Citation: LIU Xue-Ting, ZHU Hong-Cheng, LI Yuan, WANG Fang, ZHANG Yong-Tao, JIN Guan-Ping, WEI Feng-Yu. A High-Efficiency Visible-Light-Driven Mesoporous AgI@Fe-MIL-88B-NH₂ Photocatalyst via Z-Scheme Mechanism[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(7): 1255-1266. doi: 10.11862/CJIC.2019.141 shu

A High-Efficiency Visible-Light-Driven Mesoporous AgI@Fe-MIL-88B-NH₂ Photocatalyst via Z-Scheme Mechanism

School of Chemistry and Chemical Engineering, Hefei University of Technology, Anhui Key Laboratory of Controllable Chemical Reaction & Material Chemical Engineering, Hefei 230009, China

Corresponding author: WEI Feng-Yu, weifyliuj@hfut.edu.cn
Received Date: 14 September 2018
Revised Date: 3 April 2019

Figures(16)

Sulfonated polystyrene (PS) microspheres have been used as template to produce mesoporous Fe-MIL-88B-NH₂ spherical shell with open pore. Based on the shell a novel visible-light-active AgI modified microsphere Fe-MIL-88B-NH₂ was prepared by in situ reaction method. The photocatalytic activity of the resulted AgI@Fe-MIL-88B-NH₂ composite was enhanced significantly as compared with pure AgI and Fe-MIL-88B-NH₂, which can be derived from the enhanced adsorption capacity and the promoted separation of charge carriers. The possible mechanism for the separation of charge carriers can be attributed to the formation of a redox-mediator-free direct Z-scheme system which causes the photogenerated electrons to migrate from CB of Fe-MIL-88B-NH₂ to VB of AgI, thus yielding more active·O₂^- and·OH.
- microspheres,
- photocatalysis,
- AgI,
- Z-scheme
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

A High-Efficiency Visible-Light-Driven Mesoporous AgI@Fe-MIL-88B-NH2 Photocatalyst via Z-Scheme Mechanism

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通讯作者: 陈斌, bchen63@163.com

A High-Efficiency Visible-Light-Driven Mesoporous AgI@Fe-MIL-88B-NH₂ Photocatalyst via Z-Scheme Mechanism