Citation: YU Meng, MU Hao-Ran, LIU Ling-Zhi, LI Na, BAI Yang, DONG Xiu-Yan. Syntheses, Structures and Hirshfeld Analyses of Trinuclear Ni(Ⅱ) Salamo-Type Complexes[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(6): 1109-1120. doi: 10.11862/CJIC.2019.128 shu

Syntheses, Structures and Hirshfeld Analyses of Trinuclear Ni(Ⅱ) Salamo-Type Complexes

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, China

Corresponding author: DONG Xiu-Yan, dxy568@163.com
Received Date: 3 February 2019
Revised Date: 28 March 2019

Figures(12)

Two newly designed complexes, {[Ni(L¹)(n-propanol)]₂(OAc)₂Ni}·2(n-propanol) (1) and {[Ni(L²)(n-butanol)]₂(OAc)₂Ni}·2(n-butanol) (2) derived from tetradentate Salamo-type chelating ligands (H₂L¹=5-methoxy-2, 2'-(ethylenedioxybis(azomethine))diphenol and H₂L²=4, 4'-dinitro-2, 2'-(ethylenediyldioxybis(nitrilomethylidyne))diphenol) have been synthesized and characterized by elemental analyses, IR and UV-Vis spectra, Hirshfeld surfaces analyses and single crystal X-ray crystallography. X-ray crystallographic analyses showed that complexes 1 and 2 are all symmetric trinuclear Ni(Ⅱ) complexes. Nickel(Ⅱ) in both 1 and 2 is hexa-coordinated, forming a twisted octahedral geometry. Both crystal structure and Hirshfeld surface analysis indicate that 1 and 2 form stable one-dimensional chain and two-dimensional supramolecular structures, respectively, by intermolecular hydrogen bonding.
- Salamo-type ligand,
- complex,
- synthesis,
- crystal structure,
- Hirshfeld analysis
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