Citation: HU Guo-Rong, HUANG Jin-Long, DU Ke, CAO Yan-Bing, PENG Zhong-Dong. Synthesis of High Capacity Gradient Cathode Material Li[Ni_0.85Co_0.08Mn_0.07]O₂ for Lithium Ion Battery[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(7): 1139-1147. doi: 10.11862/CJIC.2019.140 shu

Synthesis of High Capacity Gradient Cathode Material Li[Ni_0.85Co_0.08Mn_0.07]O₂ for Lithium Ion Battery

School of Metallurgical and Environment, Central South University, Changsha 410083, China

Corresponding author: HU Guo-Rong, 499498080@163.com
Received Date: 30 November 2018
Revised Date: 20 April 2019

Figures(13)

Precursor[Ni_0.85Co_0.08Mn_0.07](OH)₂ with continuous concentration gradient change of metal elements were prepared by a continuous crystallization method. The new gradient composite Cathode material Li[Ni_0.85Co_0.08Mn_0.07]O₂ was synthesized by sintering the mixture of as-prepared precursor and LiOH·H₂O in O₂. X-ray diffraction results indicated a low degree of cationic miscibility and a better layered structure. Scanning electronic microscopy showed the gradient material had a perfect spherical morphology. Particle size distribution was relatively concentrated in 11.5~12 μm. The line scan test of elements on the cross section area of coating shell showed that the main elements of the materials changed gradiently. From the center to the outer surface, the content of nickel became lower, while that of cobalt and manganese were higher. The initial discharge capacity was 204.3 mAh·g^-1 at 0.1C rate between 2.8 and 4.3 V. At 1C rate, its capacity was 185.3 mAh·g^-1 and retained 164.7 mAh·g^-1 (89.17%) after 100 cycles. When cycled at 55℃, the capacity of 1C rate was 202.7 mAh·g^-1 and retained 85.84% after 100 cycles, indicating good electrochemical capacity and cycling stability.
- Li-ion battery,
- cathode,
- high capacity,
- Li[Ni_0.85Co_0.08Mn_0.07]O₂
1. [1]
  Kang I K, Reddy Y K, Shin Y B, et al. Ceram. Int., 2018, 44:7808-7813 doi: 10.1016/j.ceramint.2018.01.213
2. [2]
  Maheshwari A, Heck M, Santarelli M. Electrochim. Acta, 2018, 273:335-348 doi: 10.1016/j.electacta.2018.04.045
3. [3]
  Aguilar E N, Ramos S G, González F, et al. Electrochem. Commun., 2018, 96:32-36 doi: 10.1016/j.elecom.2018.09.002
4. [4]
  Li Y, Yu H, Hu Y, et al. J. Energy Chem., 2018, 27:559-564 doi: 10.1016/j.jechem.2017.11.004
5. [5]
  Chen K L, Mu D B, Wu B R, et al. Int. J. Miner. Metall. Mater., 2017, 24(3):342-351 doi: 10.1007/s12613-017-1413-6
6. [6]
  Park S H, Yoon C S, Kang S G, et al. Electrochim. Acta, 2004, 49(4):557-563 doi: 10.1016/j.electacta.2003.09.009
7. [7]
  Park K, Choi B. J. Alloys Compd., 2018, 766:470-476 doi: 10.1016/j.jallcom.2018.06.135
8. [8]
  Delmas C, Ménétrier M, Croguennec L, et al. Electrochim. Acta, 1999, 45(1/2):243-253
9. [9]
  Kalyani P, Kalaiselvi N, Renganathan N G. J. Power Sources, 2003, 123(1):53-60 doi: 10.1016/S0378-7753(03)00458-0
10. [10]
