Citation: HAN Xiao, SHAO Zhichao, ZHAO Bei, REN Ning, MENG Xiang-Ru, DING Jie, HOU Hong-Wei. Synthesis, Crystal Structure, Magnetic Properties and Catalytic Activity of Co(Ⅱ)/Ni(Ⅱ) Complexes with 3, 3'-(Pyridine-3, 5-diyl) Dibenzoic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(11): 2159-2167. doi: 10.11862/CJIC.2019.241 shu

Synthesis, Crystal Structure, Magnetic Properties and Catalytic Activity of Co(Ⅱ)/Ni(Ⅱ) Complexes with 3, 3'-(Pyridine-3, 5-diyl) Dibenzoic Acid

HAN Xiao ^1,2 ,
SHAO Zhichao ² ,
ZHAO Bei ² ,
REN Ning ¹ ,
MENG Xiang-Ru ² ,
DING Jie ² ,
HOU Hong-Wei ^2,,

1.
Hebei Key Laboratory of Heterocyclic Compounds, College of Chemical engineering & Material, Handan University, Handan, Hebei 056005, China
2.
College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, China

Corresponding author: HOU Hong-Wei, houhongw@zzu.edu.cn
Received Date: 11 September 2019
Revised Date: 2 October 2019

Figures(8)

