Citation: LI Yue-Jun, CAO Tie-Ping, ZHAO Yan-Hui, SUN Da-Wei, WANG Xia. Preparation of Bi@Bi₂Sn₂O₇/TiO₂ Plasmonic Composite Fibers with Enhanced Photocatalytic Hydrogen Generation Activity[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(8): 1371-1378. doi: 10.11862/CJIC.2019.187 shu

Preparation of Bi@Bi₂Sn₂O₇/TiO₂ Plasmonic Composite Fibers with Enhanced Photocatalytic Hydrogen Generation Activity

LI Yue-Jun ¹ ,
CAO Tie-Ping ^1,, ,
ZHAO Yan-Hui ¹ ,
SUN Da-Wei ^1,2 ,
WANG Xia ¹

1.
College of Chemistry, Baicheng Normal University, Baicheng, Jilin 137000, China
2.
College of Chemistry, Jilin Normal University, Siping, Jilin 136000, China

Corresponding author: CAO Tie-Ping, bcctp2008@163.com
Received Date: 16 March 2019
Revised Date: 8 June 2019

Figures(10)

By employing electrospun TiO₂ nanofiber as substrate, Bi@Bi₂Sn₂O₇/TiO₂ plasmonic composite fibers were prepared via one-step hydrothermal method. The composition, morphology and optical properties were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscope (SEM), high-resolution transmission electron microscope (HRTEM), ultraviolet-visible diffuse reflection spectra (UV-Vis DRS) and photoluminescence spectroscopy (PL) analysis. The photocatalytic water splitting for hydrogen evolution was investigated over Bi@Bi₂Sn₂O₇/TiO₂ plasmonic composite fibers with triethanolamine as the donor residue. The results showed that the Bi nanoparticles were generated onto Bi₂Sn₂O₇ nanoparticle via the in situ reduction of Bi³⁺ by glucose, meanwhile grew on the TiO₂ nanofibers surface. The enhanced photocatalytic activity of the Bi@Bi₂Sn₂O₇/TiO₂ plasmonic composites fibers can be further improved mainly attributed to the formation of high-quality p-n heterojunctions between Bi₂Sn₂O₇ and titanium dioxide, the plasma resonance effect of metal bismuth, and the synergistic effect of plasma resonance effect and p-n heterojunction. The corresponding H₂ production rate was 7.26 mmol·h^-1·g^-1.
- composite fibers,
- plasma,
- photocatalysis,
- hydrogen generation
1. [1]
  Xie J F, Zhang J J, Li S, et al. J. Am. Chem. Soc., 2013, 135(47):17881-17888 doi: 10.1021/ja408329q
2. [2]
  Ahmad H, Kamarudin S K, Minggu L J, et al. Renewable Sustainable Energy Rev., 2015, 43:599-610 doi: 10.1016/j.rser.2014.10.101
3. [3]
  Shimura K, Yoshida H. Energy Environ. Sci., 2011, 4(7):2467-2481 doi: 10.1039/c1ee01120k
4. [4]
  Jovic V, Smith K E, Idriss H, et al. ChemSusChem, 2015, 8(15):2551-2559 doi: 10.1002/cssc.201500126
5. [5]
  Liu L C, Liu Z, Liu A N, et al. ChemSusChem, 2014, 7(2):618-626 doi: 10.1002/cssc.201300941
6. [6]
  LI Yue-Jun, CAO Tie-Ping, MIE Zhe-Min, et al. Chinese J. Inorg. Chem., 2019, 35(1):82-88
7. [7]
  Zalfani M, Hu Z Y, Yu W B, et al. Appl. Catal. B, 2017, 205(15):121-132
8. [8]
  Park H, Park Y, Kim W, et al. J. Photochem. Photobiol. A, 2013, 15:1-20 doi: 10.1016/j.jphotochemrev.2012.10.001
9. [9]
