Citation: HE Yan-Li, MENG Yin-Shan, SUN Hui-Ying, JIANG Wen-Jing, JIAO Cheng-Qi, LIU Tao. Synthesis and Magnetism of Cyano-Bridged Fe₂Ni Double-Zigzag Chains[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(9): 1570-1578. doi: 10.11862/CJIC.2019.176 shu

Synthesis and Magnetism of Cyano-Bridged Fe₂Ni Double-Zigzag Chains

State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, Liaoning 116024, China

Corresponding author: LIU Tao, liutao@dlut.edu.cn
Received Date: 20 March 2019
Revised Date: 30 June 2019

Figures(6)

Three cyano-bridged Fe₂Ni chain compounds were synthesized via the reaction of tetracyanometallate building block and pyridine ligands with different steric hindrance. Compounds {[Fe(bpy)(CN)₄]₂[Ni(bp)₂]·2H₂O}_n (1) (bpy=2, 2'-bipyridine; bp=4-phenylpyridine), {[Fe(bpy)(CN)₄]₂[Ni(papy)₂]·H₂O}_n (2) (papy=4-(phenyldiazenyl)pyridine) and {[Fe(bpy)(CN)₄]₂[Ni(azp)]·4H₂O}_n (3) (azp=1, 2-di(pyridin-4-yl)diazene) all show double-zigzag chain-like structures. Magnetic study indicates that compounds 1~3 all show intrachain ferromagnetic interactions. Alternating current susceptibility measurements demonstrated the single-chain magnet behavior of compound 1 with the relaxation energy barrier E_a/k_B of 10.9 K.
- cyano-bridged,
- double-zigzag chain,
- ferromagnetic,
- single-chain magnets
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Synthesis and Magnetism of Cyano-Bridged Fe₂Ni Double-Zigzag Chains