Citation: WANG Lan, WEI Zhi-Li, YU Meng, PAN Ying-Qi, ZHANG Yang, DONG Wen-Kui. Multihalogen-Substituted Salamo-Type Mn(Ⅱ) Complexes: Syntheses, Crystal Structures, Hirshfeld Analyses and Fluorescence Properties[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(10): 1791-1804. doi: 10.11862/CJIC.2019.212 shu

Multihalogen-Substituted Salamo-Type Mn(Ⅱ) Complexes: Syntheses, Crystal Structures, Hirshfeld Analyses and Fluorescence Properties

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, China

Corresponding author: DONG Wen-Kui, dongwk@126.com
Received Date: 15 January 2019
Revised Date: 6 August 2019

Figures(16)

Two manganese(Ⅱ) complexes[Mn(L¹)(H₂O)₂] (1) and[Mn(L²)(H₂O)₂]·0.37H₂O (2) were synthesized by the reactions of halogen-substituted salamo-type bisoxime ligands H₂L¹, H₂L¹ with manganese(Ⅱ) acetate tetrahydrate in organic solvents, and the two complexes were characterized by the means of elemental analyses, FT-IR, UV-visible absorption spectra, single-crystal X-ray diffractions, fluorescence spectra and Hirshfeld surfaces analyses. X-ray crystallography results indicated that the manganese(Ⅱ) ions in the two complexes are all six-coordinated, in which the N₂O₂ of the salamo-type ligand occupied the planar position, and two coordinated water molecules occupied the axial positions, forming distorted octahedral coordination geometries. Due to abundant hydrogen bonding interactions, infinite 1D and 2D supramolecular structures are formed in complexes 1 and 2, respectively.
- samalo-type ligand,
- complex,
- synthesis,
- fluorescence property,
- Hirshfeld surface analysis
1. [1]
  Liu P P, Wang C Y, Zhang M, et al. Polyhedron, 2017, 129:133-140 doi: 10.1016/j.poly.2017.03.019
2. [2]
  Song X Q, Liu P P, Liu Y A, et al. Dalton Trans., 2016, 45:8154-8163 doi: 10.1039/C6DT00212A
3. [3]
  Subramaniam P, Anbarasan S, Devi S S, et al. Polyhedron, 2016, 119:14-22
4. [4]
  Akine S, Miyashita M, Piaob S, et al. Inorg. Chem. Front., 2014, 1:53-57 doi: 10.1039/C3QI00067B
5. [5]
  Dong X Y, Zhao Q, Kang Q P, et al. Crystals, 2018, 8:230 doi: 10.3390/cryst8050230
6. [6]
  Zhang L W, Li X Y, Kang Q P, et al. Crystals, 2018, 8:173 doi: 10.3390/cryst8040173
7. [7]
  Li X Y, Kang Q P, Liu L Z. Crystals, 2018, 8:43 doi: 10.3390/cryst8010043
8. [8]
  Peng Y D, Li X Y, Kang Q P, et al. Crystals, 2018, 8:1079
9. [9]
  Peng Y D, Wang F, Gao L, et al. J. Chin. Chem. Soc., 2018, 65:893-899 doi: 10.1002/jccs.201800038
10. [10]
  Li X Y, Chen L, Gao L, et al. RSC Adv., 2017, 7:35905-35916 doi: 10.1039/C7RA06796H
11. [11]
  Xu L, Li N, Zhao L. Z. Kristallogr.:New Cryst. Struct., 2016, 231:967-968
12. [12]
  Li L H, Dong W K, Zhang Y, et al. Appl. Organomet. Chem., 2017, e3818
13. [13]
  Chin T K, Endud S, Jamil S, et al. Catal. Lett., 2013, 143:282-288 doi: 10.1007/s10562-012-0959-1
14. [14]
