Citation: SHEN Xian-Rong, MENG Yue, XIA Sheng-Jie. Water Gas Shift Reaction Catalyzed by AuCu Alloy Nanoparticles Supported on Layered Double Hydroxides: Catalytic Performance and Structural Composition[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(7): 1239-1247. doi: 10.11862/CJIC.2019.159 shu

Water Gas Shift Reaction Catalyzed by AuCu Alloy Nanoparticles Supported on Layered Double Hydroxides: Catalytic Performance and Structural Composition

1.
School of Biological and Chemical Engineering, Anhui Polytechnic University, Wuhu, Anhui 241000, China
2.
School of Life Sciences, Huzhou University, Huzhou, Zhejiang 313000, China
3.
College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China

Corresponding author: XIA Sheng-Jie, xiasj@zjut.edu.cn
Received Date: 30 March 2019
Revised Date: 15 May 2019

Figures(5)

Au nanoparticles supported on layered double hydroxides (Au/LDHs) and AuCu alloy nanoparticles supported on layered double hydroxides (AuCu/LDHs) based on ZnAl layered double hydroxides (ZnAl-LDHs) were synthesized and used for catalyzing water gas shift reaction (WGSR). The structure and composition of Au/LDHs and AuCu/LDHs was characterized and confirmed by using X-ray powder diffraction (XRD), high resolution transmission electron microscopy (HRTEM) and scanning and transmission electron microscope (STEM). The effect of different molar ratios of Au and Cu (n_Au:n_Cu) for AuCu/LDHs onto the catalytic performance of WGSR was investigated and compared with the activity from Au/LDHs. It indicates that Au/LDHs has obviously higher activity compared to plain LDHs, while, AuCu alloy supporting can further largely enhance the catalytic activity for WGSR. Au₂Cu₁/LDHs (n_Au:n_Cu=2:1) exhibited the best catalytic efficiency:activity was 207.1 μmol·g_cat^-1·s^-1, TOF was 1.79 s^-1, and activity energy was 31.1 kJ·mol^-1. The effect of n_Au:n_Cu onto the Au particle size, Au dispersity, coverage degree of Au, and catalytic activity was discussed based on the comparison of physicochemical properties for different catalysts. The active species of Au/LDHs and AuCu/LDHs with different n_Au:n_Cu were analyzed and compared by X-ray photoelectron spectrometry (XPS). It was found that the introduction of the secondary element increased the percentage of Au^δ+ (Au₂Cu₁/LDHs had the highest Au^δ+ content), which maybe resulted in the enhancement of WGSR activity.
- AuCu alloy,
- supporting,
- layered double hydroxides,
- water gas shift reaction,
- catalyst composition,
- reaction activity
1. [1]
  Bobadilla L F, Penkova A, lvarez A, et al. Appl. Catal. A, 2015, 492:38-47 doi: 10.1016/j.apcata.2014.12.029
2. [2]
  Li Z, He T, Matsumura D, et al. ACS Catal., 2017, 7(10):6762-6769 doi: 10.1021/acscatal.7b01790
3. [3]
  Sivagurunathan P, Kumar G, Bakonyi P, et al. Int. J. Hydrogen Energy, 2016, 41(6):3820-3836 doi: 10.1016/j.ijhydene.2015.12.081
4. [4]
  Zhao Z J, Li Z L, Cui Y R, et al. J. Catal., 2017, 345:157-169 doi: 10.1016/j.jcat.2016.11.008
5. [5]
  WU Kai. Acta Phys.-Chim. Sin., 2018, 34(1):3-4
6. [6]
  Yang M, Li S, Wang Y, et al. Science, 2014, 346:1498-1501 doi: 10.1126/science.1260526
7. [7]
  Devaiah D, Smirniotis P G. Ind. Eng. Chem. Res., 2017, 56(7):1772-1781 doi: 10.1021/acs.iecr.6b04707
8. [8]
  Zhu M H, Wachs I E. ACS Catal., 2016, 6(2):722-732
9. [9]
  Pal D B, Chand R, Upadhyay S N, et al. Renewable Sustainable Energy Rev., 2018, 93:549-565 doi: 10.1016/j.rser.2018.05.003
10. [10]
