer, 2004, 45:5557-5568 doi: 10.1016/j.polymer.2004.06.008
17. [17]
  Verker R, Grossman E, Eliaz N. Acta Mater., 2009, 57(4):1112-1119 doi: 10.1016/j.actamat.2008.10.054
18. [18]
  Wu Y R, Wu Y C, Kuo S W. Macromol. Chem. Phys., 2013, 214(13):1496-1503 doi: 10.1002/macp.201300251
19. [19]
  Matsuno H, Tsukamoto R, Shimomura S, et al. Polymer J., 2016, 48(4):413-419 doi: 10.1038/pj.2015.118
20. [20]
  Michalowski S, Hebda E, Pielichowski K. J. Therm. Anal. Calorim., 2017, 130(1):155-163 doi: 10.1007/s10973-017-6391-4
21. [21]
  Jeon J E, Kim H H, Jo N J. J. Nanosci. Nanotechno., 2019, 19(3):1463-1469 doi: 10.1166/jnn.2019.16244
22. [22]
  Takala M, Karttunen M, Pelto J, et al. IEEE Trans. Dielectr. Electr. Insul., 2008, 15(5):1224-1235 doi: 10.1109/TDEI.2008.4656229
23. [23]
  Liu K, Lu S R, Li S R, et al. Iran Polym. J., 2012, 21(3):497-503
24. [24]
  Kumar B P, Vijaykumar B V D, Raghavan C M, et al. J. Mater. Sci., 2013, 48(21):7533-7539 doi: 10.1007/s10853-013-7568-2
25. [25]
  Lee C W, Josse Y, Hsu C H, et al. Eur. Phys. J.-Appl. Phys., 2008, 42(6):213-218
26. [26]
  Li J, Xie B, Xia K, et al. Opt. Mater., 2018, 78:279-284 doi: 10.1016/j.optmat.2018.01.050
27. [27]
  HU Hao, LI Ying. Nonfer. Met. Mater. Eng., 2018, 39(2):23-27
28. [28]
  Zhao Y L, Qiu X L, Yu T Z, et al. Inorg. Chim. Acta, 2016, 445:134-139 doi: 10.1016/j.ica.2016.02.031
29. [29]
  Mohamed M G, Hsu K C, Hong J L, et al. Polym. Chem., 2016, 7(1):135-145 doi: 10.1039/C5PY01537E
30. [30]
  Mohamed M G, Jheng Y R, Yeh S L, et al. Polymers, 2017, 9(3):103
31. [31]
  Dasog M, Yang Z Y, Regli S, et al. ACS Nano, 2013, 7(3):2676-2685 doi: 10.1021/nn4000644
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