Citation: LI Shan-Shan, ZHANG Mei-Na, LI Zheng, LI Xia. Nickel Complex Constructed by Biphenyldicarboxylic Acid: Synthesis, Crystal Structure and Photocatalytic Activity of Rhodamine B[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(7): 1148-1154. doi: 10.11862/CJIC.2019.149 shu

Nickel Complex Constructed by Biphenyldicarboxylic Acid: Synthesis, Crystal Structure and Photocatalytic Activity of Rhodamine B

Department of Chemistry, Capital Normal University, Beijing 100048, China

Corresponding author: LI Xia, xiali@cnu.edu.cn
Received Date: 5 December 2018
Revised Date: 5 May 2019

Figures(4)

Two complexes[Ni(3, 3'-dpdc)(dpp)]_n (1) and[Ni(2, 2'-dpdc)(phen)(H₂O)₂]_n (2) were obtained under different reaction conditions (2, 2'-H₂dpdc=2, 2'-biphenyldicarboxylic acid, 3, 3'-H₂dpdc=3, 3'-biphenyldicarboxylic acid, phen=1, 10-phenanthroline, dpp=1, 3-bis(4-pyridyl)propane), and their structures were characterized by X-ray single crystal diffraction. Complex 1 belongs to monoclinic system, space group P2₁/c. It has two-dimensional grid structure and the coordination environment of Ni(Ⅱ) ion is[NiO₂N₄]. The two carboxyl groups of the 3, 3'-dpdc ligand coordinate to the Ni(Ⅱ) ion by a bidentate chelate coordination mode to form a Ni-(3, 3'-dpdc) one-dimensional chain structure, and the dpp ligand adopts a single nitrogen atom bridged coordination mode to connect two Ni(Ⅱ)) ions to form a Ni-dpp one-dimensional chain. The two chains penetrate each other to form a two-dimensional grid structure. The two-dimensional grid structure is stacked into a three-dimensional structure by C15D-H15…O2, C21-H21A…O1 hydrogen bonding. Complex 2 belongs to orthorhombic crystal system, space group P2₁2₁2₁. The complex shows a one-dimensional zigzag structure. The coordination envrionment of Ni(Ⅱ) ion is[NiO₄N₂]. The two carboxyl groups of 2, 2'-dpdc adopt a single-tooth bridged coordination mode. The adjacent Ni(Ⅱ) ions are linked by 2, 2'-dpdc ligand to form the Ni-2, 2'-dpdc zigzag chain structure, and the chains are connected to form a three-dimensional supramolecular structure by O-H…O and C-H…π. The photocatalytic degradation of the organic dye rhodamine B by two complexes was investigated. The results show that complexes can degrade rhodamine B efficiently.
- transition metal complex,
- 2, 2'-biphenyldicarboxylic acid,
- 3, 3'-biphenyldicarboxylic acid,
- rhodamine B,
- crystal structure,
- photocatalysis
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