  Gao L, Liu C, Wang F, et al. Crystals, 2018, 8:77 doi: 10.3390/cryst8020077
15. [15]
  Wu H L, Bai Y H, Zhang Y H, et al. Z. Anorg. Allg. Chem., 2014, 640:2062-2071 doi: 10.1002/zaac.201400109
16. [16]
  Wu H L, Pan G L, Wang H, et al. J. Photochem. Photobiol. B, 2014, 135:33-43 doi: 10.1016/j.jphotobiol.2014.04.005
17. [17]
  Wu H L, Pan G L, Bai Y C, et al. J. Chem. Res., 2014, 38:211-217 doi: 10.3184/174751914X13933417974082
18. [18]
  Wu H L, Bai Y C, Zhang Y H, et al. J. Coord. Chem., 2014, 67:3054-3066 doi: 10.1080/00958972.2014.959507
19. [19]
  Wang F, Xu Y L, Aderinto S O, et al. J. Photochem. Photobiol. A, 2017, 332:273-282 doi: 10.1016/j.jphotochem.2016.09.004
20. [20]
  Wu H L, Wang H, Wang X L, et al. New J. Chem., 2014, 38:1052-1061 doi: 10.1039/c3nj01145c
21. [21]
  Wu H L, Pan G L, Bai Y C, et al. Res. Chem. Intermed., 2015, 41:3375-3388 doi: 10.1007/s11164-013-1440-5
22. [22]
  Hao J, Li X Y, Wang L, et al. Spectrochim. Acta Part A, 2018, 204:388-402 doi: 10.1016/j.saa.2018.06.074
23. [23]
  Wang L, Hao J, Zhai L X, et al. Crystals, 2017, 7:277 doi: 10.3390/cryst7090277
24. [24]
  Ömer S, Ümmühan Ö Ö, Nurgul S, et al. Tetrahedron, 2016, 72:5843-5852 doi: 10.1016/j.tet.2016.08.004
25. [25]
  Li J, Zhang H J, Chang J, et al. Crystals, 2018, 8:176 doi: 10.3390/cryst8040176
26. [26]
  Chai L Q, Zhang K Y, Tang L J, et al. Polyhedron, 2017, 130:100-107 doi: 10.1016/j.poly.2017.04.010
27. [27]
  Dong X Y, Li X Y, Liu L Z, et al. RSC Adv., 2017, 7:48394-48403 doi: 10.1039/C7RA07826A
28. [28]
  Jia H R, Chang J, Zhang H J, et al. Crystals, 2018, 8:272 doi: 10.3390/cryst8070272
29. [29]
  Chen L, Dong W K, Zhang H, et al. Cryst. Growth Des., 2017, 17:3636-3648 doi: 10.1021/acs.cgd.6b01860
30. [30]
  Zhang L W, Liu L Z, Wang F, et al. Molecules, 2018, 23:1141 doi: 10.3390/molecules23051141
31. [31]
  Dong X Y, Zhao Q, Wei Z L, et al. Molecules, 2018, 23:1006 doi: 10.3390/molecules23051006
32. [32]
  Chai L Q, Tang L J, Chen L C, et al. Polyhedron, 2017, 122:228-240 doi: 10.1016/j.poly.2016.11.032
33. [33]
  Dong W K, Li X L, Wang L, et al. Sens. Actuators B, 2016, 229:370-378 doi: 10.1016/j.snb.2016.01.139
34. [34]
  Wang B J, Dong W K, Zhang Y, et al. Sens. Actuators B, 2017, 247:254-264 doi: 10.1016/j.snb.2017.02.154
35. [35]
  Wang F, Gao L, Zhao Q, et al. Spectrochim. Acta Part A, 2018, 190:111-115 doi: 10.1016/j.saa.2017.09.027
36. [36]
  Dong Y J, Li X L, Zhang Y, et al. Supramol. Chem., 2017, 29:518-527 doi: 10.1080/10610278.2017.1285031
37. [37]
  Hao J, Li X Y, Zhang Y, et al. Materials, 2018, 11:523 doi: 10.3390/ma11040523
38. [38]
  Dong W K, Akogun S F, Zhang Y, et al. Sens. Actuators B, 2017, 238:723-734 doi: 10.1016/j.snb.2016.07.047
39. [39]
  Dong W K, Ma J C, Zhu L C, et al. Cryst. Growth Des., 2016, 16:6903-6914 doi: 10.1021/acs.cgd.6b01067
40. [40]