Two complexes 1~2 (1={[Co₂(pddb)₂(μ₂-H₂O)(H₂O)₂]·2DMA·5H₂O}_n and 2={[Ni₂(pddb)₂(μ₂-H₂O)(H₂O)₂]·2DMA·5H₂O}_n, H₂pddb=3, 3'-(pyridine-3, 5-diyl) dibenzoic acid, DMA=N, N-dimethylacetamide) have been synth-esized and identified by Infrared spectroscopy (IR), elemental analysis, thermogravimetric analysis (TG) and single crystal X-ray diffraction. Structural analyses show that 1 and 2 are isostructural, and display a 3D (3, 6)-connected net with the point symbol (4²·6)·(4⁴·6²·8⁸·10). Besides, the UV-Vis absorption spectra in solid state, the magnetic properties and catalytic activity of 1~2 were investigated. Between the proximal Co(Ⅱ)/Ni(Ⅱ) ions, the variable-temperature (2~300 K) magnetic susceptibilities of 1~2 display antiferromagnetic coupling. Furthermore, 1 have been verified to be effectual catalysts for the oxidation of arylacycloalkanes in aqueous medium.
- 3, 3'-(pyridine-3, 5-diyl) dibenzoic acid,
- complex,
- crystal structure,
- magnetic property,
- heterogeneous catalyst
1. [1]
  Zhang J, Li B D, Wu X J, et al. J. Mol. Struct., 2010, 984:276-281 doi: 10.1016/j.molstruc.2010.09.040
2. [2]
  Shen P P, Ren N, Zhang J J, et al. J. Therm. Anal. Calorim., 2019, 135:2687-2695 doi: 10.1007/s10973-018-7265-0
3. [3]
  Fan Y R, Li H B, Jia Z Y, et al. Inorg. Chem. Commun., 2019, 102:229-232 doi: 10.1016/j.inoche.2019.02.037
4. [4]
  Xing Y B, Liu Y Q, Meng B F, et al. J. Chem. Crystallogr., 2019:1-8
5. [5]
  Wu Y P, Xu G W, Dong W W, et al. Inorg. Chem., 2017, 56:1402-1411 doi: 10.1021/acs.inorgchem.6b02476
6. [6]
  Ma K, Zhao Y N, Han X, et al. Cryst. Growth Des., 2018, 18:7419-7425 doi: 10.1021/acs.cgd.8b01113
7. [7]
  Maity D K, Dey A, Ghosh S, et al. Inorg. Chem., 2018, 57:251-263 doi: 10.1021/acs.inorgchem.7b02435
8. [8]
  Shao Z C, Han X, Liu Y Y, et al. Dalton Trans., 2019, 48:6191-6197 doi: 10.1039/C9DT00968J
9. [9]
  Sun Y Y, Wang F, Zhang J. Inorg. Chem., 2019, 58:4076-4079 doi: 10.1021/acs.inorgchem.9b00261
10. [10]
  Zhao B, Li H J, Jia Y Y, et al. Polyhedron, 2014, 68:138-143 doi: 10.1016/j.poly.2013.10.022
11. [11]
  WANG Gui-Xian, CAO Ke-Li, CHEN Fei-Yan, et al. Chinese J. Inorg. Chem., 2016, 32: 43-48
12. [12]
  LIN Jian-Jun, LIU Zhen, LÜ Ling-Zhi, et al. Chinese J. Inorg. Chem., 2018, 34: 230-236
13. [13]
  Zhao L, Zhang J, Wang J, et al. J. Solid State Chem., 2018, 268:1-8 doi: 10.1016/j.jssc.2018.08.028
14. [14]
  Liu L, Huang C, Xue X, et al. Cryst. Growth Des., 2015, 15:4507-4517 doi: 10.1021/acs.cgd.5b00757
15. [15]
  Corma A, García H, Xamena F X L I. Chem. Rev., 2010, 110:4606-4655 doi: 10.1021/cr9003924
16. [16]
  Yoon M, Srirambalaji R, Kim K. Chem. Rev., 2012, 112:1196-1231 doi: 10.1021/cr2003147
17. [17]
  Zhao M, Ou S, Wu C D. Acc. Chem. Res., 2014, 47:1199-1207 doi: 10.1021/ar400265x
18. [18]
  Liu J, Chen L, Cui H, et al. Chem. Soc. Rev., 2014, 43:6011-6061 doi: 10.1039/C4CS00094C
19. [19]
  Dhakshinamoorthy A, Asiri A M, Garcia H. Chem. Soc. Rev., 2015, 44:1922-1947 doi: 10.1039/C4CS00254G
20. [20]
  Zhu Q L, Xu Q. Chem. Soc. Rev., 2014, 43:5468-5512 doi: 10.1039/C3CS60472A
21. [21]
  Wang H R, Meng W, Wu J, et al. Coord. Chem. Rev., 2016, 307:130-146 doi: 10.1016/j.ccr.2015.05.009
22. [22]
  Park S S, Hontz E R, Sun L, et al. J. Am. Chem. Soc., 2015, 137:1774-1777 doi: 10.1021/ja512437u
23. [23]
  Chughtai A H, Ahmad N, Younus A Y, et al. Chem. Soc. Rev., 2015, 44:6804-6849 doi: 10.1039/C4CS00395K
24. [24]
  Yao H F, Yang Y, Liu H, et al. J. Mol. Catal. A:Chem., 2014, 394:57-65 doi: 10.1016/j.molcata.2014.06.040
25. [25]
  Guo L, Huang C, Liu L, et al. Cryst. Growth Des., 2016, 16:4926-4933 doi: 10.1021/acs.cgd.6b00494
26. [26]
  Shaabani A, Farhangi E, Rahmati A. Appl. Catal. A, 2008, 338:14-19 doi: 10.1016/j.apcata.2007.12.014
27. [27]
  Hossain M M, Shyu S. Tetrahedron, 2016, 72:4252-4257 doi: 10.1016/j.tet.2016.05.066
28. [28]
  Gao K, Huang C, Yang Y, et al. Cryst. Growth Des., 2019, 19:976-982 doi: 10.1021/acs.cgd.8b01527
29. [29]
  SAINT, Bruker AXS, Inc., Madison, WI, 2001.
30. [30]
  Sheldrick G M. SADABS, University of Göttingen, Germany, 2003.
31. [31]
  Sheldrick G M. Acta Crystallogr. Sect. A:Found. Crystallogr., 2008, A64:112-122
32. [32]
  Liu P P, Wang C Y, Zhang M, et al. Polyhedron, 2017, 129:133-140 doi: 10.1016/j.poly.2017.03.019
33. [33]
