Citation: XU Dan, ZHU Liang-Kui, ZHOU Dan, FU Yu-Rong, FU Xiao-Wen, CHEN Rong, LI Hai-Xia. Preparation of Metal-Organic Framework-Derived Nano-Scale Nickel Phosphide Catalysts[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(8): 1455-1462. doi: 10.11862/CJIC.2019.148 shu

Preparation of Metal-Organic Framework-Derived Nano-Scale Nickel Phosphide Catalysts

XU Dan ^1,, ,
ZHU Liang-Kui ² ,
ZHOU Dan ¹ ,
FU Yu-Rong ¹ ,
FU Xiao-Wen ¹ ,
CHEN Rong ¹ ,
LI Hai-Xia ^1,,

1.
College of Pharmacy, Hainan Medical College, Haikou 571119, China
2.
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, China

Corresponding author: XU Dan, 1005036640@qq.com LI Hai-Xia, lihx0801@163.com
Received Date: 4 March 2019
Revised Date: 5 May 2019

Figures(7)

Herein, nickel phosphides nanoparticles with different phases were successfully prepared by multi-step calcination and phosphidation process at low temperature using Ni based MOF (Ni-MOF) as the precursor. The resulting materials were applied to the hydrogen evolution reaction (HER) catalyst, Ni1P1-500 obtained at a mass ratio of Ni@C to red phosphorus of 1:1 and a pyrolysis temperature of 500℃ exhibited a remarkably enhanced electrocatalytic performance with a current density of 10 mA·cm^-2 at an overpotential of 178 mV and a superior durability for the HER in acid media. A small Tafel slope of 62 mV·dec^-1 revealed a Desorption-Heyrovsky mechanism during the HER. The excellent electrocatalytic performance might be ascribed to the presence of the proton acceptor (P site) and hydride-acceptor (Ni site) centers on the surface of nickel phosphide.
- metal-organic framework,
- nickel phosphide,
- nanoparticles,
- hydrogen evolution reaction,
- electrocatalysis
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