Citation: LI Jiang, HAN Sen, CHEN Tuan-Jie, GOU Zhao-Xi, ZHANG Qi, NIE Xiao-Sahuang, CAO Hai-Ru. Two Homologous Metal-Organic Frameworks Based on Zn(Ⅱ) and Cd(Ⅱ): Luminescent Sensors for Nitro Aromatic Compounds in Solution and Vapor Medium[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(10): 1843-1852. doi: 10.11862/CJIC.2019.204 shu

Two Homologous Metal-Organic Frameworks Based on Zn(Ⅱ) and Cd(Ⅱ): Luminescent Sensors for Nitro Aromatic Compounds in Solution and Vapor Medium

1.
School of Materials Science and Engineering, Chang'an University, Xi'an 710064, China
2.
CCCC Fisrt Highway Consultans Co., Ltd., Xi'an 710062, China

Corresponding author: LI Jiang, lijiang@chd.edu.cn
Received Date: 26 April 2019
Revised Date: 8 July 2019

Figures(7)

Two homologous luminescent metal-organic frameworks (LMOFs), [Cd₂(DDCPB)(DMF)₂(H₂O)]_n (CHD-1) and {[Zn₂(DDCPB)(DMA)₂]·DMA}_n (CHD-2) (H₄DDCPB=1, 1':3', 1″-terphenyl-3, 3″, 5, 5″-tetracarboxylic acid), were constructed to explore sensing mechanisms for series of nitro aromatic compounds (NACs). Among various kinds of organic compounds, both CHD-1 and CHD-2 only respond to a series of nitro aromatic compounds through luminescence quenching with distinct analytes concentration in vapor and liquid phase. Quantitative experiments in solution were conducted to confirm the higher dynamic quenching efficiency and to calculate the quenching constants. Meanwhile, both CHD-1 and CHD-2 show high selectivity and excellent sensitivity for NACs with low detection limits in solution. Moreover, the film based on the MOFs sample identifies high sensitivity towards nitrobenzene (NB) and 2-nitrotoluene (o-MNT) vapor. In addition, the relationship between the sensing efficiency and the inherent structure of compounds the sensing mechanisms were discussed in detail.
- metal-organic frameworks,
- luminescent sensing,
- nitro aromatic compounds
1. [1]
  Cui S Q, Pu S Z, Dai Y F. Anal. Methods, 2015, 7:3593-3599 doi: 10.1039/C5AY00322A
2. [2]
  Jung J Y, Kang M, Yoon J, et al. Chem. Commun., 2013, 49:176-178 doi: 10.1039/C2CC36626F
3. [3]
  Ruan Y B, Li C, Xie J, et al. Chem. Commun., 2010, 46:9220-9222 doi: 10.1039/c0cc03825c
4. [4]
  Jang Y K, Nam U C, Kim C. Dyes Pigm., 2013, 99:6-13 doi: 10.1016/j.dyepig.2013.04.002
5. [5]
  Megharaj M, Pearson H W, Venkateswarlu K. Arch. Environ. Contam. Toxicol., 1991, 21:578-584 doi: 10.1007/BF01183881
6. [6]
  Dunnick J K, Elwell M R. Fundam. Appl. Toxicol., 1994, 22:411-422 doi: 10.1006/faat.1994.1047
7. [7]
  Uberol V, Bhatacharya S K. Water Environ. Res., 1997, 69:146-156 doi: 10.2175/106143097X125290
8. [8]
  Jjiunju P M, Maher S, Cooks R G, et al. Anal. Chem., 2015, 87:10047-10055 doi: 10.1021/acs.analchem.5b02684
9. [9]
  Peveler W J, Roldan A, Parkin I P, et al. ACS Nano, 2016, 10:1139-1146 doi: 10.1021/acsnano.5b06433
10. [10]
  Xiong W, Liu X L, Zhao J C, et al. Anal. Chem., 2016, 88:10826-10830 doi: 10.1021/acs.analchem.6b03618
11. [11]
  Zeng S, Baillargeat D, Yong K, et al. Chem. Soc. Rev., 2014, 43:3426-3452 doi: 10.1039/c3cs60479a
12. [12]
