Citation: ZHANG Zhao-Pei, Vlasenko Volodymyr Anatoliyovych, Liu Run-Qiang, YANG Li, LIU Lu, ZHANG Yu-Ping. Syntheses, Characterization and Crystal S tructures of Cd(Ⅱ)/Co(Ⅱ)/Zn(Ⅱ) Complexes Based on Flexible Bis(methylbenzimidazole) and Carboxylate Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(9): 1642-1650. doi: 10.11862/CJIC.2019.194 shu

Syntheses, Characterization and Crystal S tructures of Cd(Ⅱ)/Co(Ⅱ)/Zn(Ⅱ) Complexes Based on Flexible Bis(methylbenzimidazole) and Carboxylate Ligands

1.
School of Life Science and Technology, Henan Institute of Science and Technology, Collaborative Innovation Center of Modern Biological Breeding of Henan Province, Henan Institute of Science and echnology, Xinxiang, Henan 453003, China
2.
Agrotechnologies and Environmental Use Department, Sumy National Agrarian University, Sumy, 40021, Ukraine
3.
School of Resource and Environmental Sciences, Henan Institute of Science and Technology, Xinxiang, Henan 453003, China
4.
School of Chemistry and Chemical Engineering, Henan Institute of Science and Technology Xinxiang, Henan 453003, China

Corresponding author: LIU Lu, liululiulu2012@126.com
Received Date: 17 December 2018
Revised Date: 23 June 2019

Figures(4)

Three Cd(Ⅱ)/Co(Ⅱ)/Zn(Ⅱ) coordination complexes, formulated as[Cd(hbmb)_0.5(pta)]_n (1), [Co(hbmb)(1, 4-bdc)]_n (2), {[Zn₂(hbmb)_1.5(bptc)(H₂O)]·0.5hbmb·3H₂O}_n (3) (hbmb=1, 1'-(1, 6-hexane)bis-(2-methylbenzimidazole), H₂pta=homophthalic acid, 1, 4-H₂bdc=1, 4-benzenedicarboxylic acid, H₄bptc=3, 3', 4, 4'-benzophenone tetracar-boxylic acid), have been obtained by hydrothermal/solvothermal reactions. Complex 1 is a flat 4-connected 2D topology net with point symbol of (4⁴·6²), complex 2 features a undulated 2D network with point symbol of (4²·6)(4²·6³·8), while complex 3 (3, 4, 4)-connected 3-fold interpenetrating network with a vertex symbol of (4²·6²·8²)(4·6²)(4·6⁴·8) topology. Crystal data are monoclinic, space group, P2₁/c, a=0.758 32(15) nm, b=1.452 8(3) nm, c=1.911 3(5) nm, β=112.26(3)°, Z=4 for 1; and monoclinic, space group, P2₁/n, a=1.090 8(2) nm, b=1.873 1(4) nm, c=1.301 9(3) nm, β=91.09(3)°, Z=4 for 2; and triclinic, space group, P1, a=1.119 6(2) nm, b=1.481 2(3) nm, c=1.926 6(4) nm, α=89.72(3)°, β=87.65(3)°, γ=68.28(3)°, Z=2 for 3.
- coordination complex,
- crystal structure,
- topology
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