Citation: REN Xiu-Hui, WANG Peng, SU Jian, CHENG Jun-Yan. Syntheses and Crystal Structures of Two Discrete Complexes Generated from 3, 6-Bis(2-(4-oxide-quinoxaline)-yl)-4, 5-diaza-3, 5-octadiene and Ag(Ⅰ) Salt[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(8): 1436-1444. doi: 10.11862/CJIC.2019.174 shu

Syntheses and Crystal Structures of Two Discrete Complexes Generated from 3, 6-Bis(2-(4-oxide-quinoxaline)-yl)-4, 5-diaza-3, 5-octadiene and Ag(Ⅰ) Salt

REN Xiu-Hui ¹ ,
WANG Peng ^2,, ,
SU Jian ³ ,
CHENG Jun-Yan ^1,,

1.
School of Chemistry, Chemical Engineering and Materials Science, Shandong Normal University, Jinan 250014, China
2.
College of Chemical and Environmental Engineering, Shandong University of Science and Technology, Qingdao, Shandong 266590, China
3.
School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China

Corresponding author: WANG Peng, pengwang@sdust.edu.cn CHENG Jun-Yan, chengjunyan@sdnu.edu.cn
Received Date: 26 November 2018
Revised Date: 22 May 2019

Figures(8)

Two novel discrete complexes with Ag(Ⅰ) centers based on the double Schiff-base ligand, 3, 6-bis(2-(4-oxide-quinoxaline)-yl)-4, 5-diaza-3, 5-octadiene (L), have been synthesized. The obtained Ag(Ⅰ) complexes, [Ag₈(L)₈](BF₄)₈·CH₂Cl₂·3CH₃OH (1) and[Ag₄(L)₄](PF₆)₄·CH₂Cl₂ (2), were fully characterized by infrared spectroscopy, elemental analysis, and single-crystal X-ray diffraction. Both complexes exist as dimers. Through hydrogen bonds, uncoordinated counter ions and discrete molecular complex building blocks formed one-dimensional (1D) or two-dimensional (2D) frameworks.
- double Schiff-base ligand,
- discrete compound,
- hydrogen bond
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沈阳化工大学材料科学与工程学院沈阳 110142