  Rougier A, Gravereau P, Delmas C. J. Electrochem. Soc., 1996, 143(4):1168-1175 doi: 10.1149/1.1836614
11. [11]
  Zhong Q M, Sacken V, Lrich U. J. Power Sources, 1995, 54(2):221-223 doi: 10.1016/0378-7753(94)02071-A
12. [12]
  Ohzuku T, Ueda A, Nagayama M, et al. Electrochim. Acta, 1993, 38(9):1159-1167 doi: 10.1016/0013-4686(93)80046-3
13. [13]
  Kim J, Amine K. J. Power Sources, 2002, 104:33-39 doi: 10.1016/S0378-7753(01)00900-4
14. [14]
  Deng M M, Tang Z F, Shao Y, et al. J. Alloys Compd., 2018, 762:163-170 doi: 10.1016/j.jallcom.2018.05.245
15. [15]
  Nageswaran S, Keppeler M, Kim S J, et al. J. Power Sources, 2017, 346:89-96 doi: 10.1016/j.jpowsour.2017.02.013
16. [16]
  Yamamoto Y, Ohtsuka M, Azuma Y, et al. J. Power Sources, 2018, 401:263-270 doi: 10.1016/j.jpowsour.2018.08.100
17. [17]
  Lee D J, Bruno S, Sun Y K, et al. J. Power Sources, 2011, 196:7742-7746 doi: 10.1016/j.jpowsour.2011.04.007
18. [18]
  Seino Y, Ota T, Takada K, et al. J. Power Sources, 2011, 196:6488-6492 doi: 10.1016/j.jpowsour.2011.03.090
19. [19]
  Cho Y, Cho J. J. Electrochem. Soc., 2010, 157(6):A625-A629 doi: 10.1149/1.3363852
20. [20]
  Park B C, Kim H B, Bang H. J. et al. Ind. Eng. Chem. Res., 2008, 47:3876-3882 doi: 10.1021/ie0715308
21. [21]
  Yoon W S, Chung K Y, McBreen J, et al. Electrochem. Commun., 2006, 8:1257-1262 doi: 10.1016/j.elecom.2006.06.005
22. [22]
  Deutschen T, Gasser S, Schaller M, et al. J. Energy Storage, 2018, 19:113-119 doi: 10.1016/j.est.2018.07.003
23. [23]
  Sun Y K, Myung S T, Kim M H, et al. J. Am. Oil Chem. Soc., 2005, 127(38):13411-13418 doi: 10.1021/ja053675g
24. [24]
  Sun Y K, Myung S T, Shin H S, et al. J. Phys. Chem., 2006, 110:6810-6815 doi: 10.1021/jp0571473
25. [25]
  Park B C, Bang H J, Amine K, et al. J. Power Sources, 2007, 174:658-662 doi: 10.1016/j.jpowsour.2007.06.114
26. [26]
  Zhao Y J, Xia D G, Liu Q G. Chin. J. Chem., 2004, 22:1148-1152
27. [27]
  Smart M C, Whitacre J F, Ratnakumar B V. J. Power Sources, 2007, 168:501-508 doi: 10.1016/j.jpowsour.2006.10.106
28. [28]
  van Bommel A, Dahn J R. J. Electrochem. Soc., 2009, 156(5):A362-A365 doi: 10.1149/1.3079366
29. [29]
  Sun Y K, Myung S T, Park B C, et al. Nat. Mater., 2009, 8:320-324 doi: 10.1038/nmat2418
30. [30]
  Hu G R, Zhang M F, Liang L W, et al. Electrochim. Acta, 2016, 190:264-275 doi: 10.1016/j.electacta.2016.01.039
31. [31]
  Lee W, Muhammad S, Kim T, et al. Adv. Energy Mater., 2019, 8:1701788
32. [32]
  Sun Y K, Kima D H, Junga H G, et al. Electrochim. Acta, 2010, 55:8621-8627 doi: 10.1016/j.electacta.2010.07.074
33. [33]
  Huang Z L, Gao J, He X M. J. Power Sources, 2012, 202:284-290 doi: 10.1016/j.jpowsour.2011.10.143
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis of High Capacity Gradient Cathode Material Li[Ni0.85Co0.08Mn0.07]O2 for Lithium Ion Battery

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通讯作者: 陈斌, bchen63@163.com

Synthesis of High Capacity Gradient Cathode Material Li[Ni_0.85Co_0.08Mn_0.07]O₂ for Lithium Ion Battery