Citation: LIU Xiao-Jun, SUN Li-Ting, ZHANG Shu, ZHOU Chen, LIU Yan-Zhu, ZHOU Xue-Zhen, LI Yong-Xiu. Highly Sensitive Luminescent Sensor for Cr(Ⅲ) Based on a Water Dispersed Nano-sized Amorphous Methyl Salicylate Terbium Complex[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(8): 1445-1454. doi: 10.11862/CJIC.2019.166 shu

Highly Sensitive Luminescent Sensor for Cr(Ⅲ) Based on a Water Dispersed Nano-sized Amorphous Methyl Salicylate Terbium Complex

Research Center for Rare Earths & Nano/micro Functional Material, Nanchang University, Nanchang 330031, China

Corresponding author: LIU Yan-Zhu, zhouxuezhen@ncu.edu.cn
Received Date: 3 December 2018
Revised Date: 8 May 2019

Figures(8)

To expand the application fields of rare earth fluorescence complexes, and meet the requirements of high sensitivity and selectivity for the detection of trace chromium in aqueous solution, we prepared a sensitive luminescence sensor for Cr³⁺ ion based on a water dispersed nano-sized amorphous luminescence terbium complex with methyl salicylate (A-MS-Tb). It was found that the synthesized A-MS-Tb is an amorphous precipitation with particle size ranging from 50 to 100 nm and similar composition to the reported crystalline MS-Tb(C-MS-Tb). A-MS-Tb showed strong green luminescence at 494, 549, 591, 625 nm, which belongs to the energy level transition of ⁵D₄→⁷F_J (J=6, 5, 4, 3) of Tb³⁺, respectively. The difference between A-MS-Tb and the reported C-MS-Tb lies in the stability and dispersion performance towards water which is very important for expanding its application as materials and sensors. In particularly, with the addition of Cr³⁺ into the water suspension of A-MS-Tb, the coordination between the ligand and Tb³⁺ is weakened, causing its green fluorescence to be quenched. Therefore, a highly sensitive sensor for detecting Cr³⁺ was established, and the sensitivity, selectivity and anti-interference ability was evaluated.
- methyl salicylate terbium complex,
- luminescence,
- nano size,
- sensor for Cr³⁺
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