Citation: GENG Cong, ZHENG Hui, CHEN Yu-Ting, JIANG Jian-Zhuang. Receptor Influence on Sensing Performance of Metal-Free Porphyrin Sensor[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(11): 2152-2158. doi: 10.11862/CJIC.2019.235 shu

Receptor Influence on Sensing Performance of Metal-Free Porphyrin Sensor

1.
Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, Beijing 100083, China
2.
Department of Chemistry, Dezhou University, Dezhou, Shandong 253023, China

Corresponding author: CHEN Yu-Ting, ch_yt@126.com JIANG Jian-Zhuang, jianzhuang@ustb.edu.cn
Received Date: 4 September 2019
Revised Date: 25 September 2019

Figures(5)

The optical properties of a metal-free tetra(aryl)porphyrin with two N, N-di(2-pyridylmethyl)amino groups (Porphyrin-2-DPA) upon respective addition of different metal ion were investigated. Systemic studies show that the rigid π-conjugated tetrapyrrole macrocyclic moiety of Porphyrin-2-DPA is employed not only as the sensitive signaling fluorophore but also as the primary receptor with excellent binding affinity and distinctive selectivity to metal ion, which together with the no-conjugated DPA auxiliary receptor endows Porphyrin-2-DPA the sensitive versatile sensor to Pb²⁺/Cu²⁺ on the basis of dual-optical signals.
- fluorescent probe,
- porphyrin,
- N, N-di(2-pyridylmethyl)amino group (DPA),
- cations,
- dual-analytes,
- multi-signals
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沈阳化工大学材料科学与工程学院沈阳 110142