  Wang H X, Wang N, Jiang Q W, et al. Environ. Sci. Technol., 2017, 51:3518-3525 doi: 10.1021/acs.est.6b06474
13. [13]
  Zhou J M, Shi W, Cheng P, et al. Inorg. Chem., 2013, 52:8082-8090 doi: 10.1021/ic400770j
14. [14]
  Lustig W P, Mukherjee S, Ghosh S K, et al. Chem. Soc. Rev., 2017, 46:3242-3285 doi: 10.1039/C6CS00930A
15. [15]
  Chen Y Q, Li G R, Bu X H, et al. Chem. Sci., 2013, 4:3678-3682 doi: 10.1039/c3sc00057e
16. [16]
  Kim T K, Lee J H., Moon H R, et al. Inorg. Chem., 2013, 52:589-595
17. [17]
  Zheng Q, Yang F, Zhou Y, et al. Inorg. Chem., 2013, 52:10368-10374 doi: 10.1021/ic401092j
18. [18]
  Zhou H C, Long J R, Yaghi O M, et al. Chem. Rev., 2012, 112:673-674 doi: 10.1021/cr300014x
19. [19]
  Tan Y X, Wang F and Zhang J, et al. Chem. Soc. Rev., 2018, 47:2130-2144 doi: 10.1039/C7CS00782E
20. [20]
  Hu Y L, Ding M L, Jiang H L, et al. Chem. Commun., 2016, 52:5734-5737 doi: 10.1039/C6CC01597B
21. [21]
  Yi F Y, Chen D, Jiang H L, et al. ChemPlusChem, 2016, 81:675-690 doi: 10.1002/cplu.201600137
22. [22]
  CHENG Mei-Ling, YANG Bin-Xin, TANG Xiao-Yan, et al. Chinese J. Inorg. Chem., 2019, 35(4):687-694
23. [23]
  Hou S L, Dong J, Zhao B, et al. Anal. Chem., 2018, 90:1516-1519 doi: 10.1021/acs.analchem.7b05088
24. [24]
  Hou Y, Xu H, Zhao B, et al. Chem. Commun., 2015, 51:6769-6772 doi: 10.1039/C5CC01181G
25. [25]
  Zhou L J, Deng W H, Liu Q Y, et al. Inorg. Chem., 2016, 55:6271-6277 doi: 10.1021/acs.inorgchem.6b00928
26. [26]
  Li Y J, Wang Y L, Liu Q Y, et al. Inorg. Chem., 2017, 56:2159-2164 doi: 10.1021/acs.inorgchem.6b02811
27. [27]
  He R, Wang Y L, Liu Q Y, et al. Dyes Pigm., 2018, 151:342-347 doi: 10.1016/j.dyepig.2018.01.018
28. [28]
  Fu H R, Yan L B, Wu N T, et al. J. Mater. Chem. A, 2018, 6:9183-9191 doi: 10.1039/C8TA02857E
29. [29]
  Zhou Z, Han M L, Li D S, et al. Dalton Trans., 2018, 47:5359-5365 doi: 10.1039/C8DT00594J
30. [30]
  Vishnoi P, Walawalkar M, Muruqavel R, et al. Phys. Chem. Chem. Phys., 2014, 16:10651-10658 doi: 10.1039/C4CP00930D
31. [31]
  Li J, Men C P, Cui L, et al. Z. Anorg. Allg. Chem., 2018, 644:228-234 doi: 10.1002/zaac.201700406
32. [32]
  Xue Y Y, He Y, Chen B, et al. J. Mater. Chem. A, 2013, 1:4525-4530 doi: 10.1039/c3ta01118f
33. [33]
  Lakowicz J R. Principles of Fluorescence Spectroscopy. 3rd Ed. New York:Springer, 2006:5-33
34. [34]
  Xiao Y, Cui Y, Zheng Q, Xiang S, et al. Chem. Commun., 2010, 46:5503-5505 doi: 10.1039/c0cc00148a
35. [35]
  Chen S G, Shi Z Z, Zheng H G, et al. Cryst. Growth Des., 2017, 17:67-72 doi: 10.1021/acs.cgd.6b01197
36. [36]
  Liu J, Ji G, Xiao J, et al. Inorg. Chem., 2017, 56:4197-4205 doi: 10.1021/acs.inorgchem.7b00157
37. [37]
  Wu X X, Fu H R, Ma L F. Cryst. Growth Des., 2017, 17:6041-6048 doi: 10.1021/acs.cgd.7b01155
38. [38]
  Pang L Y, Yang G P, Shi Q Z, et al. Cryst. Growth Des., 2014, 14:2954-2961 doi: 10.1021/cg5002418
39. [39]
  Wang H, Yang W T, Sun Z M. Chem. Asian J., 2013, 8:982-989 doi: 10.1002/asia.201201184
40. [40]
  Zhang S R, Du D Y, Su Z M, et al. Chem. Eur. J., 2014, 20:3589-3594 doi: 10.1002/chem.201304692
41. [41]
