Citation: CHEN Peng, JIANG Lin-Wen, LIU Jin-Jun, YANG Shan-Shan, LI Jiang-Tao, CHEN Hong-Bing, HE Jun, WANG Yu. Syntheses and Magnetic Properties of Spinel-Type MFe₂O₄ (M=Ca, Mg, Cu, Zn) Nanocrystalline Powders[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(6): 1101-1108. doi: 10.11862/CJIC.2019.133 shu

Syntheses and Magnetic Properties of Spinel-Type MFe₂O₄ (M=Ca, Mg, Cu, Zn) Nanocrystalline Powders

1.
State Key Laboratory Base of Functional Materials and its Preparation Science, Key Laboratory of Photoelectric Detection Materials and Devices of Zhejiang Province, Ningbo University, Ningbo, Zhejiang 315211, China
2.
Division of Functional Material Research, Central Iron & Steel Research Institute, Beijing 100081, China

Corresponding author: JIANG Lin-Wen, jianglinwen@nbu.edu.cn HE Jun, hejun@cisri.com.cn
Received Date: 6 January 2019
Revised Date: 30 March 2019

Figures(6)

Magnetic spinel-type MFe₂O₄ (M=Ca, Mg, Cu and Zn) nanocrystalline powders were successfully prepared by auto-combustion method using a novel amino-based gel. The phase identification, morphology and magnetic properties of as-synthesized powders were studied in detail. The high purity of synthesized MFe₂O₄ powders was comfirmed by energy dispersive X-ray spectroscopy. Magnetic properties of as-synthesized MFe₂O₄ nanocrystalline powders were investigated systematically. All the samples presented a rather narrow hysteresis loop, suggesting the soft magnetic features. The saturated magnetization (M_s) of the four ferrites were 2.1, 29.3, 24.1, and 4.2 emu·g^-1, respectively, and the residual magnetization (M_r) were 0.2, 2.3, 11.4, and 0.2 emu·g^-1, respectively. M_r/M_s values of four ferrite samples were all less than 0.5. Zero-field-cooled and field-cooled magnetic properties of CaFe₂O₄ and MgFe₂O₄ samples as two typical ferrites were investigated in detail. The magnetization of CaFe₂O₄ sample presented an inconsistent variation tendency below 75 K due to the occurrence of magnetic phase transition.
- spinel-type ferrites,
- auto-combustion method,
- magnetic properties
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沈阳化工大学材料科学与工程学院沈阳 110142

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通讯作者: 陈斌, bchen63@163.com

Syntheses and Magnetic Properties of Spinel-Type MFe₂O₄ (M=Ca, Mg, Cu, Zn) Nanocrystalline Powders