  Zhou S B, Wang X F, Du C C, et al. CrystEngComm, 2017, 19:3124-3137 doi: 10.1039/C7CE00394C
34. [34]
  Yan W, Han L J, Jia H L, et al. Inorg. Chem., 2016, 55:8816-8821 doi: 10.1021/acs.inorgchem.6b01328
35. [35]
  Fan C, Zong Z, Zhang X, et al. CrystEngComm, 2018, 20:4973-4988 doi: 10.1039/C8CE00868J
36. [36]
  Li D S, Zhao J, Wu Y P, et al. Inorg. Chem., 2013, 52:8091-8098 doi: 10.1021/ic4007718
37. [37]
  Zeng M H, Zhou Y L, Wu M C, et al. Inorg. Chem., 2010, 49:6436-6442 doi: 10.1021/ic100021f
38. [38]
  Qin J, Jia Y, Li H, et al. Inorg. Chem., 2014, 53:685-687 doi: 10.1021/ic402598p
39. [39]
  Wang X, Liu M, Wang Y, et al. Inorg. Chem., 2017, 56:13329-13336 doi: 10.1021/acs.inorgchem.7b02106
1. [1]
  Xiaoling WANG , Hongwu ZHANG , Daofu LIU . Synthesis, structure, and magnetic property of a cobalt(Ⅱ) complex based on pyridyl-substituted imino nitroxide radical. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 407-412. doi: 10.11862/CJIC.20240214
2. [2]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
3. [3]
  Lulu DONG , Jie LIU , Hua YANG , Yupei FU , Hongli LIU , Xiaoli CHEN , Huali CUI , Lin LIU , Jijiang WANG . Synthesis, crystal structure, and fluorescence properties of Cd-based complex with pcu topology. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 809-820. doi: 10.11862/CJIC.20240171
4. [4]
  Yinling HOU , Jia JI , Hong YU , Xiaoyun BIAN , Xiaofen GUAN , Jing QIU , Shuyi REN , Ming FANG . A rhombic Dy₄-based complex showing remarkable single-molecule magnet behavior. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 605-612. doi: 10.11862/CJIC.20240251
5. [5]
  Shuyan ZHAO . Field-induced Co^Ⅱ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
6. [6]
  Shenhao QIU , Qingquan XIAO , Huazhu TANG , Quan XIE . First-principles study on electronic structure, optical and magnetic properties of rare earth elements X (X=Sc, Y, La, Ce, Eu) doped with two-dimensional GaSe. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2250-2258. doi: 10.11862/CJIC.20240104
7. [7]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
8. [8]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
9. [9]
  Yao HUANG , Yingshu WU , Zhichun BAO , Yue HUANG , Shangfeng TANG , Ruixue LIU , Yancheng LIU , Hong LIANG . Copper complexes of anthrahydrazone bearing pyridyl side chain: Synthesis, crystal structure, anticancer activity, and DNA binding. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 213-224. doi: 10.11862/CJIC.20240359
10. [10]
  Jia JI , Zhaoyang GUO , Wenni LEI , Jiawei ZHENG , Haorong QIN , Jiahong YAN , Yinling HOU , Xiaoyan XIN , Wenmin WANG . Two dinuclear Gd(Ⅲ)-based complexes constructed by a multidentate diacylhydrazone ligand: Crystal structure, magnetocaloric effect, and biological activity. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 761-772. doi: 10.11862/CJIC.20240344
11. [11]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
12. [12]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
13. [13]
  Xiumei LI , Linlin LI , Bo LIU , Yaru PAN . Syntheses, crystal structures, and characterizations of two cadmium(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 613-623. doi: 10.11862/CJIC.20240273
14. [14]
  Yukun CHEN , Kexin FENG , Bolun ZHANG , Wentao SONG , Jianjun ZHANG . Syntheses, crystal structures, and diametrically opposed mechanically-stimulated luminescence response of two Mg(Ⅱ) metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1227-1234. doi: 10.11862/CJIC.20240448
15. [15]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
16. [16]
  Yan XU , Suzhi LI , Yan LI , Lushun FENG , Wentao SUN , Xinxing LI . Structure variation of cadmium naphthalene-diphosphonates with the changing rigidity of N-donor auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 395-406. doi: 10.11862/CJIC.20240226
17. [17]
  Zhaodong WANG . In situ synthesis, crystal structure, and magnetic characterization of a trinuclear copper complex based on a multi-substituted imidazo[1,5-a]pyrazine scaffold. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 597-604. doi: 10.11862/CJIC.20240268
18. [18]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
19. [19]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
20. [20]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(1067)
HTML views(49)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142