  Wang G Y, Song C, Li Y, et al. J. Mater. Chem. A, 2014, 2:2213-2220 doi: 10.1039/C3TA14199C
42. [42]
  Hu Z C, Deibert B J, Li J. Chem. Sov. Rev., 2014, 43:5815-5840 doi: 10.1039/C4CS00010B
43. [43]
  Chen B, Yang Y, Lobkovsky E B, et al. Adv. Mater., 2007, 19:1693-1696 doi: 10.1002/adma.200601838
44. [44]
  Nagarkar S S, Joarder B, Ghosh S K, et al. Angew. Chem. Int. Ed., 2013, 52(10):2881-2885 doi: 10.1002/anie.201208885
45. [45]
  Wang J, Mei J, Tang B Z, et al. J. Mater. Chem. A, 2011, 21:4056-4059 doi: 10.1039/c0jm04100a
46. [46]
  Wei W, Huang X, Tang X, et al. RSC Adv., 2012, 2:3765-3771 doi: 10.1039/c2ra20263h
47. [47]
  Ramachandra S, Popovic Z D, Cola L D, et al. Small, 2011, 7(10):1488-1494 doi: 10.1002/smll.201100010
48. [48]
  Wu Z F, Tan B, Huang X Y, et al. J. Mater. Chem. A, 2014, 2:6426-6431 doi: 10.1039/C3TA15071B
1. [1]
  Jimin HOU , Mengyang LI , Chunhua GONG , Shaozhuang ZHANG , Caihong ZHAN , Hao XU , Jingli XIE . Synthesis, structures, and properties of metal-organic frameworks based on bipyridyl ligands and isophthalic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 549-560. doi: 10.11862/CJIC.20240348
2. [2]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
3. [3]
  Yueyue WEI , Xuehua SUN , Hongmei CHAI , Wanqiao BAI , Yixia REN , Loujun GAO , Gangqiang ZHANG , Jun ZHANG . Two Ln-Co (Ln=Eu, Sm) metal-organic frameworks: Structures, magnetism, and fluorescent sensing sulfasalazine and glutaraldehyde. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2475-2485. doi: 10.11862/CJIC.20240193
4. [4]
  Chao Liu , Chao Jia , Shi-Xian Gan , Qiao-Yan Qi , Guo-Fang Jiang , Xin Zhao . A luminescent one-dimensional covalent organic framework for organic arsenic sensing in water. Chinese Chemical Letters, 2024, 35(11): 109750-. doi: 10.1016/j.cclet.2024.109750
5. [5]
  Deshuai Zhen , Chunlin Liu , Qiuhui Deng , Shaoqi Zhang , Ningman Yuan , Le Li , Yu Liu . A review of covalent organic frameworks for metal ion fluorescence sensing. Chinese Chemical Letters, 2024, 35(8): 109249-. doi: 10.1016/j.cclet.2023.109249
6. [6]
  Xin Chen , Meng Zhao , Yan-Yuan Jia . Stable Eu(III)-based metal-organic framework for fluorescence sensing of benzaldehyde and its analogues. Chinese Journal of Structural Chemistry, 2025, 44(3): 100445-100445. doi: 10.1016/j.cjsc.2024.100445
7. [7]
  Ze Liu , Xiaochen Zhang , Jinlong Luo , Yingjian Yu . Application of metal-organic frameworks to the anode interface in metal batteries. Chinese Chemical Letters, 2024, 35(11): 109500-. doi: 10.1016/j.cclet.2024.109500
8. [8]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
9. [9]
  Youlin SI , Shuquan SUN , Junsong YANG , Zijun BIE , Yan CHEN , Li LUO . Synthesis and adsorption properties of Zn(Ⅱ) metal-organic framework based on 3, 3', 5, 5'-tetraimidazolyl biphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1755-1762. doi: 10.11862/CJIC.20240061
10. [10]
  Fugui XI , Du LI , Zhourui YAN , Hui WANG , Junyu XIANG , Zhiyun DONG . Functionalized zirconium metal-organic frameworks for the removal of tetracycline from water. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 683-694. doi: 10.11862/CJIC.20240291