  Wang L, Li X Y, Zhao Q, et al. RSC Adv., 2017, 7:48730-48737 doi: 10.1039/C7RA08789F
41. [41]
  Dong W K, Li G, Wang Z K, et al. Spectrochim. Acta Part A, 2014, 133:340-347 doi: 10.1016/j.saa.2014.04.190
42. [42]
  Hao J, Li L H, Zhang J T, et al. Polyhedron, 2017, 134:1-10 doi: 10.1016/j.poly.2017.05.060
43. [43]
  Zhang H, Dong W K, Zhang Y, et al. Polyhedron, 2017, 133:279-293 doi: 10.1016/j.poly.2017.05.051
44. [44]
  Ma J C, Dong X Y, Dong W K, et al. J. Coord. Chem., 2016, 69:149-159 doi: 10.1080/00958972.2015.1108410
45. [45]
  Hao J, Liu L Z, Dong W K, et al. J. Coord. Chem., 2017, 70:1936-1952 doi: 10.1080/00958972.2017.1324152
46. [46]
  YANG Yu-Hua, HAO Jing, DONG Yin-Juan, et al. Chinese. J. Inorg. Chem., 2017, 33:1280-1292 doi: 10.11862/CJIC.2017.150
47. [47]
  Akine S, Taniguchi T, Saiki T, et al. J. Am. Chem. Soc., 2005, 127:540-541 doi: 10.1021/ja046790k
48. [48]
  Zhao Q, Wei Z L, Kang Q P, et al. Spectrochim. Acta Part A, 2018, 203:472 doi: 10.1016/j.saa.2018.06.007
49. [49]
  Dong W K, Zheng S S, Zhang J T, et al. Spectrochim. Acta Part A, 2017, 184:141-150 doi: 10.1016/j.saa.2017.04.061
50. [50]
  ZHANG Hong-Jia, CHANG Jian, JIA Hao-Ran, et al. Chinese J. Inorg. Chem., 2018, 34:2261-2270 doi: 10.11862/CJIC.2018.261
51. [51]
  CHANG Jian, ZHANG Hong-Jia, JIA Hao-Ran, et al. Chinese J. Inorg. Chem., 2018, 34:2097-2107 doi: 10.11862/CJIC.2018.256
52. [52]
  Dong W K, Sun Y X, Zhao C Y, et al. Polyhedron, 2010, 29:2087-2097 doi: 10.1016/j.poly.2010.04.006
53. [53]
  Dong X Y, Wang L, Yang Y H, et al. Asian J. Chem., 2013, 8:4289-4292
54. [54]
  Dong W K, Zhao C Y, Sun Y X, et al. Inorg. Chem. Commu., 2009, 12:234-236 doi: 10.1016/j.inoche.2008.12.019
55. [55]
  Zheng S S, Dong W K, Zhang Y, et al. New J. Chem., 2017, 41:4966-4973 doi: 10.1039/C6NJ04090J
56. [56]
  Dong W K, Lan P F, Zhou W M, et al. J. Coord. Chem., 2016, 69:1272-1283 doi: 10.1080/00958972.2016.1168520
57. [57]
  Wang L, Dong X Y, Zhao L, et al. Asian J. Chem., 2013, 6:3440-3442
58. [58]
  Sheldrick G M. Acta Crystallogr. Sect. A:Found. Crystallogr., 2008, A64:112-122
59. [59]
  WANG Li, KANG Quan-Peng, HAO Jing, et al. Chinese J. Inorg. Chem., 2018, 34:525-533 doi: 10.11862/CJIC.2018.035
60. [60]
  Dong X Y, Gao L, Wang F, et al. Crystals, 2017, 7:267 doi: 10.3390/cryst7090267
61. [61]
  Dong W K, Ma J C, Dong Y J, et al. Polyhedron, 2016, 115:228-235 doi: 10.1016/j.poly.2016.05.017
62. [62]
  Gao L, Wang F, Zhao Q, et al. Polyhedron, 2018, 139:7-16 doi: 10.1016/j.poly.2017.10.004
63. [63]
  Ghosh K, Harms K, Chattopadhyay S. Polyhedron, 2017, 123:162-175 doi: 10.1016/j.poly.2016.10.027
64. [64]
  Wang F, Liu L Z, Gao L, et al. Spectrochim. Acta Part A, 2018, 203:56-64 doi: 10.1016/j.saa.2018.05.088
65. [65]
  Kang Q P, Li X Y, Zhao Q, et al. Appl. Organomet. Chem., 2018, 32:e4379 doi: 10.1002/aoc.4379
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