  Wijayapala R, Yu F, Pittman C U, et al. Appl. Catal. A, 2014, 480:93-99 doi: 10.1016/j.apcata.2014.04.044
11. [11]
  Tang Q L, Duan X X, Zhang T T, et al. J. Phys. Chem. C, 2016, 120(44):25351-25360 doi: 10.1021/acs.jpcc.6b07050
12. [12]
  González-Castao M, Reina T R, Ivanova S, et al. Appl. Catal. B, 2016, 185:337-343 doi: 10.1016/j.apcatb.2015.12.032
13. [13]
  Rodriguez J A, Senanayake S D, Stacchiola D, et al. Acc. Chem. Res., 2014, 47(3):773-782 doi: 10.1021/ar400182c
14. [14]
  Abdel-Mageed A M, Kucerova G, Bansmann J, et al. ACS Catal., 2017, 7(10):6471-6484 doi: 10.1021/acscatal.7b01563
15. [15]
  Yao S Y, Zhang X, Zhou W, et al. Science, 2017, 357(6349):389-393 doi: 10.1126/science.aah4321
16. [16]
  GU Yan, LIU Guan-Ting, ZOU Cheng-Heng, et al. Chinese J. Inorg. Chem., 2017, 33(5):787-795
17. [17]
  Gamboa-Rosales N K, Ayastuy J L, Gutiérrez-Ortiz M A. Int. J. Hydrogen Energy, 2016, 41(42):19408-19417 doi: 10.1016/j.ijhydene.2016.05.237
18. [18]
  Nguyen-Phan T D, Baber A E, Rodriguez J A, et al. Appl. Catal. A, 2016, 518:18-47 doi: 10.1016/j.apcata.2015.12.012
19. [19]
  Flytzani-Stephanopoulos M. Acc. Chem. Res., 2014, 47(3):783-792 doi: 10.1021/ar4001845
20. [20]
  Carter J H, Althahban S, Nowicka E, et al. ACS Catal., 2016, 6(10):6623-6633 doi: 10.1021/acscatal.6b01275
21. [21]
  Xia S J, Shao M M, Zhou X B, et al. Phys. Chem. Chem. Phys., 2015, 17(40):26690-26702 doi: 10.1039/C5CP04125B
22. [22]
  Xia S J, Meng Y, Zhou X B, et al. Appl. Catal. B, 2016, 187:122-133 doi: 10.1016/j.apcatb.2016.01.027
23. [23]
  Xia S J, Zhang X F, Zhou X B, et al. Appl. Catal. B, 2017, 214:78-88 doi: 10.1016/j.apcatb.2017.05.033
24. [24]
  Hao C H, Guo X N, Pan Y T, et al. J. Am. Chem. Soc., 2016, 138:9361-9364 doi: 10.1021/jacs.6b04175
25. [25]
  Shi Y, Yang H M, Zhao X G, et al. Catal. Commun., 2012, 18:142-146 doi: 10.1016/j.catcom.2011.12.003
26. [26]
  Iqbal K, Iqbal A, Kirillov A M, et al. J. Mater. Chem. A, 2017, 5:6716-6724 doi: 10.1039/C6TA10880F
27. [27]
  Dutta S, Ray C, Negishi Y, et al. ACS Appl. Mater. Interfaces, 2017, 9(9):8134-8141 doi: 10.1021/acsami.7b00030
28. [28]
  Fang L, Luo W, Meng Y, et al. J. Phys. Chem. C, 2018, 122:17358-17369 doi: 10.1021/acs.jpcc.8b05463
29. [29]
  Liu Y, Wang N Y, Pan J H, et al. J. Am. Chem. Soc., 2014, 136(41):14353-14356 doi: 10.1021/ja507408s
30. [30]
  Mikami G, Grosu F, Kawamura S, et al. Appl. Catal. B, 2016, 199:260-271 doi: 10.1016/j.apcatb.2016.06.031
31. [31]
  Leandro S R, Mourato A C, Lapinska U, et al. J. Catal., 2018, 358:187-198 doi: 10.1016/j.jcat.2017.12.014
32. [32]
  Fu S F, Zheng Y, Zhou X B, et al. J. Hazard. Mater., 2019, 363:41-54 doi: 10.1016/j.jhazmat.2018.10.009
33. [33]
  Jin X J, Taniguchi K, Yamaguchi K, et al. Chem. Sci., 2016, 7(8):5371-5383 doi: 10.1039/C6SC00874G
34. [34]
  Zhang G H, Zhang X F, Meng Y, et al. J. Mater. Chem. A, 2018, 6:15839-15852 doi: 10.1039/C8TA05383A
35. [35]
  Zhang X F, Wang L W, Zhou X B, et al. ACS Sustainable Chem. Eng., 2018, 6:13395-13407 doi: 10.1021/acssuschemeng.8b03186
1. [1]
  Tongtong Zhao , Yan Wang , Shiyue Qin , Liang Xu , Zhenhua Li . New Experiment Development: Upgrading and Regeneration of Discarded PET Plastic through Electrocatalysis. University Chemistry, 2024, 39(3): 308-315. doi: 10.3866/PKU.DXHX202309003
2. [2]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
3. [3]