  Udod L V, Aplesnin S S, Sitnikov M N, et al. Phys. Solid State, 2014, 56(7):1315-1319 doi: 10.1134/S1063783414070336
10. [10]
  Andrews P C, Junk P C, Nuzhnaya I, et al. Inorg. Chem., 2012, 51(2):751-753
11. [11]
  Wu J J, Huang F Q, Lu X J, et al. J. Mater. Chem., 2011, 21(11):3872-3876 doi: 10.1039/c0jm03252b
12. [12]
  Tian Q F, Zhuang J D, Wang J X, et al. Appl. Catal. A, 2012, 425-426(28):74-78
13. [13]
  Wu X F, Sun Y, Li H, et al. J. Alloys Compd., 2018, 740(5):1197-1203
14. [14]
  Qin F, Wang R M, Li G F, et al. Catal. Commun., 2013, 42:14-19 doi: 10.1016/j.catcom.2013.07.039
15. [15]
  Dong F, Zhao Z W, Sun Y J, et al. Environ. Sci. Technol., 2015, 49(20):12432-12440 doi: 10.1021/acs.est.5b03758
16. [16]
  Dong F, Li Q Y, Sun Y J, et al. ACS Catal., 2014, 4(12):4341-4350 doi: 10.1021/cs501038q
17. [17]
  Qu L L, Luo Z J, Tang C. Mater. Res. Bull., 2013, 48(11):4601-4605 doi: 10.1016/j.materresbull.2013.07.047
18. [18]
  Wang L L, Duan X D, Wang G M, et al. Appl. Catal. B, 2016, 186:88-96 doi: 10.1016/j.apcatb.2015.12.056
19. [19]
  Ai Z H, Ho W K, Lee S C, et al. Environ. Sci. Technol., 2009, 43(11):4143-4150 doi: 10.1021/es9004366
20. [20]
  Xu H, Zhang K, Wang J. Appl. Surf. Sci., 2017, 416:191-199 doi: 10.1016/j.apsusc.2017.04.160
21. [21]
  Mohai M, Tth A, Hornsby P R, et al. Surf. Interface Anal., 2002, 34(1):735-739 doi: 10.1002/sia.1400
22. [22]
  Li Y Y, Dang L Y, Han L F, et al. J. Mol. Catal. A:Chem., 2013, 379(15):146-151
23. [23]
  Toudert J, Serna R, Castro M J D. J. Phys. Chem. C, 2012, 116(38):20530-20539 doi: 10.1021/jp3065882
24. [24]
  Wang Z, Jiang C L, Huang R, et al. J. Phys. Chem. C, 2014, 118(2):1155-1160
25. [25]
  LIANG Meng-Jun, DENG Nan, XIANG Xin-Yi, et al. Chinese J. Inorg. Chem., 2019, 35(2):263-270
26. [26]
  Yu Y, Cao C Y, Liu H, et al. J. Mater. Chem. A, 2014, 2(6):1677-1681 doi: 10.1039/C3TA14494A
27. [27]
  Zhang M Y, Shao C L, Mu J B, et al. CrystEngComm, 2012, 14(2):605-612 doi: 10.1039/C1CE05974B
28. [28]
  Ma D C, Zhao Y, Zhao J Z, et al. Superlattices Microstruct., 2015, 83:411-421 doi: 10.1016/j.spmi.2015.03.052
29. [29]
  Atwater H A, Polman A. Nat. Mater., 2010, 9(3):205-213
1. [1]
  Jianyin He , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . ZnCoP/CdLa₂S₄肖特基异质结的构建促进光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2404030-. doi: 10.3866/PKU.WHXB202404030
2. [2]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
3. [3]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
4. [4]
  Shijie Li , Ke Rong , Xiaoqin Wang , Chuqi Shen , Fang Yang , Qinghong Zhang . Design of Carbon Quantum Dots/CdS/Ta₃N₅ S-Scheme Heterojunction Nanofibers for Efficient Photocatalytic Antibiotic Removal. Acta Physico-Chimica Sinica, 2024, 40(12): 2403005-. doi: 10.3866/PKU.WHXB202403005
5. [5]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . 钛酸铋/氮化碳无机有机复合S型异质结纯水光催化产过氧化氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-. doi: 10.3866/PKU.WHXB202403009
6. [6]