11. [11]
  Yuxin Wang , Zhengxuan Song , Yutao Liu , Yang Chen , Jinping Li , Libo Li , Jia Yao . Methyl functionalization of trimesic acid in copper-based metal-organic framework for ammonia colorimetric sensing at high relative humidity. Chinese Chemical Letters, 2024, 35(6): 108779-. doi: 10.1016/j.cclet.2023.108779
12. [12]
  Xiaoyan Peng , Xuanhao Wu , Fan Yang , Yefei Tian , Mingming Zhang , Hongye Yuan . Gas sensors based on metal-organic frameworks: challenges and opportunities. Chinese Journal of Structural Chemistry, 2024, 43(3): 100251-100251. doi: 10.1016/j.cjsc.2024.100251
13. [13]
  Kang Wang , Qinglin Zhou , Weijin Li . Conductive metal-organic frameworks for electromagnetic wave absorption. Chinese Journal of Structural Chemistry, 2024, 43(10): 100325-100325. doi: 10.1016/j.cjsc.2024.100325
14. [14]
  Genlin Sun , Yachun Luo , Zhihong Yan , Hongdeng Qiu , Weiyang Tang . Chiral metal-organic frameworks-based materials for chromatographic enantioseparation. Chinese Chemical Letters, 2024, 35(12): 109787-. doi: 10.1016/j.cclet.2024.109787
15. [15]
  Guoying Han , Qazi Mohammad Junaid , Xiao Feng . Topology-driven directed synthesis of metal-organic frameworks. Chinese Journal of Structural Chemistry, 2025, 44(3): 100447-100447. doi: 10.1016/j.cjsc.2024.100447
16. [16]
  Cheng-Shuang Wang , Bing-Yu Zhou , Yi-Feng Wang , Cheng Yuan , Bo-Han Kou , Wei-Wei Zhao , Jing-Juan Xu . Bifunctional iron-porphyrin metal-organic frameworks for organic photoelectrochemical transistor gating and biosensing. Chinese Chemical Letters, 2025, 36(3): 110080-. doi: 10.1016/j.cclet.2024.110080
17. [17]
  Jian Yang , Guang Yang , Zhijie Chen . Capturing carbon dioxide from air by using amine-functionalized metal-organic frameworks. Chinese Journal of Structural Chemistry, 2024, 43(5): 100267-100267. doi: 10.1016/j.cjsc.2024.100267
18. [18]
  Zhiqiang Liu , Qiang Gao , Wei Shen , Meifeng Xu , Yunxin Li , Weilin Hou , Hai-Wei Shi , Yaozuo Yuan , Erwin Adams , Hian Kee Lee , Sheng Tang . Removal and fluorescence detection of antibiotics from wastewater by layered double oxides/metal-organic frameworks with different topological configurations. Chinese Chemical Letters, 2024, 35(8): 109338-. doi: 10.1016/j.cclet.2023.109338
19. [19]
  Longlong Geng , Huiling Liu , Wenfeng Zhou , Yong-Zheng Zhang , Hongliang Huang , Da-Shuai Zhang , Hui Hu , Chao Lv , Xiuling Zhang , Suijun Liu . Construction of metal-organic frameworks with unsaturated Cu sites for efficient and fast reduction of nitroaromatics: A combined experimental and theoretical study. Chinese Chemical Letters, 2024, 35(8): 109120-. doi: 10.1016/j.cclet.2023.109120
20. [20]
  Xian-Fa Jiang , Chongyun Shao , Zhongwen Ouyang , Zhao-Bo Hu , Zhenxing Wang , You Song . Generating electron spin qubit in metal-organic frameworks via spontaneous hydrolysis. Chinese Chemical Letters, 2024, 35(7): 109011-. doi: 10.1016/j.cclet.2023.109011

Get Citation

PDF

XML

Metrics

PDF Downloads(6)
Abstract views(475)
HTML views(99)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142