  Xi YANG , Chunxiang CHANG , Yingpeng XIE , Yang LI , Yuhui CHEN , Borao WANG , Ludong YI , Zhonghao HAN . Co-catalyst Ni₃N supported Al-doped SrTiO₃: Synthesis and application to hydrogen evolution from photocatalytic water splitting. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 440-452. doi: 10.11862/CJIC.20240371
4. [4]
  Haodong JIN , Qingqing LIU , Chaoyang SHI , Danyang WEI , Jie YU , Xuhui XU , Mingli XU . NiCu/ZnO heterostructure photothermal electrocatalyst for efficient hydrogen evolution reaction. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1068-1082. doi: 10.11862/CJIC.20250048
5. [5]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
6. [6]
  Yaping Li , Sai An , Aiqing Cao , Shilong Li , Ming Lei . The Application of Molecular Simulation Software in Structural Chemistry Education: First-Principles Calculation of NiFe Layered Double Hydroxide. University Chemistry, 2025, 40(3): 160-170. doi: 10.12461/PKU.DXHX202405185
7. [7]
  Zelong LIANG , Shijia QIN , Pengfei GUO , Hang XU , Bin ZHAO . Synthesis and electrocatalytic CO₂ reduction performance of metal-organic framework catalysts loaded with silver particles. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 165-173. doi: 10.11862/CJIC.20240409
8. [8]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
9. [9]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
10. [10]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
11. [11]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
12. [12]
  Ji-Quan Liu , Huilin Guo , Ying Yang , Xiaohui Guo . Calculation and Discussion of Electrode Potentials in Redox Reactions of Water. University Chemistry, 2024, 39(8): 351-358. doi: 10.3866/PKU.DXHX202401031
13. [13]
  Guanghui SUI , Yanyan CHENG . Application of rice husk-based activated carbon-loaded MgO composite for symmetric supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 521-530. doi: 10.11862/CJIC.20240221
14. [14]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
15. [15]
  Yu Wang , Haiyang Shi , Zihan Chen , Feng Chen , Ping Wang , Xuefei Wang . 具有富电子Pt^δ^-壳层的空心AgPt@Pt核壳催化剂：提升光催化H₂O₂生成选择性与活性. Acta Physico-Chimica Sinica, 2025, 41(7): 100081-. doi: 10.1016/j.actphy.2025.100081
16. [16]
  Heng Zhang . Determination of All Rate Constants in the Enzyme Catalyzed Reactions Based on Michaelis-Menten Mechanism. University Chemistry, 2024, 39(4): 395-400. doi: 10.3866/PKU.DXHX202310047
17. [17]
  Fangxuan Liu , Ziyan Liu , Guowei Zhou , Tingting Gao , Wenyu Liu , Bin Sun . Hollow structured photocatalysts. Acta Physico-Chimica Sinica, 2025, 41(7): 100071-. doi: 10.1016/j.actphy.2025.100071
18. [18]
  Hao GUO , Tong WEI , Qingqing SHEN , Anqi HONG , Zeting DENG , Zheng FANG , Jichao SHI , Renhong LI . Electrocatalytic decoupling of urea solution for hydrogen production by nickel foam-supported Co₉S₈/Ni₃S₂ heterojunction. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2141-2154. doi: 10.11862/CJIC.20240085
19. [19]
  Yue Zhao , Yanfei Li , Tao Xiong . Copper Hydride-Catalyzed Nucleophilic Additions of Unsaturated Hydrocarbons to Aldehydes and Ketones. University Chemistry, 2024, 39(4): 280-285. doi: 10.3866/PKU.DXHX202309001
20. [20]
  Hong Lu , Yidie Zhai , Xingxing Cheng , Yujia Gao , Qing Wei , Hao Wei . Advancements and Expansions in the Proline-Catalyzed Asymmetric Aldol Reaction. University Chemistry, 2024, 39(5): 154-162. doi: 10.3866/PKU.DXHX202310074

Get Citation

PDF

XML

Metrics

PDF Downloads(12)
Abstract views(1203)
HTML views(410)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142