  Xin Zhou , Zhi Zhang , Yun Yang , Shuijin Yang . A Study on the Enhancement of Photocatalytic Performance in C/Bi/Bi₂MoO₆ Composites by Ferroelectric Polarization: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(4): 296-304. doi: 10.3866/PKU.DXHX202310008
7. [7]
  Chenye An , Abiduweili Sikandaier , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . 红磷纳米颗粒嵌入花状CeO₂分级S型异质结高效光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-. doi: 10.3866/PKU.WHXB202405019
8. [8]
  Qin Hu , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Ni掺杂构建电子桥及激活MoS₂惰性基面增强光催化分解水产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2406024-. doi: 10.3866/PKU.WHXB202406024
9. [9]
  Jingzhuo Tian , Chaohong Guan , Haobin Hu , Enzhou Liu , Dongyuan Yang . 废塑料促进S型NiCr₂O₄/孪晶Cd_0.5Zn_0.5S同质异质结光催化产氢. Acta Physico-Chimica Sinica, 2025, 41(6): 100068-. doi: 10.1016/j.actphy.2025.100068
10. [10]
  Qin Li , Huihui Zhang , Huajun Gu , Yuanyuan Cui , Ruihua Gao , Wei-Lin Dai . In situ Growth of Cd_0.5Zn_0.5S Nanorods on Ti₃C₂ MXene Nanosheet for Efficient Visible-Light-Driven Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2025, 41(4): 100031-. doi: 10.3866/PKU.WHXB202402016
11. [11]
  Yuchen Zhou , Huanmin Liu , Hongxing Li , Xinyu Song , Yonghua Tang , Peng Zhou . 设计热力学稳定的贵金属单原子光催化剂用于乙醇的高效非氧化转化形成高纯氢和增值产物乙醛. Acta Physico-Chimica Sinica, 2025, 41(6): 100067-. doi: 10.1016/j.actphy.2025.100067
12. [12]
  Xi YANG , Chunxiang CHANG , Yingpeng XIE , Yang LI , Yuhui CHEN , Borao WANG , Ludong YI , Zhonghao HAN . Co-catalyst Ni₃N supported Al-doped SrTiO₃: Synthesis and application to hydrogen evolution from photocatalytic water splitting. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 440-452. doi: 10.11862/CJIC.20240371
13. [13]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
14. [14]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
15. [15]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016
16. [16]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-. doi: 10.3866/PKU.WHXB202408005
17. [17]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
18. [18]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
19. [19]
  Jingyu Cai , Xiaoyu Miao , Yulai Zhao , Longqiang Xiao . Exploratory Teaching Experiment Design of FeOOH-RGO Aerogel for Photocatalytic Benzene to Phenol. University Chemistry, 2024, 39(4): 169-177. doi: 10.3866/PKU.DXHX202311028
20. [20]
  Yulian Hu , Xin Zhou , Xiaojun Han . A Virtual Simulation Experiment on the Design and Property Analysis of CO₂ Reduction Photocatalyst. University Chemistry, 2025, 40(3): 30-35. doi: 10.12461/PKU.DXHX202403088

Get Citation

PDF

XML

Metrics

PDF Downloads(14)
Abstract views(1644)
HTML views(276)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of Bi@Bi2Sn2O7/TiO2 Plasmonic Composite Fibers with Enhanced Photocatalytic Hydrogen Generation Activity

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation of Bi@Bi₂Sn₂O₇/TiO₂ Plasmonic Composite Fibers with Enhanced Photocatalytic Hydrogen Generation Activity