Citation: BAI Yu-Lin, WANG Cheng, WU Yue, LIU Yu-Si, MA Chao, CAI Zhi-Peng, WANG Kai-Xue, CHEN Jie-Sheng. Preparation and Performance for Lithium Storage of Core-Shell-Structured MoO_x/C Microspheres[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(11): 2045-2050. doi: 10.11862/CJIC.2019.233 shu

Preparation and Performance for Lithium Storage of Core-Shell-Structured MoO_x/C Microspheres

BAI Yu-Lin ¹ ,
WANG Cheng ¹ ,
WU Yue ² ,
LIU Yu-Si ¹ ,
MA Chao ¹ ,
CAI Zhi-Peng ¹ ,
WANG Kai-Xue ^1,, ,
CHEN Jie-Sheng ¹

1.
School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China
2.
Faculty of Engineering, China University of Petroleum-Beijing at Karamay, Karamay, Xinjiang 834000, China

Corresponding author: WANG Kai-Xue, k.wang@sjtu.edu.cn
Received Date: 10 July 2019
Revised Date: 11 September 2019

Figures(5)

Core-shell-structured MoO_x/C microspheres were prepared through the calcination of a MoO₃/resin precursor obtained by a hydrothermal method. Upon calcination, carbonized resin reduced hexagonal MoO₃ into monoclinic MoO₂. A small amount of monoclinic MoO₂ was further oxidized to orthorhombic MoO₃, forming core-shell MoO_x/C microspheres. The hierarchical MoO_x/C microspheres showed excellent electrochemical lithium storage performance when used as an anode material for lithium-ion batteries. High reversible capacities of 640.6 mAh· g^-1 was maintained at 100 mA·g^-1 after 100 cycles, demonstrating the high reversible capacity and excellent cycle performance of the MoO_x/C microspheres for lithium storage.
- lithium ion battery,
- MoO₂,
- MoO₃,
- electrochemical performance
1. [1]
  Dunn B, Kamath H, Tarascon J M. Science, 2011, 334:928-935 doi: 10.1126/science.1212741
2. [2]
  Cao K Z, Jin T, Yang L, et al. Mater. Chem. Front., 2017, 1(11):2213-2242 doi: 10.1039/C7QM00175D
3. [3]
  Hu X L, Zhang W, Liu X X, et al. Chem. Soc. Rev., 2015, 44(8):2376-2404 doi: 10.1039/C4CS00350K
4. [4]
  Tang K, Farooqi S A, Wang X F, et al. ChemSusChem, 2019, 12(4):755-771 doi: 10.1002/cssc.201801860
5. [5]
  Zhang J, Zhou L, Sun Q J, et al. Chem. Eur. J., 2019, 25(37):8813-8819
6. [6]
  Meng T, Qin J W, Yang Z, et al. J. Mater. Chem. A, 2019, 7(29):17570-17580 doi: 10.1039/C9TA04774C
7. [7]
  CUI Ping, LIANG Ying, SUN Yong-Lin. Chinese J. Inorg. Chem., 2012, 28(9):1861-1866
8. [8]
  ZHONG Yan-Jun, WU Zhen-Guo, TIAN Hai, et al. Chinese J. Inorg. Chem., 2018, 34(8):1581-1589
9. [9]
  Zhang H J, Wu T H, Wang K X, et al. J. Mater. Chem. A, 2013, 1(39):12001-12372 doi: 10.1039/c3ta90245e
10. [10]
  Wang P X, Zhang Y, Yin Y Y, et al. Chem. Eng. J., 2018, 334:257-263 doi: 10.1016/j.cej.2017.10.009
11. [11]
  Wang Y W, Yu L, Lou X W. Angew. Chem. Int. Ed., 2016, 55(47):14668-14672 doi: 10.1002/anie.201608410
12. [12]
  Yang L C, Sun W, Zhong Z W, et al. J. Power Sources, 2016, 306:78-84 doi: 10.1016/j.jpowsour.2015.11.073
13. [13]
  Zhang X J, Fu C L, Li J L, et al. Ceram. Int., 2017, 43(4):3769-3773 doi: 10.1016/j.ceramint.2016.12.018
14. [14]
  Wang K X, Li X H, Chen J S. Adv. Mater., 2015, 27(3):527-545 doi: 10.1002/adma.201402962
15. [15]
  Pathak A, Gangan A S, Ratha S, et al. J. Phys. Chem. C, 2017, 121(35):18992-19001 doi: 10.1021/acs.jpcc.7b04478
16. [16]
  Yang X, Li Q, Wang H J, et al. Chem. Eng. J., 2018, 337:74-81 doi: 10.1016/j.cej.2017.12.072
17. [17]
  Wang C L, Sun L S, Zhang F F, et al. Small, 2017, 13(32):1701246 doi: 10.1002/smll.201701246
18. [18]
  Bai Y L, Liu W X, Yu C H, et al. J. Phys. Chem. C, 2016, 120(5):2984-2992 doi: 10.1021/acs.jpcc.5b10222
19. [19]
  Zhu Q C, Xu S M, Harris M M, et al. Adv. Funct. Mater., 2016, 26(46):8514-8520 doi: 10.1002/adfm.201603462
20. [20]
  Scanlon D O, Watson G W, Payne D J, et al. J. Phys. Chem. C, 2010, 114(10):4636-4645 doi: 10.1021/jp9093172
21. [21]
  Qing M Q, Meng Y, Wang Y J, et al. Electrochim. Acta, 2019, 319:740-752 doi: 10.1016/j.electacta.2019.07.017
22. [22]
  Ni J F, Zhao Y, Li L, et al. Nano Energy, 2015, 11:129-135 doi: 10.1016/j.nanoen.2014.10.027
23. [23]
  Zhou J B, Lin N, Wang L B, et al. J. Mater. Chem. A, 2015, 3(14):7463-7468 doi: 10.1039/C5TA00516G
24. [24]
  Wang W, Shi G G, Cai H J, et al. J. Alloys Compd., 2019, 792:191-202 doi: 10.1016/j.jallcom.2019.03.401
25. [25]
  Su Y B, Tong R A, Zhang H J, et al. J. Alloys Compd., 2019, 787:295-300 doi: 10.1016/j.jallcom.2019.02.051
26. [26]
  Herdt T, Bruns M, Schneider J J. Dalton Trans., 2018, 47(42):14897-14907 doi: 10.1039/C8DT02076K
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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Performance for Lithium Storage of Core-Shell-Structured MoOx/C Microspheres

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通讯作者: 陈斌, bchen63@163.com

Preparation and Performance for Lithium Storage of Core-Shell-Structured MoO_x/C Microspheres